Physico-Chemical and Phytochemical Characterization of Moroccan Wild Jujube “Zizyphus lotus (L.)” Fruit Crude Extract and Fractions

Wild jujube “Ziziphus lotus (L.) Desf.” belongs to the Rhamnaceae family and is a traditionally herbaceous medicinal plant. It is very common in arid and semi-arid regions and is currently used for its antidiabetic, sedative, analgesic, anti-inflammatory and hypoglycemic activities. The aim of the present work was to characterize the physico-chemical properties and the phytochemical profile of wild jujube sample collected from the Guercif region, in order to determine the polyphenolic compounds and the antioxidant ability Analyses were carried out directly after the harvest for the determination of pH, refractive index, total soluble solid (°Brix), dry matter, sugar/acidity, total sugars, reducing sugars, as well as lipid and protein content. Results showed that the investigated fruit is acidic (pH 4.9 ± 0.23) and rich in sugars (80.2 g/100 g ± 3.81). The GC-MS analysis of the fruit revealed a number of volatile compounds, as many as 97, belonging to different chemical classes. The HPLC-DAD-ESI/MS analysis showed the presence of a total of 20 polyphenolic compounds in both EtOAc and MeOH-water extracts. Among them, p-Hydroxybenzoic acid was the most abundant in the EtOAc extract (185.68 µg/100 mg ± 0.5) whereas Quercetin 3-O-rhamnoside-7-O-glucoside was found in higher amounts in the MeOH-water extract (25.40 µg/100 mg ± 0.5). These components have medical interest, notably for human nutrition, as well as health benefits and therapeutic effects. Therefore, Moroccan jujube “Zizyphus lotus (L.)” fruit may have potential industrial applications for food formulations.     

Particle motion and turbulence in dense two-phase flows

Measurements of particle mean and r.m.s. velocity were obtained by laser-Doppler anemometry in a descending solid-liquid turbulent flow in a vertical pipe with volumetric concentrations of suspended spherical particles of 270 μm mean diameter in the range 0.1–14%. Similar measurements were obtained in the flow downstream of an axisymmetric baffle of 50% area blockage placed in the pipe with volumetric concentrations of 310 μm particles up to 8% and of 665 μm particles up to 2%. In order to enable measurements in high particle concentrations without blockage of the laser beams the refractive index of the particles was matched to that of the carrier fluid.

The results show that the particle mean velocity profiles become more uniform and the particle r.m.s. velocity decreases with increasing concentration in both flow cases. The particle mean velocity in the pipe flow also decreases with concentration and the relative velocity, the difference between the particle velocity and the fluid velocity in single-phase flow, decreases with increasing Reynolds number. The length of the recirculation region downstream of the baffle was shorter than in single-phase flow by 11 and 24% for particle concentrations of 4 and 8%, respectively. The particle mean velocities were hardly affected by size for concentrations up fo 2%, but the r.m.s. velocities were lower with the larger particles.     

Local mixture injection to extend the lean limit of spark-ignition engines

 The effect of charge stratification by direct, in-cylinder injection of a small quantity of propane-air mixture in a single-cylinder, propane-fuelled, spart-ignition engine, has been determined in terms of in-cylinder pressure, flame visualisation and exhaust emissions. The operating conditions ranged from low load to wide open throttle at 1000 and 1500 rpm, and with quiescent and swirling in-cylinder flows. The effects of injection-driven flow and turbulence on combustion have been considered independently of mixture strength by assessing the consequences of injecting a local mixture of an equivalence ratio equal to that of the port-induced charge. The results provide further evidence to support the concept of direct in-cylinder mixture injection. At 1000 rpm and low load, faster development of the flame kernel and subsequent enflamed area were observed, together with a 60% increase in peak cylinder combustion pressure at an overall equivalence ratio of 0.7 (A/F of 22.5). The relative effect of local-charge stratification increased with reduction in equivalence ratio at this engine speed and without increase in emissions; at 1500 rpm, stable combustion was achieved even at an equivalence ratio of 0.61 (A/F of 25.8), which was below the flammability limit of the homogeneous port-only propane/ air mixture. Unthrottled engine operation produced similar results so that at an equivalence ratio of 0.55 (A/F of 28.5), for example, the Coefficient of variation of the indicated mean effective pressure was reduced from 0.4 to less than 0.1 by mixture local injection. With a shrouded inlet valve generating mean gas velocities of 6 m/s at the time of ignition in the vicinity of the spark plug, control of rich mixture injection both with and against the bulk in-cylinder flow, resulted in stable combustion with Coefficient of variation of the indicated mean effective pressure of less than 0.1 at an equivalence ratio of 0.55 (A/F of 28.5). Received: 28 October 1997/Accepted: 23 March 1998     

On the Analytical Derivation of Quantum Fisher Information and Skew Information for two Qubit X States

The quantum Fisher information defined via the symmetric logarithmic derivative and the skew information are two different aspects describing the information contents of quantum mechanical density operators. They are considered as natural generalizations of the classical Fisher information and constitute key ingredients in the emerging field of quantum metrology. In this paper, we give the analytical expression of quantum Fisher information and skew information for two-qubit system prepared in a two-qubit state of X type.

     

Influence of strain/stress on the nonlinear-optical properties of sprayed deposited ZnO:Al thin films

Nanocrystalline ZnO:Al thin films were deposited by reactive chemical pulverization spray pyrolysis technique on heated glass substrates at 450 °C to study their crystalline structure, composition, strain, stress, roughness characteristics and nonlinear optical susceptibility as a function of Al concentration (0, 2, 3, 5 at.%). The films were characterized by X-ray diffractometer (XRD), EDAX 9100 analyser, atomic force microscopy (AFM) and third harmonic generation (THG). The Al (3 at.%) doped ZnO thin films exhibited the lower strain/stress than undoped films. The nonlinear properties of the ZnO:Al thin films have been found to be influenced by the films strain/stress.     

Effects of injection timing on performance and droplet characteristics of a sixteen-valve four cylinder engine

 The performance and droplet characteristics of a sixteen-valve, four cylinder engine operating with combustion in one cylinder have been measured with part load, a speed of 1200 rpm and a stoichiometric mixture of gasoline and air. The indicated mean-effective cylinder pressure was found to be constant with initiation of injection from 150° to 630° of crank angle after top-dead-centre of intake and with a 10% reduction between 30° and 60° which coincided with maxima in the covariance in pressure and in the emissions of unburned hydrocarbon. There was also a tendency for performance to decline with injection after 660°. Measurements with laser- and phase-Doppler velocimeters showed that the number of droplets entering the cylinder was much reduced with injection at crank angles corresponding to closed inlet valves due to evaporation, and that the few large droplets which emerged did not survive until top-dead-centre of compression. In contrast, some of the many droplets associated with injection with the valves open survived to the crank angle of ignition and it is likely that these led to an inhomogeneous charge with poorer flame-front propagation responsible for reduction in performance. Received: 19 February 1996/Accepted: 8 October 1996     

slow release rubber formulations containing ZnSO4

Styrene butadiene (SBR) and natural rubber (NR) can be used as binding matrices to control the release of zinc (Zn) which is a micro-nutrient for plants. The leaching rate of zinc in an aqueous medium depends on the concentration of zinc sulphate loaded in the two types of rubber used, the temperature of the surrounding environment and the pH of the aqueous medium. Water uptake was increased with increasing concentration of ZnSO₄. The sustained release of zinc ions from the investigated formulations was prolonged for over five months. The mechanical properties of the vulcanizates were affected as the concentration of zinc sulphate changed.     

Interpretation of cyclic flow variations in motored internal combustion engines

Cyclic variations and turbulence characterisation are considered in the context of in-cylinder flows. Three methods of data analysis, namely ensemble averaging, high pass filtering and cycle-by-cycle smoothing, are applied to velocity data obtained by laser Doppler velocimetry in a model axisymmetric and a realistic engine configuration. The interpretation of the results is supported by similar analysis of a steady-state simulation of in-cylinder flow with emphasis on the discrimination between random and deterministic flow variations. The results suggest that it is not always possible to identify cyclic variations as deterministic processes and that turbulence estimates based on filtering techniques may be misleading. The differences in the estimates of mean values are, however, small.     

Velocity and Strain-Rate Characteristics of Opposed Isothermal Flows

Velocity measurements in the isothermal flows created by an opposed nozzle configuration are reported with emphasis on the axis, stagnation plane and the distributions of mean and instantaneous strain rates. The instrumentation comprised particle image velocimetry (PIV) with silicon oil droplets added to the flows upstream of both nozzles with the laser sheet passing through the axis between the nozzles. The results identify the regions of high strain rates and quantify the development of the mean and turbulent components of the flow from the nozzle exits as a function of bulk velocities from 3 to 8.2 m/s and nozzle separations from 0.4 to 1.0 diameters. Results show, for example, the rise in the values of axial and radial normal stress towards the stagnation plane with values increasing by up to 300% and 160% respectively. The maximum mean strain rate occurred just over one nozzle radius from the axis at the smallest separation and with values that increased from 450 to 950 s⁻¹ with decreasing separation at a bulk velocity of 3.0 m/s. Probability density functions were near Gaussian and hence much larger instantaneous strain rates were observed. The PIV image size had the advantage that it allowed the entire flow field to be viewed in terms of velocity vectors and derived quantities include mean strain rates. Small asymmetry of the flow and the higher strain rates at finite distances from the nominal impingement plane were observed. The experimental results permitted the domain of applicability of different modelling approaches to be defined more accurately and calculations were performed with different turbulence models. The results showed that two-equation turbulence models did not represent turbulence intensities close to impingement and that Reynolds stress closures produce superior agreement. It was further shown that ad hoc modifications to the dissipation equation, such as those based on the ratio of the turbulent to mean strain time scale, can improve results at the expense of generality. It is also shown that mean flows are well reproduced by a Reynolds stress closure for all nozzle separations. Comments are included on the implications of the results for investigations of reacting flows and extinction.