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51.
Deiglmayr J Aymar M Wester R Weidemüller M Dulieu O 《The Journal of chemical physics》2008,129(6):064309
The rapid development of experimental techniques to produce ultracold alkali molecules opens the ways to manipulate them and to control their dynamics using external electric fields. A prerequisite quantity for such studies is the knowledge of their static dipole polarizability. In this paper, we computed the variations with internuclear distance and with vibrational index of the static dipole polarizability components of all homonuclear alkali dimers including Fr(2), and of all heteronuclear alkali dimers involving Li to Cs, in their electronic ground state and in their lowest triplet state. We use the same quantum chemistry approach as in our work on dipole moments [Aymar and Dulieu, J. Chem. Phys. 122, 204302 (2005)], based on pseudopotentials for atomic core representation, Gaussian basis sets, and effective potentials for core polarization. Polarizabilities are extracted from electronic energies using the finite-field method. For the heaviest species Rb(2), Cs(2), and Fr(2) and for all heteronuclear alkali dimers, such results are presented for the first time. The accuracy of our results on atomic and molecular static dipole polarizabilities is discussed by comparing our values with the few available experimental data and elaborate calculations. We found that for all alkali pairs, the parallel and perpendicular components of the ground state polarizabilities at the equilibrium distance R(e) scale as (R(e))(3), which can be related to a simple electrostatic model of an ellipsoidal charge distribution. Prospects for possible alignment and orientation effects with these molecules in forthcoming experiments are discussed. 相似文献
52.
Hechtfischer U Rostas J Lange M Linkemann J Schwalm D Wester R Wolf A Zajfman D 《The Journal of chemical physics》2007,127(20):204304
We have measured the photodissociation spectrum of CH(+) and CD(+) molecular ions, stored as fast (MeV) ion beams in the heavy-ion storage ring TSR. Several b (3)Sigma(-)-a (3)Pi bands were observed as strong resonances because a large fraction of the ions in the metastable a (3)Pi(v=0) state were pumped to b (3)Sigma(-) levels and predissociated via the c (3)Sigma(+) state into C(+) and H(D) fragments. From a rotational analysis of the 2-0, 3-0, and 4-0 bands in CH(+) and the 3-0 and 4-0 bands in CD(+), we derive spectroscopic constants for these levels and also revise a previous analysis of the 0-0 and 1-0 bands in CH(+). Combining all data delivers new, significantly adjusted equilibrium constants for the b (3)Sigma(-) and a (3)Pi electronic states. Apart from the spectroscopic analysis, we estimate the predissociation rates of the upper b (3)Sigma(-) vibrational levels in CH(+) and compare them to a model. For the initial rovibrational distribution of the stored metastable CH(+) molecules, the data indicate a faster vibrational cooling than derived before, and rotational cooling at a rate similar to the X (1)Sigma(+) ground state. New aspects of the spin-forbidden a (3)Pi-X (1)Sigma(+) radiative decay are discussed. Finally, we predict b (3)Sigma(-)-a (3)Pi absorption and a (3)Pi-X (1)Sigma(+) emission lines through which CH(+) in the metastable a (3)Pi(v=0) state might be detectable in astrophysical environments. 相似文献
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Scattering of flexural waves by circular scatterers in a quarter-infinite thin plate is formulated using the wave expansion method together with the method of images. The scattered waves are expressed as a summation series of wave functions and the unknown scattering coefficients are determined by enforcing boundary conditions at the scatterers. Both holes and rigid scatterers are studied. Simply-supported and roller-supported boundary conditions on the quarter-infinite thin plate are also considered. The analysis can be used to determine the stress concentration caused by circular scatterers in quarter-infinite thin plates. 相似文献
55.
Isotope effects in reactions between Mg+ in the 3p{2}P{3/2} excited state and molecular hydrogen at thermal energies are studied through single reaction events. From only approximately 250 reactions with HD, the branching ratio between formation of MgD+ and MgH+ is found to be larger than 5. From an additional 65 reactions with H2 and D2 we find that the overall fragmentation probability of the intermediate MgH2+, MgHD+, or MgD2+ complexes is the same. Our study shows that few single ion reactions can provide quantitative information on ion-neutral reactions. Hence, the method is well suited for reaction studies involving rare species, e.g., rare isotopes or short-lived unstable elements. 相似文献
56.
G. Ooms C. Poelma P. Poesio MJ.B.M. Pourquie J. Westerweel 《International Journal of Multiphase Flow》2008
In an earlier publication some of the authors presented a theoretical model for the calculation of the influence of particle inertia and gravity on the turbulence in a stationary particle-laden flow. In the present publication the model is extended for application to a decaying suspension. Also a comparison is given between predictions made with the model and experimental data (own data and data reported in the literature) on a decaying turbulent flow with particles in a water tunnel or in a wind tunnel. For most of the experiments a prediction with reasonable accuracy and an interpretation is possible by means of the model. 相似文献
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Analytical and Bioanalytical Chemistry - Within a research programme of the specimen bank the standard operation procedures have to be elaborated for roe deer. The liver seems to be one of the... 相似文献
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