全文获取类型
收费全文 | 85049篇 |
免费 | 1467篇 |
国内免费 | 1373篇 |
专业分类
化学 | 29405篇 |
晶体学 | 825篇 |
力学 | 7172篇 |
综合类 | 62篇 |
数学 | 32705篇 |
物理学 | 17720篇 |
出版年
2023年 | 142篇 |
2022年 | 252篇 |
2021年 | 302篇 |
2020年 | 316篇 |
2019年 | 305篇 |
2018年 | 10602篇 |
2017年 | 10410篇 |
2016年 | 6334篇 |
2015年 | 1192篇 |
2014年 | 656篇 |
2013年 | 802篇 |
2012年 | 4325篇 |
2011年 | 11126篇 |
2010年 | 6036篇 |
2009年 | 6436篇 |
2008年 | 7046篇 |
2007年 | 9135篇 |
2006年 | 623篇 |
2005年 | 1684篇 |
2004年 | 1795篇 |
2003年 | 2204篇 |
2002年 | 1248篇 |
2001年 | 460篇 |
2000年 | 456篇 |
1999年 | 308篇 |
1998年 | 346篇 |
1997年 | 277篇 |
1996年 | 335篇 |
1995年 | 264篇 |
1994年 | 196篇 |
1993年 | 197篇 |
1992年 | 125篇 |
1991年 | 164篇 |
1990年 | 108篇 |
1989年 | 119篇 |
1988年 | 106篇 |
1987年 | 89篇 |
1986年 | 79篇 |
1985年 | 64篇 |
1984年 | 53篇 |
1983年 | 47篇 |
1982年 | 52篇 |
1981年 | 43篇 |
1980年 | 47篇 |
1979年 | 46篇 |
1914年 | 45篇 |
1913年 | 40篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 71 毫秒
11.
The following results are proved in this paper. Let G be a 2k-edge-connected eulerian graph. (i) For every set {e1, e2, ?, e2k+1} ? E(G) there is an eulerian trail T of the form e1, e2, ?, e2k+1, ?. (ii) For every set E* = {e1, e2, ?, ek} ? E(G) there is an eulerian trail T = e1, ?, e2, ?, ek, ? in which the elements of E* are traversed in accordance with a prescribed orientation. © 1995 John Wiley & Sons, Inc. 相似文献
12.
本文主要论证了在不完全市场条件下带风险指数的金融均衡的存在性,并揭示其均衡结构的特征.本文中建立的模型是一、二期货币投入产出金融经济且具有可微的资产结构,这一模型包括了许多具有特殊资产结构的均衡模型,如实资产结构、虚资产结构、恒秩资产结构的均衡模型.因此本文的这一模型具有广泛的应用前景和实用价值.接着给出了本文的金融均衡的存在性定理,再借助微分拓扑给出它的证明过程,这一证明过程较之以前证明均衡存在性的经典方法(如Duffie,D&W.Shfer(1985)的方法)要简便得多.同时也应注意到本文的这一结论既适用于资产市场下会随机风险因素的情形,也适用于商品空间为无限维的情形,除此之外,还给出了怎样判别资产结构是否属于T类的判别法,为检验均衡存在性提供了更为便利的途径.最后,本文论证了在金融市场里,尽管由于稀缺性的存在,从而导致均衡分配的多样化,然而均衡分配集却形成了一光滑子流,但该流形的维数与稀缺性有关.换句话说,尽管市场是不完全的,但均市分配不确定性的反却是可比的.如此使得人们对均衡资产结构的认识更进一步. 相似文献
13.
14.
James Tanton 《Mathematical Intelligencer》2007,29(3):55-59
This column is a place for those bits of contagious mathematics that travel from person to person in the community, because
they are so elegant, suprising, or appealing that one has an urge to pass them on.
Contributions are most welcome. 相似文献
15.
16.
Oleg V. Mikhailov Marina A. Kazymova Tatyana A. Shumilova Galina A. Chmutova Svetlana E. Solovieva 《Transition Metal Chemistry》2005,30(3):299-304
The complexing process proceeding in the NiII–thiocarbohydrazide (H2N–H–NC(=S)–NH–NH2)–propanone triple system in EtOH solution and nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix has been studied. It has been found that in the first case, template synthesis leading, as a minimum, to formation of three coordination compounds of NiII with (N,N,S,S)-donor tetradentate ligands having NiL1, NiL2 and NiL3compositions where L1 is 4,6,6-trimethyl-2,3,7,8-tetraazanonen-3-di(thiohydrazide)-1,9, L2 is 4,6,6,12-tetrametyl-1,9-dithio-2,3,7,8,10,11-hexaazatridekadien-3,11-hydrazide-1 and L3 is 2,8,10,10,16-pentamethyl-5,13-dithio-3,4,6,7,11,12,14,15-octaazaheptadekatrien-2,7,15 is observed, whereas in the gelatin-immobilized matrix, a complexing process in the system considered does not occur. 相似文献
17.
Adsorption, desorption and activities of acid phosphatase on various colloidal particles from an Ultisol 总被引:1,自引:0,他引:1
Adsorption, desorption and activity of acid phosphatase on various soil colloidal particles and pure clay minerals were studied. Higher adsorption amounts and low percentage of desorption of acid phosphatase were found on fine soil clays (<0.2 μm). Electrostatic force and ligand exchange are the major driving forces that are involved in the adsorption of enzymes on soil clays. More enzyme molecules were adsorbed on soil clays in the presence of organic components. However, enzymes on organic clays were more easily released. One-third of the enzyme on goethite was adsorbed via ligand exchange process. Some other interactions, such as van der Waals force, hydrophobic force and hydrogen bonding may be more important in the adsorption of enzyme on kaolinite and the enzyme in this system cannot be easily removed. Coarse clays (0.2–2 μm) and inorganic soil clays had higher affinities for enzyme molecules than fine clays and organic clays, respectively. The activity of enzyme bound on soil clays was inhibited and the thermal stability was increased in the presence of organic matter. Data obtained in this study are helpful for a better understanding of the interactions of enzymes with inorganic and organic constituents in soil and associated environments. 相似文献
18.
Syed Laik Ali 《Analytical and bioanalytical chemistry》1973,262(4):278-282
The different aspects of Vitamin D3 determination and the data reported in the literature are discussed. The spectrophotometric determination of Vitamin D3 in cod-liver oil is carried out after the alkaline saponification, extraction of unsaponified parts, precipitation of accompanying sterols and the column- and thin-layer chromatographic purification and separation of vitamin D3 on 40 cm plates from other vitamins. The dyestuff α-naphtholbenzein is suited well as standard substance for the better location and identification of vitamin D3 zone on the thin-layer plate. The results obtained from the chemical method were checked through the simultaneous biological determination. 相似文献
19.
Analytic expressions of the dyadic Green's function of an arbitrary electric current source embedded in a general biisotropic sphere are presented at first, and the radiation characteristics of an electric dipole antenna placed on the surface of a biisotropic sphere lens are examined. The effects of the electric-and the magnetic-coefficients (
e
and
m
) of biisotropic medium on the radiation patterns of electric dipole antenna are investigated in detail. 相似文献
20.
The self-assembled monolayer structure of the products of elaidic acid iodination (the racemic mixture of 9,10-(9S,10R)-diiodooctadecanoic acid and 9,10-(9R,10S)-diiodooctadecanoic acid) and the products of oleic acid iodination (the racemic mixture of 9,10-(9R,10R)-diiodooctadecanoic acid and 9,10-(9S,10S)-diiodooctadecanoic acid) are studied by high-resolution scanning tunneling microscopy. For the iodination products of elaidic acid, the separation of enantiomers into distinct chiral domains during the formation of the 2-D crystal on the highly ordered pyrolytic graphite (HOPG) surface is not observed. Instead, within the diiodooctadecanoic acid SAM, each row of molecules is composed of opposite racemates. The two opposite racemates pack alternately inside a row, using different faces to adsorb on the surface. The unit cell is composed of a pair of opposite racemates, forming a heterochiral structure. For the iodination products of oleic acid, the racemic mixture is observed to exhibit quasi-phase separation during the formation of the 2-D crystal on the HOPG surface. Each row is composed of homochiral acid molecules, either the 9,10-(9R,10R)-diiodooctadecanoic acid (R) or the 9,10-(9S,10S)-diiodooctadecanoic acid (S). The R row and the S row pack alternately, with a unit cell composed of four molecules. Two of the molecules in the unit cell are the 9,10-(9R,10R)-diiodooctadecanoic acid (R) molecules; two are the 9,10-(9S,10S)-diiodooctadecanoic acid (S) molecules. In the unit cell, the two molecules that have the same chirality pack antiparallel inside the homochiral row, using different faces to adsorb on the surface. These results suggest that several different types of chiral assembly are possible. Enantiomers with opposite chirality exhibit many chiral assembly patterns, forming heterochiral structures on the surface in addition to separation to form macroscopic chiral domains. By using different conformations, similar enantiomers with opposite chirality will display many chiral assembly patterns to form heterochiral structures on the surface. 相似文献