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61.
Stearic acid coated Bi2O3 nanoparticles in the size range of 5-13 nm were synthesized by the microemulsion method. HRTEM showed that the morphology of Bi2O3 nanoparticles was ellipsoidal. The absorption edge of Bi2O3 nanoparticles showed a blue shift of ∼0.45 eV, comparing with that of the bulk Bi2O3. At room temperature, Bi2O3 nanoparticles also showed a strong luminescence at 397 and 420 nm, depending on the excitation wavelength. 相似文献
62.
现代汽车中有一种先进的制动机构。可保证在制动时不是完全刹死滑行,而是让车轮仍有一定的滚动.经研究这种方法可以更有效地制动.防抱死系统有一个自动检测车速的装置,用来控制车轮的转动,其原理如图1,铁质齿圈P与车轮同步转动,右端有一个绕有线圈的磁体,G是一个电流检测器.当车轮带动齿轮转动时,由于齿靠近线圈时被磁化,使磁通量增强, 相似文献
63.
Yin Jingxue 《数学年刊B辑(英文版)》1991,12(4):500-519
This paper applies the compensated compactnessmethod to the study of a class of quasilinear parbolic equations of higher order with doubly strong degeneration. Some existence and uniqueness results are proved under certain conditions. 相似文献
64.
Cellulose carbamate, an environmentally friendly material presents an interesting alternative to petroleum-based polymers because of its renewable, biodegradable, biocompatible nature and its solubility in conventional solvents. In synthesis process of cellulose carbamate, urea was firstly impregnated into the cellulose pulp by supercritical CO2(scCO2), followed by the esterification of cellulose. The structure of cellulose carbamate was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The rheological properties of these cellulose carbamates in 9% sodium hydroxide solution were investigated, using a range of the nitrogen content, concentrations and shear rates. 相似文献
65.
Cu nanotube arrays were fabricated by electroless deposition using porous anodic aluminium oxide membranes as templates. This was accomplished by a four-step procedure, i.e. pore-wall modification, polishing treatment, sensitization-activation and electroless deposition. The as-synthesized Cu nanotubes possess controllable inner diameter and open ends. 相似文献
66.
Y.X. Yin 《Applied Surface Science》2006,253(3):1584-1589
Wear resistant Cu-based solid solution (Cuss) toughened Cr5Si3 metal silicide composite coatings were fabricated on austenitic stainless steel AISI321 by laser cladding process. Due to the rapidly solidified microstructural characteristics and the excellent toughening effect of Cuss on Cr5Si3, the Cuss/Cr5Si3 coatings have outstanding wear resistance and low coefficient of friction under room temperature dry sliding wear test conditions coupling with hardened 0.45% C steel. 相似文献
67.
Yan Yin Otoo Yamada Shunsuke Hayashi Kazuhiro Tanaka Hidetoshi Kita Ken‐Ichi Okamoto 《Journal of polymer science. Part A, Polymer chemistry》2006,44(12):3751-3762
A series of branched/crosslinked sulfonated polyimide (B/C‐SPI) membranes were prepared and evaluated as proton‐conducting ionomers based on the new concept of in situ crosslinking from sulfonated polyimide (SPI) oligomers and triamine monomers. Chemical branching and crosslinking in SPI oligomers with 1,3,5‐tris(4‐aminophenoxy)benzene as a crosslinker gave the polymer membranes very good water stability and mechanical properties under an accelerated aging treatment in water at 130 °C, despite their high ion‐exchange capacity (2.2–2.6 mequiv g?1). The resulting polymer electrolytes displayed high proton conductivities of 0.2–0.3 S cm?1 at 120 °C in water and reasonably high conductivities of 0.02–0.03 S cm?1 at 50% relative humidity. In a single H2/O2 fuel‐cell system at 90 °C, they exhibited high fuel‐cell performances comparable to those of Nafion 112. The B/C‐SPI membranes also displayed good performances in a direct methanol fuel cell with methanol concentrations as high as 50 wt % that were superior to those of Nafion 112. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3751–3762, 2006 相似文献
68.
Baijun Liu Gilles P. Robertson Michael D. Guiver Yi‐Ming Sun Yin‐Ling Liu Juin‐Yih Lai Serguei Mikhailenko Serge Kaliaguine 《Journal of Polymer Science.Polymer Physics》2006,44(16):2299-2310
A series of sulfonated poly(aryl ether ether ketone ketone)s statistical copolymers with high molecular weights were synthesized via an aromatic nucleophilic substitution polymerization. The sulfonation content (SC), defined as the number of sulfonic acid groups contained in an average repeat unit, could be controlled by the feed ratios of monomers. Flexible and strong membranes in sodium sulfonate form could be prepared by the solution casting method, and readily transformed to their proton forms by treating them in 2 N sulfuric acid. The polymers showed high Tgs, which increased with an increase in SC. Membranes prepared from the present sulfonated poly(ether ether ketone ketone) copolymers containing the hexafluoroisopropylidene moiety (SPEEKK‐6F) and copolymers containing the pendant 3,5‐ditrifluoromethylphenyl moiety (SPEEKK‐6FP) had lower water uptakes and lower swelling ratios in comparison with previously prepared copolymers containing 6F units. All of the polymers possessed proton conductivities higher than 1 × 10?2 S/cm at room temperature, and proton conductivity values of several polymers were comparable to that of Nafion at high relative humidity. Their thermal stability, oxidative stability, and mechanical properties were also evaluated. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2299–2310, 2006 相似文献
69.
Two novel dithienylethenes with ferrocene units were synthesized by Wittig reaction. The structure of 2a has been established by X‐ray diffraction studies. They could reversibly interconvert between two thermally stable forms, an open and a closed one, using light of different wavelengths as triggers. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
70.