Mass spectrum and strong decays of strangeonium in a constituent quark model

In this work we calculate the mass spectrum of strangeonium up to the 3D multiplet within a nonrelativistic linear potential quark model.Furthermore,using the obtained wave functions,we also evaluate the strong decays of the strangeonium states with the ^3P_0 model.Based on our successful explanations of the well established states φ(1020) , φ(1680) , h_1(1415) , f'_2(1525) ,and φ_3(1850) ,we further discuss the possible assignments of strangeonium-like states from experiments by combining our theoretical results with observations.It is found that some resonances,such as f_2(2010) and f_2(2150) ,listed by the Particle Data Group,and X(2062) and X(2500) ,newly observed by BESIII,may be interpreted as strangeonium states.The possibility of φ(2170) as a candidate for φ(3S) or φ(2D) cannot be excluded.We expect our results to provide useful references for looking for the missing s\bar{s} states in future experiments.     

Metastable Liquid Properties and Surface Flow Patterns of Ultrahigh Temperature Alloys Explored in Outer Space

The metastable liquid properties and chemical bonds beyond 2000 K remain a huge challenge for ground-based research on liquid materials chemistry. We show the strong undercooling capability, metastable liquid properties and surface wave patterns of refractory Nb−Si and Zr−V binary alloys explored in space environment. The floating droplet of Nb_82.7Si_17.3 eutectic alloy superheated up to 2338 K exhibited an extreme undercooling of 437 K, approaching the 0.2T_E threshold for homogeneous nucleation of liquid-solid reaction. The microgravity state endowed alloy droplets with nearly perfect sphericity and thus ensured the high accuracy to determine metastable undercooled liquid properties. A special kind of swirling flow was induced for liquid alloy owing to Marangoni convection, which resulted in the spiral microstructures on Zr₆₄V₃₆ alloy surface during liquid-solid phase transition. The coupled impacts of surface nucleation and surface flow brought in a novel olivary shape for these binary alloys. Furthermore, the chemical bonds and atomic structures of high temperature liquids were revealed to understand the liquid properties in outer space circumstances.     

先进高强度钢的断裂失效准则研究

先进高强度钢(AHSS)是通过相变获得高强度的应用前景最好的汽车轻量化材料.与传统深拉钢相比,AHSS韧性相对较低,在冲压成形过程中容易发生断裂,阻碍了它在汽车上的广泛应用,因而AHSS的断裂失效研究成为当前国内外研究的热点.论文以AHSS的代表钢种双相钢(DP)为研究对象,通过试验与数值计算相结合的方法研究其在不同三轴应力状态下的失效特性,尝试寻找一个适用于它的失效准则,用于其断裂失效的预测.     

拖曳线列阵管中校准方法研究

本文阐述了一种在长管中校准拖曳线列阵或其阵元组的方法,这种方法通过在线列阵上形成一个等效于其接收到一个任意角度入射的自由场平面坡时的声场分布来校准线列阵的复数灵敏度和远场指向性。在阐述了这种校准方法的基本原理以后。通过建立理论模型,用计算机模拟研究了该方法的可行性及校准声场偏差与各种参数之间的关系,并对其结论进行了实验验证。实验线列阵的方向性和灵敏度的测量结果表明,在低频情况下该方法是校准长线列阵的有效方法。     

Atomic defects,functional groups and properties in Mxenes

MXenes,a new family of functional two-dimensional(2 D) materials,have shown great potential for an extensive variety of applications within the last decade.Atomic defects and functional groups in MXenes are known to have a tremendous influence on the functional properties.In this review,we focus on recent progress in the characterization of atomic defects and functional group chemistry in MXenes,and how to control them to directly influence various properties(e.g.,electron transport,Li⁺ adsorption,hydrogen evolution reaction(HER) activity,and magnetism) of 2 D MXenes materials.Dynamic structural transformations such as oxidation and growth induced by atomic defects in MXenes are also discussed.The review thus provides perspectives on property optimization through atomic defect engineering,and bottom-up synthesis methods based on defect-assisted homoepitaxial growth of MXenes.     

Effect of Different Heat Treatments on the Quality and Flavor Compounds of Black Tibetan Sheep Meat by HS-GC-IMS Coupled with Multivariate Analysis

There are limited reports about the effect of different heat treatments on the quality and flavor of Black Tibetan sheep meat. The current study examined the effect of pan-frying, deep-frying, baking, and boiling treatment on the quality of Black Tibetan sheep meat; the amino acid, fatty acid, and volatile flavor compounds (VFCs) were investigated by a texture analyzer, ultra-high-performance liquid chromatography (UHPLC), gas chromatography (GC), and headspace-gas chromatography-ion mobility (HS-GC-IMS). The key VFCs were identified through orthogonal partial least squares discrimination analysis (OPLS-DA), and variable importance projection (VIP) values. In addition, Pearson’s correlations between meat quality parameters and key VFCs were examined. The sensory scores, including texture, color, and appearance, of baked and pan-fried meat were higher than those of deep-fried and boiled meat. The protein (40.47%) and amino acid (62.93 µmol/g) contents were the highest in pan-fried meat (p < 0.05). Additionally, it contained the highest amounts of monounsaturated and polyunsaturated fatty acids, such as oleic, linoleic, and α-linolenic acids (p < 0.05). Meanwhile, pan-fried and deep-fried meat had higher amounts of VFCs than baked meat. The OPLS-DA similarity and fingerprinting analyses revealed significant differences between the three heat treatment methods. Aldehydes were the key aroma compounds in pan-fried meat. Importantly, 3-methylbutyraldehyde and 2-heptanone contents were positively correlated with eicosenoic, oleic, isooleic, linoleic, α-Linolenic, and eicosadiene acids (p < 0.05). To sum up, pan-fried Black Tibetan sheep meat had the best edible, nutritional, and flavor quality.     

W波段扩展互作用速调管电子光学系统

W波段扩展互作用速调管电子光学系统由皮尔斯电子枪与均匀永磁聚焦系统组成,用于电子注的产生与传输。利用Vaughan迭代综合法及数值模拟优化设计了皮尔斯电子枪,并按照电子注传输特性要求研制了均匀永磁聚焦结构。根据电子光学系统的三维模拟,导流系数0.21 P,注电流大于0.5 A,注平均半径小于0.3 mm,射程大于11 mm。永磁聚焦磁场约0.33 T,传输距离大于50 mm,电子注通过率达到100%。电子枪与聚焦系统已加工完毕并通过测试,技术指标满足要求。     

Heterostructures with Built-in Electric Fields for Long-lasting Chemodynamic Therapy

Sustained signal activation by hydroxyl radicals (⋅OH) has great significance, especially for tumor treatment, but remains challenging. Here, a built-in electric field (BIEF)-driven strategy was proposed for sustainable generation of ⋅OH, thereby achieving long-lasting chemodynamic therapy (LCDT). As a proof of concept, a novel Janus-like Fe@Fe₃O₄−Cu₂O heterogeneous catalyst was designed and synthesized, in which the BIEF induced the transfer of electrons in the Fe core to the surface, reducing ≡Cu²⁺ to ≡Cu⁺, thus achieving continuous Fenton-like reactions and ⋅OH release for over 18 h, which is approximately 12 times longer than that of Fe₃O₄−Cu₂O and 72 times longer than that of Cu₂O nanoparticles. In vitro and in vivo antitumor results indicated that sustained ⋅OH levels led to persistent extracellular regulated protein kinases (ERK) signal activation and irreparable oxidative damage to tumor cells, which promoted irreversible tumor apoptosis. Importantly, this strategy provides ideas for developing long-acting nanoplatforms for various applications.     

Accelerated Transfer and Spillover of Carbon Monoxide through Tandem Catalysis for Kinetics-boosted Ethylene Electrosynthesis

Cu-based catalysts have been widely applied in electroreduction of carbon dioxide (CO₂ER) to produce multicarbon (C₂₊) feedstocks (e.g., C₂H₄). However, the high energy barriers for CO₂ activation on the Cu surface is a challenge for a high catalytic efficiency and product selectivity. Herein, we developed an in situ *CO generation and spillover strategy by engineering single Ni atoms on a pyridinic N-enriched carbon support with a sodalite (SOD) topology (Ni-SOD/NC) that acted as a donor to feed adjacent Cu nanoparticles (NPs) with *CO intermediate. As a result, a high C₂H₄ selectivity of 62.5 % and an industrial-level current density of 160 mA cm⁻² at a low potential of −0.72 V were achieved. Our studies revealed that the isolated NiN₃ active sites with adjacent pyridinic N species facilitated the *CO desorption and the massive *CO intermediate released from Ni-SOD/NC then overflowed to Cu NPs surface to enrich the *CO coverage for improving the selectivity of CO₂ER to C₂H₄.     

Reactivity Control of C?H Bond Activation over Vanadium–Silver Bimetallic Oxide Cluster Cations

Vanadium–silver bimetallic oxide cluster ions (V_xAg_yO_z⁺; x=1–4, y=1–4, z=3–11) are produced by laser ablation and reacted with ethane in a fast‐flow reactor. A reflectron time of flight (Re‐TOF) mass spectrometer is used to detect the cluster distribution before and after the reactions. Hydrogen atom abstraction (HAA) reactions are identified over VAgO₃⁺, V₂Ag₂O₆⁺, V₂Ag₄O₇⁺, V₃AgO₈⁺, V₃Ag₃O₉⁺, and V₄Ag₂O₁₁⁺ ions, in which the oxygen‐centered radicals terminally bonded on V atoms are active sites for the facile HAA reactions. DFT calculations are performed to study the structures, bonding, and reactivity. The reaction mechanisms of V₂Ag₂O₆⁺+C₂H₆ are also given. The doped Ag atoms with a valence state of +1 are highly dispersed at the periphery of the V_xAg_yO_z⁺ cluster ions. The reactivity can be well‐tuned gradually by controlling the number of Ag atoms. The steric protection due to the peripherally bonded Ag atoms greatly enhances the selectivity of the V–Ag bimetallic oxide clusters with respect to the corresponding pure vanadium oxide systems.