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11.
Characterizations of Tb:Zn2SiO4 films on silicon wafer prepared by sol-gel dip-coating and solid-phase reaction
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Terbium-doped Zn_2SiO_4 films were successfully prepared on Si wafers by a simple sol-gel dip-coating and solid-phase reaction method of ZnO and SiO_2. X-ray diffraction (XRD) and UV-Vis absorption results revealed that films processed below 850℃ were ZnO in wurzite structure, and films processed above 850℃ were Zn_2SiO_4 in wellimite structure. Photoluminescence measurements of the Tb-doped Zn_2SiO_4 films showed two strong emission bands at 490 and 545nm. The photoluminescence lifetime was 4.6ms. 相似文献
12.
Amorphous silver, copper, gold, and iron films of a thickness between 6 and 350 nm are grown on polymeric substrates by vacuum
evaporation. The nanostructure of the films is investigated. The dependence of the conductivity on the film thickness is obtained,
and a correlation between the surface morphology and the conductivity is established. 相似文献
13.
Chun‐Yan Hong Ye‐Zi You Cai‐Yuan Pan 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4873-4881
Well‐defined diblock and triblock copolymers composed of poly(N‐isopropylacrylamide) (PNIPAM) and poly(ethylene oxide) (PEO) were successfully synthesized through the reversible addition–fragmentation chain transfer polymerization of N‐isopropylacrylamide (NIPAM) with PEO capped with one or two dithiobenzoyl groups as a macrotransfer agent. 1H NMR, Fourier transform infrared, and gel permeation chromatography instruments were used to characterize the block copolymers obtained. The results showed that the diblock and triblock copolymers had well‐defined structures and narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight < 1.2), and the molecular weight of the PNIPAM block in the diblock and triblock copolymers could be controlled by the initial molar ratio of NIPAM to dithiobenzoate‐terminated PEO and the NIPAM conversion. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4873–4881, 2004 相似文献
14.
15.
V. Ye. Zaichick 《Fresenius' Journal of Analytical Chemistry》1995,352(1-2):219-223
The contents of 21 chemical elements (Ag, Br, Ca, Cl, Co, Cr, Cs, Fe, Hg, K, Mg, Mn, Na, P, Rb, Sb, Sc, Se, Sr, Zn, Zr) in synthetic reference materials (SRMs) were compared with those in natural reference materials (NRMs) using short- and long-lived radionuclides. SRMs called synthetic standards (SSs) and synthetic standards, biological (SSBs) were prepared on the basis of phenol-formaldehyde resol resins in the Institute of Physics, Georgian Academy of Science. The NRMs included such IAEA reference materials as H-4 (animal muscle), A-13 (animal blood), H-5 (animal bone), SL-1 (lake sediment), SOIL-7 (soil), A-9 (mixed human diet), and IAEA-153 (milk powder). It was shown that SSB-SRMs possessed good representativity of the 30–50 mg tablets, high precision, operational convenience, and could be recommended for the INAA of a wide range of medico-biological and bioecological objects. 相似文献
16.
J Z Hu R J Pugmire A M Orendt D M Grant C Ye 《Solid state nuclear magnetic resonance》1992,1(4):185-195
Taking advantage of the long 13C T1 values generally encountered in solids, selective saturation and inversion of more than one resonance in 13C CP/MAS experiments can be achieved by sequentially applying several DANTE pulse sequences centered at different transmitter frequency offsets. A new selective saturation pulse sequence is introduced composed of a series of 90 degrees DANTE sequences separated by interrupted decoupling periods during which the selected resonance is destroyed. Applications of this method, including the simplification of the measurement of the principal values of the 13C chemical shift tensor under slow MAS conditions, are described. The determination of the aromaticity of coal using a relatively slow MAS rate is also described. 相似文献
17.
Yong LU Hong WANG Ye LIU Ming Yuan HE 《中国化学快报》2006,17(10):1397-1400
Recently, miniature H2 generator to power fuel cells for portable/micro electronic devices and passenger propulsion has been the focus of intense research activities1-3. One of the strategies is to find simple CO-free H2 production with novel microreactor… 相似文献
18.
Fengfu Fu Liangjun Xu Wei Ye Yiquan Chen Mingyu Jiang Xueqin Xu 《中国颗粒学报》2006,4(6):323-326
Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a Scanning Electron Microscope equipped with an Energy Dispersive X-ray Spectrometer (SEM-EDX). The results indicate that most BC aerosols are spherical particles of about 50 nm in diameter and with a homogeneous surface. Results also show that these particles aggregate with other aerosols or with themselves to form larger agglomerates in the micrometer range. The shape of these 50-nm BC spherical particles was found to be very similar to that of BC particles released from petroleum-powered vehicular internal combustion engines. These spherical BC particles were shown to be different from the previously reported fullerenes found using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectrometry (MALDI-TOF-MS). 相似文献
19.
20.
1D-nanostructural zinc oxide (ZnO) with different shapes have been synthesized on p-type Si(1 0 0) and glass substrates via vapor phase growth by heating pure zinc powder at temperatures between 480 and 570 °C. The different ZnO nanostructures depend on the substrates and the growth temperatures. Scanning electron microscopy and X-ray diffraction revealed that a well-aligned nanowires array, which are vertical to the substrate of Si(1 0 0) with 18 sides on their heads, but six sides on their stems, has been formed at 480 °C. Raman study on the ZnO nanostructures shows that the coupling strength between electron and phonon determined by the ratio of the second- to the first-order Raman scattering cross-sections declines with decreasing diameter of the nanowires. However, a little changes of the coupling strength in terms of the width of the nanobelts have been observed. 相似文献