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951.
用常压MOCVD法在GaAs衬底上生长了Zn1-xCdxSe-ZnSe多层结构.通过X-射线衍射谱和光致发光等方法判断,表明该材料为多量子阱结构.从室温下的透射光谱上可以观察到这种多量子阱中的n=1的激子吸收峰,并观测到起因子激子的ns量级的光学双稳态. 相似文献
952.
Liao LA Zhang F Dmitrenko O Bach RD Fox JM 《Journal of the American Chemical Society》2004,126(14):4490-4491
A new type of parallel kinetic resolution (PKR) is reported in which quasienantiomers with very similar reactivities give products whose chromatographic properties diverge upon the addition of fluoride. This concept of a reactivity/affinity switch is applied to the PKR of cyclopropene carboxylic acids with all-carbon quaternary centers. This is the first application of alpha-amino acid quasienantiomers in PKR, and it is a complementary approach for acyltransfer systems where the asymmetry is induced by the nucleophile rather than the leaving group. Excellent diastereoselectivities (ranging from 90:10 to 99.5:5) and good yields were obtained for both quasienantiomeric products, and the reactions can be run on significant scale because the separation is trivial. High-level DFT calculations (B3LYP functional with the 6-31+G(d,p) basis set) provided transition-state structures with relative energies that are in accord with the experimental observations. 相似文献
953.
We report the observation of enhanced near-infrared transmission through arrays of subwavelength coaxial metallic structures compared with that through comparable diameter hole arrays as a result of localized electromagnetic modes supported by the complex coaxial unit cell. Polarization and angle-dependent transmission measurements clearly demonstrate the coupling between this localized mode and delocalized surface plasmon modes. A generalized, multiple discrete states Fano line shape provides a good fit to the experimental results. 相似文献
954.
We report the integration of inorganic nanotubes into metal-oxide-solution field effect transistors (FETs) which exhibit rapid field effect modulation of ionic conductance. Surface functionalization, analogous to doping in semiconductors, can switch the nanofluidic transistors from p-type to ambipolar and n-type field effect transistors. Transient study reveals the kinetics of field effect modulation is controlled by ion-exchange step. Nanofluidic FETs have potential implications in subfemtoliter analytical technology and large-scale nanofluidic integration. 相似文献
955.
The effects of repeating thickness periods on stress are studied in ZrO2/SiO2 multilayers deposited by electron-beam evaporation on BK7 glass and fused-silica substrates. The results show that the residual stress is compressive and decreases with an increase of the periods of repeating thickness in the ZrO2/SiO2 multilayers. At the same time, the residual stress in multilayers deposited on BK7 glass is less than that of samples deposited on fused silica. The variation of the microstructure examined by x-ray diffraction shows that microscopic deformation does not correspond to macroscopic stress, which may be due to variation of the interface stress. 相似文献
956.
Distinguishability and indistinguishability by local operations and classical communication 总被引:1,自引:0,他引:1
Fan H 《Physical review letters》2004,92(17):177905
It is well known that orthogonal quantum states can be distinguished perfectly. However, if we assume that these orthogonal quantum states are shared by spatially separated parties, the distinguishability of these shared quantum states may be completely different. We show that a set of linearly independent quantum states [formula: see text] where U(m,n) are generalized Pauli matrices, cannot be discriminated deterministically or probabilistically by local operations and classical communication. On the other hand, any l maximally entangled states from this set are locally distinguishable if l(l-1)< or =2d. The explicit projecting measurements are obtained to locally discriminate these states. As an example, we show that four Werner states are locally indistinguishable. 相似文献
957.
958.
Chiang CM Lu D Huang JT Hwang CC Cho CC Fan LJ Yang YW 《Journal of the American Chemical Society》2004,126(39):12242-12243
Fluorine-substituted ethyl groups on Cu(111) were generated by thermal scission of the C-I bond in the adsorbed C2F5I. Temperature-programmed reaction spectrometry observed a novel pathway resulting in the evolution of C4F6 above 400 K. Among the various isomers, this product was identified as hexafluro-2-butyne. Although abstraction of two fluorine atoms from the starting Cu-CF2CF3 was required, Cu-CCF3 (trifluoroethylidyne) was favored over Cu-CF=CF2 (trifluorovinyl) as the intermediate because this ethyl-ethylidyne-butyne pathway was suppressed on a Cu(100) surface devoid of the key threefold hollow binding sites for ethylidyne. Once formed, perfluoroethylidyne readily coupled to afford a tightly surface-bound hexafluoro-2-butyne up to 400 K. Therefore, the C-F bonds adjacent to the metal were found to be more susceptible to the bond activation, leading the chemisorbed perfluoroethyl to eliminate two F atoms successively from the alpha-carbon. This preference for alpha-elimination rather than beta-elimination (the most favorable route in hydrocarbons) may be quite general for metal surface-mediated reactions involving fluorinated alkyl groups. 相似文献
959.
J.B.?ShiEmail author Y.Y.?Fan P.H.?Peng F.C.?Jou C.Y.?Lee H.C.?Ku H.Z.?Chen S.L.?Young 《Applied Physics A: Materials Science & Processing》2004,78(3):411-414
In this paper we report the results of a detailed investigation of the double perovskite (Ca2-2xSr2x)FeMoO6 system. Chemical size effects on structural, electrical, and magnetic properties caused by the substitution of isovalent, larger Sr ions into the smaller Ca sites, resulting in (Ca2-2xSr2x)FeMoO6, have been examined. The compounds crystallize in the monoclinic space group P21/n for 0.0x<0.2, the orthorhombic space group Pbnm for 0.2x<0.4, and the tetragonal space group I4/m and I4/mmm for x0.4. Examination of the resistivity of all compounds reveals a metallic behavior which is well described by a Tn dependence except for x=1.0. These n values change from 1 to 2 as T decreases lower than Tc. This is indicative of a variation in the transport mechanism at Tc. The ferrimagnetic transition temperature Tc increases with increasing x from 318 (x=0.0) to 393 K (x=1.0). For all samples, the saturation magnetization at 82 K obeys Ms3.5B/(formula unit), compared to a theoretical spin-only moment of 4B/(formula unit) for a perfectly ordered compound. PACS 74.25.Fy; 74.25.Ha 相似文献
960.
Fabrication of alternating polycation and albumin multilayer coating onto stainless steel by electrostatic layer-by-layer adsorption 总被引:1,自引:0,他引:1
Ji J Tan Q Fan DZ Sun FY Barbosa MA Shen J 《Colloids and surfaces. B, Biointerfaces》2004,34(3):185-190
Multilayer films consisting of polyethylenimine (PEI) and albumin were successfully prepared on biomedical 316L stainless steel surface via electrostatic self-assembly of the PEI and albumin. The process of electrostatic self-assembly of PEI/albumin was monitored by125I radiolabeling, electrochemical impedance spectroscopy (EIS) and atomic force microscopy (AFM). The EIS data revealed that the multilayer coating was stable in Tris-HCl (pH 7.35) buffer solution for 21 days. 125I radiolabeling experiments indicated that less than 10% albumin was eluted by PBS in 45 days. Static platelet adhesion experiments indicated that the PEI/albumin deposited on stainless steel could resist platelet adhesion effectively. Such an easy processing and shape-independent method may have good potential for surface modification of cardiovascular devices. 相似文献