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941.
Lei Zhang Wei Tong Jiyu Fan Changjin Zhang Renwen Li Yuheng Zhang 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,83(3):325-328
Ferrimagnetic spinel selenide CuCr2Se4 has been investigated by the
electron spin resonance (ESR) spectroscopy. Experimental results reveal that ESR signals
originate from the localized d-shell electrons of Cr3+ ions.
In addition, the ESR linewidth ΔH
PP
increases
linearly with decreasing temperature. It is suggested that the spin-orbit coupling may be
one of the contributions to the broadening of
ΔH
PP
. Our ESR results support the model of
the ferrimagnetic hybridization between localized 3d
3
electrons of Cr3+ with delocalized holes of Se 4p band. 相似文献
942.
<正>PTPMEG1 is an intracellular protein tyrosine phosphatase(PTP),which contains FERM and PDZ domains. This study focuses our attention on the expression,purification and characterization of catalytic domain of PTPMEG1(△MEG1) and preparation of its polyclonal antibody.A cDNA fragment encoding△MEG1 protein(amino acid residues 643—926) was amplified by PCR and then cloned into the pT7-7 vector.Both soluble and insoluble recombinant△MEG1 proteins were observed after induction by IPTG.Soluble△MEG1 was purified via two chromatographic steps,and the purified enzyme was characterized.With para-nitrophenylphosphate(pNPP) as a substrate,△MEG1 exhibited typical enzymatic characteristics of classic PTPs and classical Michaelis-Menten kinetics.Insoluble△MEG1,which was mainly distributed in the inclusion body of E.coli cells extracts,was purified by preparative electrophoresis gel for the preparation of the polyclonal antibody.A rabbit was immunized with△MEG1 purified by preparative electrophoresis to generate anti-△MEG1 antibody.Anti-serum was collected on 28th day after initial injection and purified via affinity chromatography.The purified polyconal antibody displayed a satisfactory titer and sensitivity. 相似文献
943.
Kinetic Resolution of Racemic Allylic Alcohols by Catalytic Asymmetric Substitution of the OH Group with Monosubstituted Hydrazines
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Liang Yan Jing‐Kun Xu Chao‐Fan Huang Zeng‐Yang He Ya‐Nan Xu Prof. Dr. Shi‐Kai Tian 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(37):13041-13045
A new strategy has been established for the kinetic resolution of racemic allylic alcohols through a palladium/sulfonyl‐hydrazide‐catalyzed asymmetric OH‐substitution under mild conditions. In the presence of 1 mol % [Pd(allyl)Cl]2, 4 mol % (S)‐SegPhos, and 10 mol % 2,5‐dichlorobenzenesulfonyl hydrazide, a range of racemic allylic alcohols were smoothly resolved with selectivity factors of more than 400 through an asymmetric allylic alkylation of monosubstituted hydrazines under air at room temperature. Importantly, this kinetic resolution process provided various allylic alcohols and allylic hydrazine derivatives with high enantiopurity. 相似文献
944.
945.
Wang Xiaobo Ma Yongpeng Li Zhenxing Han Guanglu Guan Xidong Fan Kaiqi 《Journal of Applied Spectroscopy》2022,89(3):586-592
Journal of Applied Spectroscopy - A multi-ion chromogenic sensor based on a terpyridine moiety was developed for the semiquantitative, visual, and sensitive speciation analysis of Fe2+ and Co2+... 相似文献
946.
A new Hash function based on the generalized Henon map is proposed. We have obtained a binary sequence with excellent pseudo-random characteristics through improving the sequence generated by the generalized Henon map, and use it to construct Hash function. First we divide the message into groups, and then carry out the Xor operation between the ASCII value of each group and the binary sequence, the result can be used as the initial values of the next loop. Repeat the procedure until all the groups have been processed, and the final binary sequence is the Hash value. In the scheme, the initial values of the generalized Henon map are used as the secret key and the messages are mapped to Hash values with a designated length. Simulation results show that the proposed scheme has strong diffusion and confusion capability, good collision resistance, large key space, extreme sensitivity to message and secret key, and it is easy to be realized and extended. 相似文献
947.
This paper theoretically studies the double-pumped fibre-optical parametric amplifiers (FOPAs) in photonic crystal fibres. Two distinct working regimes of FOPAs are researched, which depend on the dispersion at the central wavelength of the two pumps. Extremely broad tuning range can be obtained when the central pump wavelength is in the normal dispersion regime and is insensitive to the wavelength separation between the two pumps, while the tuning range is narrow in the anomalous dispersion regime and can be significantly enhanced by increasing the wavelength separation. Impacts of higher-order dispersions and temporal walk-off on the gain spectra are also discussed. 相似文献
948.
In this paper, a new type of resonant Brewster filters (RBF) with surface relief structure for the multiple channels is first presented by using the rigorous coupled-wave analysis and the S-matrix method. By tuning the depth of homogeneous layer which is under the surface relief structure, the multiple channels phenomenon is obtained. Long range, extremely low sidebands and multiple channels are found when the RBF with surface relief structure is illuminated with Transverse Magnetic incident polarization light near the Brewster angle calculated with the effective media theory of sub wavelength grating. Moreover, the wavelengths of RBF with surface relief structure can be easily shifted by changing the depth of homogeneous layer while its optical properties such as low sideband reflection and narrow band are not spoiled when the depth is changed. Furthermore, the variation of the grating thickness does not effectively change the resonant wavelength of RBF, but have a remarkable effect on its line width, which is very useful for designing such filters with different line widths at desired wavelength. 相似文献
949.
分布在弱电介质溶液中的电磁力(Lorentz力),可以有效地控制边界层的流动.利用以转动水槽为主的实验系统和基于双时间步Roe格式的数值方法,对翼型绕流的电磁控制进行了实验和数值研究.结果表明,对于一定攻角的翼型,电磁力可以控制其绕流形态.当电磁力方向与流动方向相同时,可以抑制分离,消除涡街,其效果与减小攻角类似.当电磁力的方向与流动方向相反时,可在流场中形成大涡组成的涡街,增强流体的混合能力,其效果与增大攻角类似. 相似文献
950.
We report a high-power thin Nd:YAG slab laser with slab dimension of 1 × 10 ×60 (mm) partially edgepumped by diode laser arrays. Passive Q-switching is achieved with a Cr^4+ :YAG microchip adopted as the saturable absorber mirror. The pulse duration is around 10 ns while the pulse repetition rate is higher than 10 kHz. The average output power of 70 W is obtained with a slope efficiency of 36%. The diffraction limited beam quality in the thickness direction is obtained by controlling the pump beam diameter inside the slab. The laser head is very compact with size of only 60 × 74×150 (mm). 相似文献