Spectroscopic Properties and Electronic Structure of (L-Glutamato)(2, 2′-Bipyridine) copper(II)

Cu(L-glu)(bpy)(L-glu = L-glutamato; bpy = 2, 2′-bipyridine) was prepared. Its electronic absorption spectrum and photoacoustic spectrum were recorded at room temperature. They were compared with each other and compared quantitatively with ligand field theory(LFT) and the radical wave function of non-free ions^[1–3]. Therefore, the electronic structure was also investigated with its spectrum behaviors and PLFT^[1–3].     

Spectroscopic and Binding Properties of Berberine to DNA and Its Application to DNA Detection

Berberine(BER) binds to the double helical DNA with a high affinity There is only a much smaller hypochromism and no shifts in the absorption spectra when BER binds to calf thymus DNA(CT DNA) The fluorescence yields increase dramatically when BER binds to DNA, with no shifts in the emission maximum. These spectral changes are in contrast to the behavior observed with many fluorescent intercalates Groove binding rather than intercalation was suggested to be the cause of these spectral changes. Consistent with groove binding, for polyamide anion quenching studies showed that the magnitude of K_sv of the bound BER was higher than that of the free BER. The addition of salt to the solution releases the DNA-bound drug action from the groove and causes a decrease in the fluorescence yield. The results of all above studies proved the groove binding of BER to DNA. The large fluorescence enhancements observed when BER binds to DNA and the poor fluorescence yield of BER in the absence of DNA can be used for sensitive detection of DNA The linear concentration range was 0–20μg/ml The limit of detection for CT DNA was 12 ng/ml     

A Direct Experimental Evidence of Collective Electron Resonance Mechanism of Surface Enhanced Infrared Spectroscopy (Seirs)

Abstract

We report here the preliminary results of the surface enhanced transmission infrared spectra of CH₃(CH₂)₇Azo(CH₂)₃COOH monolayers on CaF₂ substrate which was coated by silver island films with different size and distribution. The larger enhancement of absorbance of v(C=O) in COOH residing between silver island gap and small enhancement of absorbance of vibration mode of COO^? located on the silver islands are observed. It give us a direct experimental evidence of the collective electron resonance mechanism of surface enhance infrared spectroscopy (SEIRS), i.e. the decrease of the electromagnetic (EM) coupling reduces the enhancement factor of SEIRS.     

A theoretical and experimental study on all-normal-dispersion Yb-doped mode-locked fiber lasers

We report on a theoretical and experimental study of an all-normal-dispersion (ANDi) Yb-doped mode-locked fiber laser, in which nonlinear polarization rotation (NPR) is used to realize mode-locking without any dispersion compensation. Based on the coupled nonlinear Schrdinger (CNLS) equation, a model simulating the mode-locked process of an allnormal-dispersion ring fiber laser is developed, which shows that the achievement of stable mode-locking depends on the alignment of the polarization controller (PC) along the fast-polarization axis of the fiber, the birefringence intensity, and the net cavity dispersion. According to the theoretical analysis, stable mode-locked pulses with pulse duration 300 ps and average output power 33.9mW at repetition rate 36MHz are obtained.     

A Novel “Turn On” Glucose-Based Rhodamine B Fluorescent Chemosensor for Mercury Ions Recognition in Aqueous Solution

A novel “turn-on” fluorescent sensor based on glucose and rhodamine B for detection of mercury ions was designed and synthesized. The fluorescent sensor showed an extreme specificity for mercury ions than for other metal ions in aqueous solution. On adding mercury ions to the solution of glucose-based rhodamine B sensor, the absorption and fluorescence signals enhanced remarkably at 567 and 587 nm, respectively. Titration of sensor with mercury ions showed 1:1 stoichiometric reaction. The cyclic voltammetric measurement of an increasing amount of mercury ions in the solution of glucose-based rhodamine B sensor commendably showed the change in the fluorescence characteristics. Furthermore, the successful detection of trace amount of mercury ions in water indicated that glucose-based rhodamine B sensor can be used for the detection of the limited mercury ions in drinking water.     

Multifunctional Small Molecule Fluorophore for Long‐Duration Tumor‐Targeted Monitoring and Dual Modal Phototherapy

In this work, a specific tumor‐targeted small molecular fluorophore for synchronous long‐duration cancer imaging, photodynamic therapy, and photothermal therapy is synthesized. This novel fluorophore exhibits specific targeting ability in certain tumors (U87MG, MDA‐MB‐231, A549, etc.) based on its inherent structure and efficiently generates local hyperthermia and reactive oxygen species simultaneously for imaging‐guided precise cancer therapy combining the photothermic and photodynamic effects under laser irradiation. Meanwhile, compared to traditional near infrared fluorophore, this novel fluorophore with significantly enhanced stability against photobleaching can prolong the time of tumor imaging and improve the phototherapy efficiency. This work presents a potential strategy to develop small‐molecule‐based cancer theranostic agents for simultaneous cancer targeting, imaging, and therapy.     

Theoretical and Experimental Study of the Diffraction Intensity of Gradient Refractive-Index Lenses

We develop the wave-optics approach for calculating the diffraction distribution of gradient refractiveindex lenses and observing the diffraction pattern of gradient refractive-index lenses in the experiments. The results of our calculation are in good agreement with the experimental results obtained. We show that the diffraction can be regarded as a method to check the quality of the refractive-index distributions of gradient refractive-index lenses.     

High-lying excited states in <Superscript>10</Superscript>Be from the <Superscript>9</Superscript>Be(<Superscript>9</Superscript>Be,<Superscript>10</Superscript>Be)<Superscript>8</Superscript>Be reaction

A transfer-reaction experiment of ⁹Be(⁹Be, ¹⁰Be)⁸Be was performed at a beam energy of 45 MeV. Excited states in ¹⁰Be up to 18.80 MeV are produced using missing mass and invariant mass methods. Most of the observed high-lying resonant states, reconstructed from the α + ⁶He and t + ⁷Li decay channels, agree with the previously reported results. In addition, two new resonances at 15.6 and 18.8 MeV are identified from the present measurement. The 18.55 MeV state is found to decay into both the t + ⁷Li_g.s. and t + ⁷Li* (0.478 MeV) channels, with a relative branching ratio of 0.93 ± 0.33. Further theoretical investigations are encouraged to interpret this new information on cluster structure in neutron-rich light nuclei.     

A piperidinium-based ester-functionalized ionic liquid as electrolytes in Li/LiFePO<Subscript>4</Subscript> batteries

A new functionalized ionic liquid (IL) based on cyclic quaternary ammonium cations with ester group and bis(trifluoromethanesulfonyl)imide ([TFSI]^?) anion, namely, N-methyl-N-methoxycarbonylpiperidinium bis(trifluoromethanesulfonyl)imide ([MMOCPip][TFSI]), was synthesized and characterized. Physical and electrochemical properties, including Li-ion transference number, ionic conductivity, and electrochemical stability, were investigated. The electrochemical window of [MMOCPip][TFSI] was 6 V, which was wide enough to be used as a common electrolyte material. The Li-ion transference number of this IL electrolyte containing 0.1 M LiTFSI was 0.56. The half-cell tests indicated that the [MMOCPip][TFSI] obviously improved the cyclability of a Li/LiFePO₄ cell. For the Li/LiFePO₄ half-cells, after 20 cycles at room temperature at 0.1 C, the discharge capacity was 109.7 mAh g^?1 with 98.7% capacity retention in the [MMOCPip][TFSI]/0.1 M LiTFSI electrolyte. The good electrochemical performance demonstrated that the [MMOCPip][TFSI] could be used as electrolyte for lithium-ion batteries.     

多面转镜激光器扫频光学相干层析成像系统的全光谱重采样方法

在多面转镜激光器扫频光学相干层析成像系统中,激光器存在着输出光谱错位与扫频范围波动的问题.目前的重采样方法中,普遍利用互相关运算校正光谱错位,并进行大范围的截取,保证扫频范围的一致性,但这会导致成像信噪比与分辨率的降低.本文用马赫-曾德尔干涉仪(MZI)采集到的干涉信号对扫频范围波动的问题进行了详细的测量与分析,其中干涉信号的解缠相位曲线的非随机性和平行性,表明该类激光器输出光谱的波长分布具备一致性.在此基础上,提出了一种用最长扫频范围的MZI干涉信号,对样品干涉信号进行时域光谱对齐、然后进行一对多插值的重采样方法.实验与分析表明,该方法利用了所有的光谱信号,保证了样品干涉信号的能量利用率,能有效提高图像的信噪比与分辨率.