A Novel Aluminum-Based Metal-Organic Framework with Uniform Micropores for Trace BTEX Adsorption

Metal-organic frameworks (MOFs) are potential porous adsorbents for benzene, toluene, ethylbenzene and xylene (BTEX). A novel MOF, using low toxic aluminum (Al) as the metal, named as ZJU-620(Al), with uniform micropore size of 8.37±0.73 Å and specific surface area of 1347 m² g⁻¹, was synthesized. It is constructed by one-dimensional rod-shaped AlO₆ clusters, formate ligands and 4,4′,4′′-(2,4,6-trimethylbenzene-1,3,5-triyl) tribenzoic ligands. ZJU-620(Al) exhibits excellent chemical-thermal stability and adsorption for trace BTEX, e.g., benzene adsorption of 3.80 mmol g⁻¹ at P/P₀=0.01 and 298 K, which is the largest one reported. Using Grand Canonical Monte Carlo simulations and Single-crystal X-ray diffraction analyses, it was observed that the excellent adsorption could be attributed to the high affinity of BTEX molecules in ZJU-620(Al) micropores because the kinetic diameters of BTEX are close up to the pore size of ZJU-620(Al).     

Stable sodium-ion battery anode enabled by encapsulating Sb nanoparticles in spherical carbon shells

Journal of Solid State Electrochemistry - Antimony (Sb) has been recognized as one of the most promising metal anode materials for sodium-ion batteries, owing to its high capacity and suitable...     

CO2 Aggregation on Monoethanolamine: Observations from Rotational Spectroscopy

The initial stages of the gas-phase nucleation between CO₂ and monoethanolamine were investigated via broadband rotational spectroscopy with the aid of extensive theoretical structure sampling. Sub-nanometer-scale aggregation patterns of monoethanolamine-(CO₂)_n, n=1–4, were identified. An interesting competition between the monoethanolamine intramolecular hydrogen bond and the intermolecular interactions between monoethanolamine and CO₂ upon cluster growth was discovered, revealing an intriguing CO₂ binding priority to the hydroxyl group over the amine group. These findings are in sharp contrast to the general results for aqueous solutions. In the quinary complex, a cap-like CO₂ tetramer was observed cooperatively surrounding the monoethanolamine. As the cluster approaches the critical size of new particle formation, the contribution of CO₂ self-assembly to the overall stability increases.