Swelling behavior of polyethylenimine-cobalt complex in water

Polyethylenimine (PEI) was cross-linked by polyepichlorohydrin (PECH) and the swelling behavior of cross-linked PEI-Co complex membranes in water was studied. The equilibrium swelling ratio of PEI-Co complex membranes is lower and the swelling rate is slower than that of cross-linked PEI membranes without cobalt ion complexation. Both the equilibrium swelling ratio and swelling rate of PEI-Co complex membranes increase with increasing the molar ratio of PEI to PECH. The equilibrium swelling ratio of PEI-Co complex membranes remains almost constant with the change of the membrane thickness or temperature. The diffusion mechanism of water through PEI-Co complex membranes was also discussed, and it is found that the diffusion of water primarily obeys Fickian’s law, and the activation energy of diffusion is calculated to be 40.4 kJ/mol.     

控制两相邻结构地震动响应的Maxwell模型流体阻尼器优化参数研究

运用被动连接单元减小相邻结构的振动被证明是一种行之有效的手段。将两相邻结构简化为两单自由度体系,用Maxwell模型模拟连接两相邻结构的流体阻尼器,分别导出了在地面白噪声激励下主结构平均振动能量最小或两相邻结构总平均振动能量最小这两个控制目标下流体阻尼器优化参数的一般表达式,该优化参数仅与两相邻结构的相对自振频率和相对质量有关,也讨论了两相邻结构的相对自振频率和相对质量对控制效果的影响。最后,运用具有不同相对参数的三类相邻结构在El Centro 1940 NS地震波作用下时域响应的数值结果说明了这种被动优化流体阻尼器能够非常有效地减小在地震作用下两相邻结构的振动响应。     

The effect of plating on magnetron sputtering: Residual stress and scratch behavior of Au/NiCr/Ta multi-layers

Au/NiCr/Ta multi-layers were deposited on Al₂O₃ substrate by magnetron sputtering and plating. The effect of plating technique on magnetron sputtering film in residual stress, crystal orientation and scratch resistance behavior was investigated. The all magnetron sputtering and plating films were highly textured with dominant Au-(1 1 1) orientation or a mixture of Au-(1 1 1) and Au-(2 0 0) orientation and the (1 1 1)/(2 0 0) intensity ratio were increased after plating. The residual stress in magnetron sputtering films at different substrate temperature was tensile stress with 155-400 MPa and it decreased approximately to 50 MPa after plating. The scratch resistance could be affected by the film thickness, and it increased approximately linearly with the increase of the thickness of metallic films after plating.     

Microstructure and electrical properties of (Zr, Sn)TiO4 thin film deposited on Si(1 0 0) using a sol-gel process

Polycrystalline zirconium tin titanate (Zr_0.8Sn_0.2TiO₄, ZST) thin films with thickness of 81 nm were deposited successfully along the (1 0 0) on a p-type Si substrate by an improved sol-gel method. The deposited films were crystallized when annealing temperature was up to 450 °C. The thickness and compositions of the interface layer between the ZST films and Si substrate were identified by high-resolution transmission electron microscope (HRTEM). The electrical properties such as leakage current density, flat-band voltage and capacitance of the films were measured and discussed. Furthermore, the mechanism of the leakage current was also investigated.     

PECVD a-SiNx:H薄膜中的氢分布

用红外光谱、质子核磁共振谱对以SiH₄/NH₃/N₂混合气体为源、用等离子体增强化学气相淀积法淀积的非晶氢化氮化硅(a-SiNx:H)薄膜进行了分析,结果表明膜中H以Si-H和N-H形式存在,均呈集聚和疏散两种分布状态,衬底温度影响氢的总量和分布均匀性,射频功率显著影响[N-H]/[Si-H],退火后氢仍呈集聚和疏散两种分布.     

一种自适应容错控制方法

提出了一种基于分布估计的自适应容错控制方法．该方法利用随机参数模型，并在建立自适应容错控制算法时将随机参数的概率分布估计引入控制系统性能指标，解决了系统运行模态参数不确定和系统运行模态变化不确定的问题．计算机仿真结果表明该方法可以对故障系统进行有效地容错控制     

One-pot sequential Baylis-Hillman and Michael reactions

A new one-pot procedure for the sequential Baylis-Hillman and Michael reactions has been developed to construct two carbon-carbon bonds with three components. This procedure has been applied to combine a variety of aromatic aldehydes, β-unsubstituted acrylates and activated methide nucleophiles to generate highly diversified and functionalized organic compounds.     

On the Crystal Structure of [Cu(OH)_2(H_2O)_2(4-C_5H_4NCOOH)_2]

In their report of the crystal structure of the compound claimed to be [Cu(OH)2(H2O)2(4- C5H4NCOOH)2], the authors did not give any experimental details on the location and refinement of the water and hydroxyl hydrogen atoms[1]; they had assumed the presence of the carboxylic -CO2H unit on the basis of the infrared stretching frequency at 1700 cm-1 that is only of medium intensity. The cell constants for the compound are, in fact, identical, with those documented for tetraaquabis(isonicot…