首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   158篇
  免费   22篇
  国内免费   30篇
化学   113篇
力学   10篇
综合类   7篇
数学   34篇
物理学   46篇
  2023年   4篇
  2022年   8篇
  2021年   4篇
  2020年   7篇
  2019年   2篇
  2018年   6篇
  2017年   5篇
  2016年   10篇
  2015年   13篇
  2014年   4篇
  2013年   6篇
  2012年   22篇
  2011年   17篇
  2010年   12篇
  2009年   6篇
  2008年   5篇
  2007年   8篇
  2006年   6篇
  2005年   5篇
  2004年   10篇
  2003年   8篇
  2002年   6篇
  2001年   4篇
  2000年   4篇
  1999年   4篇
  1998年   2篇
  1997年   7篇
  1996年   3篇
  1995年   3篇
  1994年   1篇
  1993年   1篇
  1990年   1篇
  1989年   2篇
  1987年   2篇
  1986年   2篇
排序方式: 共有210条查询结果,搜索用时 15 毫秒
61.
In this paper, we are able to establish two localized results on the conjecture that each large integer congruent to 4 modulo 24 can be written as the sum of four squares of primes. The proof is based on the new estimates for exponential sums over primes in short intervals and a technique to get the asymptotic formula on the enlarged major arcs in the circle method. This work is supported by the National Natural Science Foundation of China (Grant Nos. 10701048 and 10771127).  相似文献   
62.
Let Δ(a, b; x) denote the error term of the asymmetric two-dimensional divisor problem. In this paper we shall study the relation between the discrete mean value ?nT D2(a,b;n){\sum_{n\leq T} \Delta^2(a,b;n)} and the continuous mean value ò1TD2(a,b;x)dx{\int_1^T\Delta^2(a,b;x)dx} .  相似文献   
63.
For any subset , we introduce the definition of -numbers, which contains the well-known k-free numbers, k-full numbers, k-full and l-free numbers (k<l–1) as special cases. In this paper we study the distribution of -numbers in short intervals. We establish the connection of this problem with the gap problem of k-free numbers and multi-dimensional divisor problems. As applications, we study the short interval distribution of k-full and l-free numbers for k=2, 3, 4, 5, 6, 7.Received June 4, 2002; in revised form January 22, 2003 Published online June 30, 2003  相似文献   
64.
本文用红外光谱分析了聚氯乙烯(PVC)和氯化聚氯乙烯(CPVC)的分子结构,用电导法评价了它们的热稳定性. 试料 PVC系天津化工厂生产,XS-7型;CPVC系前者的氯化产品,由安徽化工研究所提供,含氯量64%,日本产CPVC,牌号H827,含氯量68.5%.  相似文献   
65.
A composite of polyaniline (PANI) with both conducting and ferromagnetic functions was synthesized by a chemical method proposed by the authors. For the electrical properties, its room-temperature conductivity was measured to be about 10−1 S/cm when doped with 1.0M HCl, and it is independent of the preparation conditions, such as reaction temperature and concentration of FeSO4 solution. Temperature dependence of the conductivity of the composites at temperature between 77 and 450 K is controlled by thermal activation and dedoping processes, which result in the decrease of conductivity with increase of temperature as T > 320 K. For their magnetic properties, unusual ferromagnetic properties with high saturated magnetization (M2) and lower coercive force (Hc = 0) were observed. An effect of the preparation conditions on the ferromagnetic properties of composites was observed. The higher the reaction temperature and the concentration of FeSO4 solution, the higher the saturated magnetization was observed. No hysteresis feature (i.e. Hc = 0) for any PANI composites synthesized in this paper was observed, and this is independent of the preparation conditions. This may be attributed to the nanometer size of the magnetic particles existing in composites. Thus, it suggests that the doping of PANI leads to electrical properties of composites, whereas the nanocrystalline magnetic particles (Fe3O4) are responsible for the observed ferromagnetic properties of PANI composites. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35 : 2129–2136, 1997  相似文献   
66.
A series of blends consisting of polylactic acid (PLA) and aliphatic succinate polyester (Bionolle#3000) have been prepared. The results of the mechanical property investigation have shown that using more than 20 wt % Bionolle#3000 can significantly increase the toughness of the PLA, increase the elongation at break (more than 200%) and increase the impact strength (more than 70 J/m). These properties were not significantly affected by the aging behavior of PLA for more than two months. DMA results show that Bio#3000 reduces the elastic modulus of the blends between −15°C and 60°C. Soil degradation rates of the PLA/Bio#3000 blends also increase with increasing Bio#3000 content. However, for the blends with less than 30 wt % of Bio#3000, the degradation rates do not significantly increase. Enzymatic degradation rates of the blends are higher than for those of the two polymers, and these rates increase with increasing PLA content. Composting biodegradation rates increase with increasing Bio#3000 content.  相似文献   
67.
原子连接次序的一些经验规则   总被引:1,自引:0,他引:1  
张文广 《化学教育》2001,22(12):39-40
在有关物质分子结构的教学中 ,经常有学生问起一些类似这样的问题 :(1)次磷酸H3PO3与PF3是等电子体 ,H3PO3为什么具有 POHO OHH的四面体结构而不与PF3相似呈 P··HO OHOH的三角锥结构(2种结构式中的P都为 + 3氧化态 ,都是sp3杂化 ) ;(2 )N2 O为什么具有线性的··N—N—O· · ··· ·· ···结构 (方框表示π4 3键 ) ,但具有同样线性和键级的结构··N—O—N· ·· ·· ·· ···却不存在 (2种结构式中中心原子的N、O均为sp杂化 ) ;(3)CO与HCN也相当于等电子体 ,CO的结构…  相似文献   
68.
大部分工程实际粗糙表面符合非高斯分布,并对齿轮接触副润滑特性有重要影响.将渐开线齿轮啮合过程中齿面接触等效为三维无限长线接触,建立了一个可分析直齿轮和斜齿轮的混合弹流润滑计算模型;采用基于快速傅里叶变换的数值仿真方法生成给定参数的非高斯粗糙表面;运用该模型对直齿轮和斜齿轮啮合过程进行分析,求得不同表面粗糙度特征齿轮在各个啮合点的油膜厚度、接触区载荷以及接触区比例的情况.结果表明:对于标准差相等的非高斯粗糙表面,偏度值对齿轮润滑状况的影响与工况紧密相关,在润滑良好的条件下,偏度值越小润滑状况越优;润滑恶劣的条件下,偏度值越大润滑状况越优;而在各种工况下,峰度值对齿轮润滑状况的影响都表现出峰度值越大润滑状况越优的特点.  相似文献   
69.
Using first-principles total-energy calculations, we show that an adatom can easily climb up at monatomic-layer-high steps on several representative fcc metal (110) surfaces via a place exchange mechanism. Inclusion of such novel adatom ascending processes in kinetic Monte Carlo simulations of Al(110) homoepitaxy as a prototypical model system can lead to the existence of an intriguing faceting instability, whose dynamical evolution and kinetic nature are explored in comparison with experimental observations.  相似文献   
70.
For fixed k3, let It is known that the asymptotic formula holds for some constant ck. Let Ek(x)=Rk(x)–ckx2/k. We cannot improve the exponent 1/k at present if we do not have further knowledge about the distribution of the zeros of the Riemann Zeta function (s). In this paper, we shall prove that if the Riemann Hypothesis (RH) is true, then Ek(x)=O(x4/15+), which improves the earlier exponent 5/18 due to Nowak. A mean square estimate of Ek(x) for k6 is also obtained, which implies that Ek(x)=(x1/k–1/k2) for k6 under RH.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号