(a,a,b)型三维除数问题余项的平方积分均值(英文)

本文研究了当b>a≥2,(a,b)=1时,(a,a,b)型三维除数问题余项的平方积分均值,得到了相应的渐近公式,且该渐近公式当b>2a时成立.     

炭黑吸附法制备掺杂镨TiO2纳米粉体及其光催化性能

以硝酸镨为掺杂的前驱物,钛酸异丙酯为TiO2的前驱物,通过炭黑吸附高温水热法制得掺杂镨的量为0.07%的纳米Pr3+/TiO2粉体。分别采用热重/差热分析(TG-DTA)、X射线衍射(XRD)、扫描电镜(SEM)、紫外可见分析(UV-VIS)和比表面积吸附(BET)对不同焙烧温度下所得粉体的物相、颗粒度、分散性及光吸收性能进行表征和分析。实验结果表明:炭黑的吸附阻止了粉体在干燥和煅烧阶段的团聚和烧结,制得的Pr3+/TiO2纳米粉体团聚较少,呈现良好的分散性,颗粒均匀,经500℃焙烧,得到纳米粉体平均颗粒直径为18 nm,比表面积为78.08 g.m-2。光催化降解实验表明,炭黑吸附后TiO2的光催化活性在一定时间内比没有炭黑的提高了将近2倍,在紫外灯照射下Pr3+/TiO2能在60 min内对亚甲基蓝的降解率达到93%。     

Redox‐Triggered Self‐Rolling Robust Hydrogel Tubes for Cell Encapsulation

In this study, mechanically strong hydrogels are synthesized by photopolymerization of 2‐vinyl‐4,6‐diamino‐1,3,5‐triazine, poly(ethylene glycol) methacrylate, and disulfide‐containing cross‐linker, N′N‐bis(acryloyl)cystamine. The bilayer hydrogel with distinct cross‐linking density is shown to self‐roll into a 3D tube, which could still be well reinforced by hydrogen bondings, upon exposing reductants such as 1,4‐dithio‐DL‐threitol (DTT) or L‐glutathione (GSH), because the redox‐induced cleavage of disulfide bonds results in the imbalanced internal shrinking stress between two layers. At an intracellular level of GSH, model L929 cells‐seeded bilayer gel sheet could curl up into a 3D tubular scaffold where the cells maintained good viability.

     

Promoting Surface Electric Conductivity for High-Rate LiCoO2

The cathode materials work as the host framework for both Li⁺ diffusion and electron transport in Li-ion batteries. The Li⁺ diffusion property is always the research focus, while the electron transport property is less studied. Herein, we propose a unique strategy to elevate the rate performance through promoting the surface electric conductivity. Specifically, a disordered rock-salt phase was coherently constructed at the surface of LiCoO₂, promoting the surface electric conductivity by over one magnitude. It increased the effective voltage (V_eff) imposed in the bulk, thus driving more Li⁺ extraction/insertion and making LiCoO₂ exhibit superior rate capability (154 mAh g⁻¹ at 10 C), and excellent cycling performance (93 % after 1000 cycles at 10 C). The universality of this strategy was confirmed by another surface design and a simulation. Our findings provide a new angle for developing high-rate cathode materials by tuning the surface electron transport property.     

Highly luminescent carbon nanodots by microwave-assisted pyrolysis

Carbon nanodots (CDs) with a low cytotoxicity have been synthesized by one-step microwave-assisted pyrolysis of citric acid in the presence of various amine molecules. The primary amine molecules have been confirmed to serve dual roles as N-doping precursors and surface passivation agents, both of which considerably enhanced the fluorescence of the CDs.     

Atomic scale control of catalytic process in oxidation of Pb thin films

Using scanning tunneling microscopy (STM), we demonstrate that oxidation on Pb films is greatly enhanced by atomic Cs catalysts. With only a minute concentration of isolated Cs substitutional atoms in the surface layer (0.004 ML coverage), surface oxidation rates are greatly enhanced. First-principles density functional theory (DFT) calculations reveal that a substitutional Cs atom strongly increases O₂ binding on the surface. Then, with additional oxygen exposure this substitutional Cs-initiated oxidation process results in growth of PbO layers in an auto-catalytic manner. Furthermore, we investigate the role of temperature in the oxidation of the Pb films with and without Cs, and we explore the overall morphology of the resultant oxide layers.     

化学激光器1/4环柱型增益发生器

设计并搭建了化学激光器1/4环柱型增益发生器的实验系统。按设计流量进行了出光实验,功率计探测到的出光功率在60 W左右。测量了燃烧室温度及压力,与Alpha激光器HL911-3实验数据类似,燃烧室温度及压力曲线都存在一个爬升阶段。环柱型增益发生器沿角向扩张的特点使得光腔区压力很低,仅为0.5 kPa左右。为验证环柱状增益区的有效形成,对3对取光孔分别进行了出光实验,结果表明每对取光孔都有功率输出,证明设计的增益发生器运行正常。     

基区无吹氦环柱型高超音速低温喷管流场分析

设计了小基区、基区不吹He的环柱型高能化学激光器环形HYLTE喷管 阵列,并使用数值模拟的方法对环形HYLTE喷管阵列流场的气动性能和光学性能进行了分 析. 结果表明,该设计有利于形成ν= 1 →ν = 0之间振转跃迁谱线,不利 于ν = 2→ν =1之间振转跃迁谱线的形成,由于光腔区绝大多数的HF(2)分 子碰撞去激活后成为HF(1)分子,从而使1P谱线的小信号增益倍增,无基 区吹He的设计有利于提高高能化学激光 器的效率. 采用小基区的设计可以增大喷管阵列的功率流密度,无基区吹He的设计不但可 以使复杂的环形高超音速低温喷管叶片的加工与装配得到简化,而且降低了激光器工作 气体的消耗. 因此该设计不但有利于实现高能激光器的紧凑化设计,还有利于节省高能 激光器建造和运行的成本.     

Activity-Based Fluorescent Probes Based on Hemicyanine for Biomedical Sensing

In recent years, fluorescent probes, as an analytical tool that can target and rapidly detect analytes, have been increasingly used for applications related to medical treatment, detection, and bioimaging. Researchers are interested in hemicyanine-based fluorescent probes because of their high quantum yield, tunable spectrum characteristics, absorption and emission in the near-infrared (NIR) region, and good photo-stability. The development of these dyes and their derivatives as NIR fluorescent probes for biological applications has advanced significantly in the last ten years. This review introduces processes for making hemicyanine dyes and the methodology for creating functional activity-based fluorescent probes. A variety of hemicyanine-based probes have been systematically developed for the detection of small biomolecules in various illnesses. Finally, the potential drawbacks of hemicyanine-based functional probes, and the prospects for future research and translation into clinical medicine, are also discussed. This study is intended to provide strategies for the development and design of novel fluorescence probes.     

V族元素掺杂的单层二维铁电α-In2Se3中的带隙异常增大现象

基于第一性原理密度泛函理论计算, 我们探索了 V 族元素(P,As 和Sb) 掺杂的单层二维铁电α-In2Se3 的电子结构. 由于本征的α-In2Se3 中存在两个不等价的In 原子层,V 族元素掺杂在不同的In 原子层会表现出不同的能带结构, 对于带隙变化尤为明显. 当掺杂元素位于α-In2Se3 的四面体配位的In 原子层时, 其带隙相比于本征的单层α-In2Se3 的带隙明显增大, 这与通常半导体或绝缘体中杂质掺杂的物理图像相反. 利用α-In2Se3 的铁电特性, V族元素掺杂的单层α-In2Se3 的带隙可以通过施加外电场翻转α-In2Se3 电极化的方向来调控. 这项工作为在二维材料中构建具有不同电子性质的非易失双态提供了一种实际有效的方法.