化学激光器用文氏咀流场特性的数值模拟

 基于现有的文氏咀流量供给管道,提取出轴对称2维计算模型,计算了不同背压下文氏咀及下游管道的流场特性。计算结果显示,随着背压的升高,激波在管道内经历了3种状态,在直管道内为斜激波,到转接段时为拟正激波,进入文氏咀后则为正激波。在进行文氏咀流量计的设计时,应尽量将正激波控制在文氏咀喉道或向下游延伸的一小段距离内,此时是文氏咀的最佳工作状态。另外,采用壁面开孔法在文氏咀下游选取测压点时,为了准确测量截面上的静压,应将测压点选取在距离直管道入口数倍管径处,一般不低于8倍管径。     

Diophantine inequalities over Piatetski-Shapiro primes

Let c>1 and : We study the solubility of the Diophantine inequality in Piatetski-Shapiro primes p₁,p₂, .., p_s of the form p_j=[m^{\gamma }] for some m\in \mathbb{N}, and improve the previous results in the cases s = 2, 3, 4.     

Wettability switching of SDS-doped polyaniline from hydrophobic to hydrophilic induced by alkaline/reduction reactions

In this paper, sodium dodecyl sulfate (SDS) is used as dopant to manipulate both morphology and wettability of polyaniline (PANI). When SDS amount is controlled within a certain range, micro/nano double-rough PANI with hydrophobic surface can be obtained, while insufficient or excess SDS can only lead to hydrophilic PANI. The double-rough PANI shows stimuli-responsive change in wettability to either alkaline reaction or reduction reaction from hydrophobicity to hydrophilicity. This quick response can be applied to quantitatively estimate NaOH concentrations within the range of 10(-3)-10(-1)M and to detect various reducing liquids.     

中温固体氧化物燃料电池复合阴极Pr0.6-zSr0.4Co0.8Fe0.2O3-δ-SDC性能研究

采用改进的溶胶-凝胶法合成固体氧化物燃料电池阴极系粉体Pr0.6-zSr0.4Co0.8Fe0.2O3-δ(PSCF)(z=0,0.02,0.05,0.1)。使用X射线衍射(XRD)、扫描电子显微镜(SEM)对其相结构与形貌进行了分析,结果表明:900℃以上焙烧后的阴极粉体Pr0.6-zSr0.4Co0.8Fe0.2O3-δ(z=0,0.02,0.05,0.1)为单一的钙钛矿结构。1000℃烧结的样品内粒子分布比较均匀,且颗粒内部存在一定程度的空隙,并与电解质附着情况良好。用直流四电极法测试阴极体系样品在400～750℃的电导率,发现各试样混合离子电子电导率均高于786 S.cm-1,能够满足固体氧化物燃料电池对阴极电导率的要求。用交流阻抗法测定PSCF-Ce0.8Sm0.2O1.9体系样品的阻抗谱,得到1000℃烧结的阴极体系对称电池在测试温度为750℃z=0,z=0.02,z=0.05时的极化电阻分别为0.041,0.040,0.034Ω.cm-2。     

Large-size linear and star-shaped dihydropyrazine fused pyrazinacenes

Linear and star-shaped pyrazinacenes 1a-b and 2 were synthesized via condensation between a new building block 11 and pyrene tetraones or cyclohexaone. Compound 2 represents the largest star-shaped dihydropyrazine fused pyrazinacene reported so far. These largely expanded pyrazinacenes show good solubility and have a strong tendency to aggregate in both solution and thin films, indicating their potential applications for organic electronic devices.     

Research on Product Core Component Acquisition Based on Patent Semantic Network

Patent data contain plenty of valuable information. Recently, the lack of innovative ideas has resulted in some enterprises encountering bottlenecks in product research and development (R&D). Some enterprises point out that they do not have enough comprehension of product components. To improve efficiency of product R&D, this paper introduces natural-language processing (NLP) technology, which includes part-of-speech (POS) tagging and subject–action–object (SAO) classification. Our strategy first extracts patent keywords from products, then applies a complex network to obtain core components based on structural holes and centrality of eigenvector algorism. Finally, we use the example of US shower patents to verify the effectiveness and feasibility of the methodology. As a result, this paper examines the acquisition of core components and how they can help enterprises and designers clarify their R&D ideas and design priorities.     

氯化亚铁/β-丙氨酸席夫碱配合物催化甲基丙烯酸甲酯原子转移自由基聚合的研究

1995年Matyjaszewski等提出的原子转移自由基聚合(ATRP)的概念为活性自由基聚合开辟了一条新的途径．近10年来,ATRP日益得到高分子合成化学家的重视．典型的ATRP反应体系所用催化剂由可变价过渡金属化合物和适当的配体组成．常用的过渡金属化合物有铜、铁、钌、和铑等．其中铁催化剂以其低毒性引起人们的重视．     

一类加性函数的倒数和

设ｇ（ｎ）＞０为任一实值函数,加性函数Ｇ（ｎ）定义为Ｇ（１）＝０,Ｇ（ｎ）＋ｋ≥１为一固定正整数。本文研究了和式∑２≤ｎ≤ｘ　,并得到了渐近公式。     

Novel Fungal Pelletization-Assisted Technology for Algae Harvesting and Wastewater Treatment

A novel fungi pelletization-assisted bioflocculation technology was developed for efficient algae harvesting and wastewater treatment. Microalga Chlorella vulgaris UMN235 and two locally isolated fungal species Aspergillus sp. UMN F01 and UMN F02 were used to study the effect of various cultural conditions on pelletization process for fungi?Calgae complex. The results showed that pH was the key factor affecting formation of fungi?Calgae pellet, and pH could be controlled by adjusting glucose concentration and fungal spore number added. The best pelletization happened when adding 20?g/L glucose and approximately 1.2E8/L spores in BG-11 medium, under which almost 100?% of algal cells were captured onto the pellets with shorter retention time. The fungi?Calgae pellets can be easily harvested by simple filtration due to its large size (2?C5?mm). The filtered fungi?Calgae pellets were reused as immobilized cells for treatment wastewaters and the nutrient removal rates of 100, 58.85, 89.83, and 62.53?% (for centrate) and 23.23, 44.68, 84.70, and 70.34?% (for diluted swine manure wastewater) for ammonium, total nitrogen, total phosphorus, and chemical oxygen demand, respectively, under both 1- and 2-day cultivations. The novel technology developed is highly promising compared with current algae harvesting and biological wastewater treatment technologies in the literature.     

Palladium-catalyzed cascade synthesis of spirocyclic oxindoles via regioselective C2-H arylation and C8-H alkylation of naphthalene ring

A simultaneous C2-H arylation and C8-H alkylation of naphthalene ring has been achieved by palladiumcatalyzed cascade reaction of N-(2-halophenyl)-2-(naphthalen-1-yl)acrylamides with aryl iodides,which provides an efficient method for synthesizing various aryl-substituted spirocyclic oxindoles.The protocol enables three C-C bonds formation via an intramolecular Heck reaction and sequentially regioselective C-H bond activation.