增益模块长高比对输出功率和提取效率的影响

为了得到HF化学激光器的增益发生器较佳的模块尺寸,研究了增益模块长高比对输出功率及放大级提取效率的影响。使用基于变换坐标系的有限差分方法,计算了主振荡功率放大器（MOPA）结构HF激光器不同增益模块长高比条件下的主振荡器输出功率、放大级提取效率及经放大后的输出功率。计算结果表明：对于MOPA结构HF激光器而言,当增益体积一定、小信号增益曲线相同时,随着增益模块长高比的减小,主振荡器输出功率和经放大级放大后的输出功率将有所增加,但放大级的能量提取效率将降低;当增益模块长高比已经较小(小于５)时,进一步降低长高比对激光器输出功率和放大级提取效率的影响微弱。     

PET表面接枝偶氮聚合物和光致取向研究

合成了一种丙烯酸酯类含芳香族偶氮生色团的单体ANB .以二苯甲酮为引发剂 ,采用固相紫外光接枝方法将上述单体接枝到聚酯 (PET)膜的表面 ,得到了一种具有光响应性的接枝膜 .通过SEM研究了接枝膜的表面和断面的形貌 ,观察到偶氮接枝层均匀地覆盖了PET表面 ,接枝层厚度约 0 4μm .研究发现 ,当使用488nm的线偏振激光照射接枝膜时 ,偶氮生色团通过快速的顺反异构化反应在垂直于偏振光极化方向上发生取向 ,得到了具有光学各向异性表面的PET接枝膜 .接枝膜的取向是一个快速过程 ,取向有序度参数在 2min时即达到最大值 ,为 0 0 6左右     

Oil Crop Biomass Residue-Based Media for Enhanced Algal Lipid Production

The aim of this study was to evaluate the use of hydrolysates from acid hydrolysis of four different oil crop biomass residues (OCBR) as low cost culture media for algae growth. The one-factor-at-a-time method was used to design a series of experiments to optimize the acid hydrolysis conditions through examining the total nitrogen, total phosphorus, chemical oxygen demand, and ammonia nitrogen in the hydrolysates. The optimal conditions were found to be using 3 % sulfuric acid and hydrolyzing residues at 90 °C for 20 h. The hydrolysates (OCBR media) produced under the optimal conditions were used to cultivate the two algae strains, namely UM258 and UM268. The results from 5 days of cultivation showed that the OCBR media supported faster algae growth with maximal algal biomass yield of 2.7 and 3 g/L, respectively. Moreover, the total lipids for UM258 and UM268 were 54 and 35 %, respectively, after 5 days of cultivation, which suggested that the OCBR media allowed the algae strains to accumulate higher lipids probably due to high C/N ratio. Furthermore, over 3 % of omega-3 fatty acid (EPA) was produced for the two algae strains. In conclusion, OCBR media are excellent alternative for algae growth and have a great potential for large-scale production of algae-based ingredients for biodiesel as well as high-value food and pharmaceutical products.     

Influence of Exogenous CO2 on Biomass and Lipid Accumulation of Microalgae Auxenochlorella protothecoides Cultivated in Concentrated Municipal Wastewater

The effects of exogenous CO₂ on the growth and lipid accumulation of a local screened facultative heterotrophic microalgae strain Auxenochlorella protothecoides (UMN280) as well as nutrient removal from concentrated municipal wastewater stream (centrate) were examined in this study. A 12-day batch experiment was conducted with CO₂ aeration at three levels, namely, 0%, 1%, and 5% (v/v) CO₂ mixed with air, under light intensity of 60???mol/(m² @@s). A two-stage growth pattern was observed. The first stage (first?Cfifth day) was dominated by heterotrophic growth in which organic carbon was the main carbon source. The second stage (6th?C12th day) was dominated by autotrophic growth in which exogenous CO₂ had a positive effect on algal biomass accumulation. The addition of 5% CO₂ was better than that of 1% CO₂ on the biomass and lipid production. The uptakes of nutrients were similar between injection and no injection of CO₂, except on phosphorus removal which was affected by the acidification of CO₂.     

Synthesis and Enhanced Photocatalytic Activity of a Hierarchical Porous Flowerlike p–n Junction NiO/TiO2 Photocatalyst

Hierarchical flowerlike β‐Ni(OH)₂ superstructures composed of intermeshed nanoflakes are synthesized by hydrothermal treatment with a mixed solution of C₂H₄(NH₂)₂, NaOH, and Ni(NO₃)₂. The as‐prepared β‐Ni(OH)₂ superstructures could be easily changed into NiO superstructures without great morphology change by calcination at 400 °C for 5 h. Furthermore, the TiO₂ nanoparticles can be homogeneously deposited on the surface of NiO superstructures by dispersing β‐Ni(OH)₂ powders in Ti(OC₄H₉)₄–C₂H₅OH mixed solution and then vaporizing to remove the ethanol at 100 °C, and finally calcination at 400 °C for 5 h. The prepared NiO/TiO₂ p–n junction superstructures show much higher photocatalytic activity for photocatalytic degradation of p‐chlorophenol aqueous solution than conventional TiO₂ powders and NiO superstructures prepared under the same experimental conditions. An obvious enhancement in the photocatalytic activity can be related to several factors, including formation of hierarchical porous structures, dispersion of TiO₂ particles on the surface of NiO superstructures, and production of a p–n junction. Further results show that NiO/TiO₂ composite superstructures can be more readily separated from the slurry system by filtration or sedimentation after photocatalytic reaction and re‐used, compared with conventional powder photocatalysts. After many recycling experiments for the photodegradation of p‐chlorophenol, the NiO/TiO₂ composite sample does not exhibit any great activity loss, confirming that NiO/TiO₂ sample is stable and not photocorroded.     

A novel chemical route to SiO_2 nanowires

A white substance was got by directly heating TiSi powder on Ti foil, under Ar+O2 atmosphere. ED, EDX, SEM and HRTEM studies reveal that the white substance consists of amorphous SiO2nanowires of smooth surface and uniform diameter (40-90 nm). X-ray-induced luminescent emission experiment shows that two broad peaks are at 430 and 570 nm. A one-dimensional growth mechanism, on the basis of the one-dimensional thermal flow during nanowire formation, is discussed.     

含双裂纹圆截面悬臂梁的损伤识别研究

裂纹的萌生和扩展直接影响构件的振动响应,对构件的安全可靠性具有重要影响.本文以圆截面悬臂梁为对象,结合转角模态振型和模态频率等高线,研究了一种双裂纹识别技术.首先,基于应力强度因子和卡氏定理推导了无裂纹梁单元和含裂纹梁单元的刚度矩阵;在此基础上,建立了含裂纹圆截面悬臂梁的有限元动力学方程;然后,结合裂纹对梁转角模态振型和模态频率的影响,提出了双裂纹识别策略.最后,通过算例讨论了双裂纹识别策略的可行性.结果表明,圆截面悬臂梁的模态转角在裂纹位置出现突变,裂纹深度越大转角突变值越大;将识别出的裂纹位置作为已知参数,通过模态频率等高线法,可以准确地识别出双裂纹的深度.     

Wettability switching of SDS-doped polyaniline from hydrophobic to hydrophilic induced by alkaline/reduction reactions

In this paper, sodium dodecyl sulfate (SDS) is used as dopant to manipulate both morphology and wettability of polyaniline (PANI). When SDS amount is controlled within a certain range, micro/nano double-rough PANI with hydrophobic surface can be obtained, while insufficient or excess SDS can only lead to hydrophilic PANI. The double-rough PANI shows stimuli-responsive change in wettability to either alkaline reaction or reduction reaction from hydrophobicity to hydrophilicity. This quick response can be applied to quantitatively estimate NaOH concentrations within the range of 10(-3)-10(-1)M and to detect various reducing liquids.     

Large-size linear and star-shaped dihydropyrazine fused pyrazinacenes

Linear and star-shaped pyrazinacenes 1a-b and 2 were synthesized via condensation between a new building block 11 and pyrene tetraones or cyclohexaone. Compound 2 represents the largest star-shaped dihydropyrazine fused pyrazinacene reported so far. These largely expanded pyrazinacenes show good solubility and have a strong tendency to aggregate in both solution and thin films, indicating their potential applications for organic electronic devices.     

高温后钢管活性粉末混凝土的动态力学性能

采用霍普金森压杆装置对高温后钢管活性粉末混凝土(reactive powder concrete-filled steel tube,RPC-FST)进行冲击压缩实验,分析了应变率效应及温度效应对试件动态力学性能的影响。结果表明:高温(200、300 ℃)后RPC-FST仍具有较好的抗冲击能力、延性和完整性;冲击荷载作用下,RPC-FST的应变率效应明显弱于RPC的应变率效应;随着过火温度的提高,RPC-FST的峰值应力逐渐增大,变形能力增强,抗冲击能力提高。动力提高系数随过火温度的提高而增大,说明高温后RPC-FST的应变率效应更显著。