CH_2Cl_2对离子液体BmimPF_6中二茂铁电化学行为的影响

应用循环伏安和交流阻抗法研究有机溶剂二氯甲烷对二茂铁在离子液体1-丁基-3-甲基咪唑六氟磷酸盐(Bm imPF6)中电化学行为的影响.实验表明,二氯甲烷可促进离子液体的离子解离,减小离子液体粘度,增加离子液体电导率,加速二茂铁在离子液体中的扩散,增大氧化还原峰电流.由于电极界面双电层结构的变化,导致双电层电容增大,电极反应电阻减小,从而加速了界面电子传递反应.     

Application of Exp-Function Method to Discrete Nonlinear Schrödinger Lattice Equation with Symbolic Computation

In this paper, we present an extended Exp-function method to differential-difference equation(s). With the help of symbolic computation, we solve discrete nonlinear Schrödinger lattice as an example, and obtain a series of general solutions in forms of Exp-function.     

X射线荧光光谱理论强度计算中激发因子的选择

激发因子是X射线荧光强度理论计算中的重要参数。对目前常用的四种激发因子算法进行了较为详细的比较,并设计了一种评价激发因子算法的实验方法,即用人工合成试样测定了八对能量接近的X射线特征谱线的强度比,然后根据不同的激发因子算法用理论方法计算出这些谱线对的强度比值,以两者的接近程度来判断这四种激发因子算法的适用性。结果表明,使用NRLXRF程序修改版中的激发因子算法计算出来的理论强度比与实测值之间的相对偏差最小。     

Orlicz空间的近端点和近严格凸性

本文给出了Orlicz函数空间中近端点的判别准则,近而推出了Orlicz函数空目近严格凸性的判别准则.另外,本文还直接给出Orlicz序列空间近严格凸的判别准则.     

由两个风扇转子设计得到的启示

本文对两个风扇转子设计进行了总结,从设计过程突破问题的关键以及流动的组织方面看,得到了几点有益启示,值得在新型叶轮机设计及有关问题研究中引以借鉴。     

一个1+1对转涡轮的初步设计

本文初步尝试１＋１对转涡轮设计,试图发现区别于常规涡轮设计存在的问题,探索对转涡轮设计体系的组成和应用策略,对１＋１对转涡轮给出初步评价。     

关于1+1对转涡轮中热痕现象的研究

热痕现象深刻影响涡轮叶片的热负荷,关于该现象的研究成果将对提高涡轮前温度、优化发动机燃烧室与涡轮叶排周向相对位置等起到促进作用。本文采用无粘时间精确解对热痕现象在所设计１＋１对转涡轮中的作用做了初步研究。     

微重力条件下舱内对流换热的地面质-热比拟

运用热量传递和质量传递的相似比拟原理,对载人航天器地面模拟舱内空气的对流换热和对流传质进行了理论分析,对萘升华质－热比拟实验技术用于微重力舱内对流换热地面模拟的可行性进行了讨论。提出了一种工作压力和模型尺寸保持的抑制自然对流的地面模拟技术,并用数值方法对其进行了验证。结果表明,这一技术可用于载人航天器工作舱内对流换热的地面模拟实验。     

A Note on Symplectic,Multisymplectic Scheme in Finite Element Method

We find that with uniform mesh, the numerical schemes derived from finite element method can keep a preserved symplectic structure in one-dimensional case and a preserved multisymplectic structure in two-dimensional case respectively. These results are in fact the intrinsic reason why the numerical experiments show that such finite element algorithms are accurate in practice.     

Superconducting Correlations in Small Metallic Grains

By applying the path-integral formulation and the Feynman theorem, we calculate the off-diagonal superconducting correlation in an ultrasmall metallic grain. Unlike its behavior in the bulk limit, we find that this correlation function is an intensive quantity in this case. Therefore, superconductivity is indeed completely suppressed by quantum fluctuations as the diameter of the grain shrinks to the nanometer scale. This conclusion confirms the previous results by numerical calculations. Furthermore, it also imposes a strong constraint on the delocalizing amplitude of the pair-mixing function, which was recently proposed to characterize superconductivity in the canonical ensemble.