全文获取类型
收费全文 | 635篇 |
免费 | 31篇 |
专业分类
化学 | 419篇 |
力学 | 11篇 |
数学 | 94篇 |
物理学 | 142篇 |
出版年
2022年 | 15篇 |
2021年 | 13篇 |
2020年 | 16篇 |
2019年 | 14篇 |
2018年 | 8篇 |
2017年 | 6篇 |
2016年 | 27篇 |
2015年 | 20篇 |
2014年 | 24篇 |
2013年 | 25篇 |
2012年 | 36篇 |
2011年 | 35篇 |
2010年 | 19篇 |
2009年 | 27篇 |
2008年 | 32篇 |
2007年 | 29篇 |
2006年 | 29篇 |
2005年 | 22篇 |
2004年 | 24篇 |
2003年 | 11篇 |
2002年 | 30篇 |
2001年 | 15篇 |
2000年 | 12篇 |
1999年 | 12篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1995年 | 7篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 9篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 10篇 |
1980年 | 10篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1977年 | 9篇 |
1976年 | 5篇 |
1975年 | 3篇 |
1974年 | 5篇 |
1973年 | 7篇 |
1969年 | 4篇 |
1905年 | 3篇 |
排序方式: 共有666条查询结果,搜索用时 0 毫秒
61.
Francisca Zamora Khalid Hakkou Abdelilah Alla Manuel Rivas Isaac Roff Manuel Mancera Sebastin Muoz‐Guerra Juan A. Galbis 《Journal of polymer science. Part A, Polymer chemistry》2005,43(19):4570-4577
The synthesis and characterization of a new series of aromatic polyesters based on D‐mannitol and galactitol are described. These polyesters were obtained by polycondensation reaction of the terephthaloyl chloride or isophthaloyl chloride and 2,3,4,5‐tetra‐O‐methyl‐D‐mannitol or 2,3,4,5‐tetra‐O‐methyl‐galactitol in o‐dichlorobenzene. All the new polyesters were characterized by elemental analyses, GPC, IR, and NMR. They were soluble in chloroform, but insoluble in water and other polar oxygenated solvents. They showed a notable hygroscopicity, lower for those containing isophthalic units. DSC and X‐ray diffraction studies showed that D‐mannitol‐based polyesters were stiffer and less crystalline than those derived from galactitol, which presented a noticeably lower thermal stability. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4570–4577, 2005 相似文献
62.
Darwin P. R. Kint Antxon Martínez de Ilarduya Abdelilah Alla Sebastin Muoz‐Guerra 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):124-134
Poly(ethylene terephthalate‐co‐isophthalate‐co‐5‐tert‐butylisophthalate) (PETItBI) terpolymers were investigated with reference to poly(ethylene terephthalate) (PET) homopolymer and poly(ethylene terephthalate‐co‐isophthalate) (PETI) copolymers. Three series of PETItBI terpolyesters, characterized by terephthalate contents of 90, 80, and 60 mol %, respectively, with different isophthalate/5‐tert‐butylisophthalate molar ratios, were prepared from ethylene glycol and mixtures of dimethyl terephthalate, dimethyl isophthalate, and 5‐tert‐butylisophthalic acid. The composition of the terpolymers and the composition of the feed agreed. All terpolymers had a random microstructure and number‐average molecular weights ranging from 10,000 to 20,000. The PETItBI terpolyesters displayed a higher glass‐transition temperature and a lower melting temperature than the PETI copolymers having the same content of terephthalic units. Thermal stability appeared essentially unchanged upon the incorporation of the 5‐tert‐butylisophthalic units. The PETItBIs were crystalline for terephthalate contents higher than 80 mol %, and they crystallized at lower rates than PETI. The crystal structure of the crystalline terpolymers was the same as that of PET with the 1,3‐phenylene units being excluded from the crystalline phase. Incorporation of isophthalate comonomers barely affected the tensile modulus and strength of PET, but the brittleness of the terpolymers decreased for higher contents in 5‐tert‐butylisophthalic units. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 124–134, 2003 相似文献
63.
Francisca Zamora Khalid Hakkou Abdelilah Alla Jos L. Espartero Sebastin Muoz‐Guerra Juan A. Galbis 《Journal of polymer science. Part A, Polymer chemistry》2005,43(24):6394-6410
The synthesis and characterization of new aromatic homo‐ and copolyesters based on l‐arabinitol and xylitol are described. These polymers were obtained by polycondensation reaction of the 2,3,4‐tri‐O‐methyl‐l‐arabinitol or 2,3,4‐tri‐O‐methyl‐xylitol, or their mixtures with ethylene glycol, with terephthaloyl chloride or isophthaloyl chloride in o‐dichlorobenzene or in the melt phase from the corresponding methyl phthalates. All the polymers were characterized by GPC, IR, and NMR. Their Mw values ranged between 11,500 and 46,500, with polydispersities from 1.5 to 2.3. They were found to be soluble in chloroform, but insoluble in water. In contrast with the homopolymers completely made with EG, they showed a significant hygroscopicity. DSC and TGA studies showed that the melting temperature of polyethylene terephthalate is depressed by the presence of pentitol units, whereas the thermal stability is kept above 350 °C. Only copolyesters containing 10% or less of pentitol units showed melting and produced X‐ray diffraction patterns characteristic of crystalline material. d‐Arabinitol‐based homopolyesters appeared to be more crystalline than those derived from xylitol and also presented a higher thermal stability. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 6394–6410, 2005 相似文献
64.
65.
This paper analyzes the effect on the optimal value of a given linear semi-infinite programming problem of the kind of perturbations which more frequently arise in practical applications: those which affect the objective function and the right-hand-side coefficients of the constraints. In particular, we give formulae which express the exact value of a perturbed problem as a linear function of the perturbation. 相似文献
66.
Giuseppe Mensitieri Domenico Larobina Gaetano Guerra Vincenzo Venditto Maurizio Fermeglia Sabrina Pricl 《Journal of Polymer Science.Polymer Physics》2008,46(1):8-15
The transport of chloroform in films of atactic polystyrene and of semicrystalline syndiotactic polystyrene in its nanoporous form (δ‐form) has been investigated by gravimetric analysis. Experimental tests have been performed at 35, 49, and 56 °C and at several vapor pressures ranging from 0.5 to 100 Torr. Nonequilibrium lattice fluid prediction of the amorphous sorption behavior was used to enucleate the sorption contribution of the crystalline nanoporous phase from semicrystalline samples. Sorption behavior of the crystalline phase has been interpreted on the basis of Langmuir equation. Moreover, the chloroform sorption at low activities in the crystalline nanoporous phase has been predicted by using Grand Canonical Monte Carlo molecular simulations. Isosteric heats of sorption were also experimentally evaluated for the crystalline phase, and compared with the corresponding prediction of molecular simulation. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 8–15, 2008 相似文献
67.
A. Del Guerra A. Giazotto M.A. Giorgi A. Stefanini D.R. Botterill D.W. Braden P.R. Norton 《Physics letters. [Part B]》1973,45(4):409-410
The azimuthal angle dependence of the process ep → enπ+ has been measured by detecting the electron and neutron in coincidence. Data are presented for momentum transfers (?k2) between 0.08 and 0.32 and at energies close to threshold. Fixed-t dispersion relation models give predictionsin good qualitative agreement with the data. 相似文献
68.
The title reaction was studied in a standard flow system with F atoms produced by RF discharge in F2-He mixture. Analysis was by gas chromatography using electron capture detection. There were two major products, identified as CF2BrCF2H and CF2BrCF2Br, plus presumably HF which was not detectable. The overall rate of disappearance of reactant was found to be of mixed one and one-half order, indicating a complex reaction. A mechanism is proposed comprising six steps and involving two radical species CF2Br?FBr (R1) and CF2Br?F2. The 300 K rate constant for the initial step F + reactant → HF + R1 is evaluated to be 2.2 × 10?13 cm3/molec·s, which fits in with rates of other saturated hydrocarbon reactants containing one hydrogen atom, thus supporting the view that in this class of reactants the rates of reactions of the type F + saturated hydrocarbon depend mainly on the number of hydrogen atoms in the reactant. 相似文献
69.
In the tolerance approach to sensitivity analysis of matrix coefficients in a linear programme, the maximum tolerance percentage characterizes the largest percentage within which selected matrix coefficients may vary simultaneously and independently while retaining the same set of optimal basic variables. While it is difficult to calculate exactly the maximum tolerance percentage under perturbations in multiple rows or columns, we show herein how it can be approximated. 相似文献
70.
Gian Fabrizio De Angelis Diego De Falco Francesco Guerra 《Physics letters. [Part B]》1977,68(3):255-257
We consider Wilson's lattice approximation to scalar Quantum Electrodynamics. We establish correlation inequalities of Griffiths-Kelly-Sherman type and a rigorous transfer matrix formalism, from which existence and non triviality of the infinite volume limit follow. 相似文献