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11.
The structures and energies of the noble gas containing anions FNgO- (Ng = He, Ar, and Kr) have been calculated by high-level ab initio calculations. The FNgO- anions were found to be deep-energy minima at the singlet electronic state, and their energies are significantly lower than those at the triplet state. High dissociation energy barriers to Ng + OF- were also predicted. The unexpected stability of the FNgO- was due to the dramatic ion-induced O=Ng bond formation. The calculated results suggested possible experimental identification of the anionic species and even some related "ionic compounds" under cryogenic conditions. 相似文献
12.
阴离子交换色谱-积分脉冲安培法测定鱼粉和玉米粉水解液中氨基酸 总被引:4,自引:0,他引:4
将高效阴离子交换色谱.积分脉冲安培直接检测法应用于鱼粉和玉米粉水解液中的氨基酸的分析测定。该方法使用Dionex AminoPac PA10阴离子交换柱为分析柱,控制柱温为35℃,以NaOH和NaAc的强碱性溶液为淋洗液,在合适的梯度条件下,可以实现对17种常见氨基酸的高效分离。在强碱性条件下,获得良好分离的各个氨基酸可在配有金工作电极的电化学检测器上以积分脉冲安培法获得高灵敏度的检测。在优化的测定条件下,该方法对这17种氨基酸的检出限在0.21—3.38pmol之间;峰面积校正曲线的线性范围为2—3个数量级;5次平行测定的峰面积的相对标准偏差RSD在0.32%—4.7%之间。该方法应用于玉米粉和鱼粉水解液中氨基酸含量的测定,结果良好。对玉米粉和鱼粉水解液标准加入的回收率分别在81.9%—108.0%和90.0%~108.0%之间。 相似文献
13.
We investigated the aggregation behavior of rod-like micelles of sodium dodecyl sulfate (SDS) in concentrated NaCl solution by quasi-elastic light scattering (QLS) and viscosity measurement over a range of temperature (25 °C to 50 °C) and NaCl concentration. The reduced viscosity of aqueous SDS in the presence of NaCl has been measured by an Ubbelohde-type capillary viscometer. We show mean hydrodynamic radius of micelles can be determined from viscosity data. We also determined mean hydrodynamic radius using quasi-elastic light scattering. Micellar size decreases with increasing temperature, whereas it increases with increasing ionic strength. The results of viscosity and dynamic light-scattering measurements are interpreted as the extension of length of rod-like micelles. We compare viscosity and light scattering experimental results. 相似文献
14.
The current response for the parameter change of a mesoscopic system is a practical issue for future's circuit design. Nowadays most considered cases are various types of bias modulation, while the effect of change of conductor Hamiltonian is seldom addressed. In this paper, we investigate the response of ballistic transport induced by a sudden change of the conductor Hamiltonian. We formulize the terminal current in language of non-equilibrium Green's function. Our method is applied to one-dimensional tight-binding chains and we find that the terminal current has a delay to the Hamiltonian change. The amount of delay is not determined by the velocity of incident electrons in the bias window, but depends on the tight-binding hopping energy γ. The delay of current response at the detecting point away from where the Hamiltonian changes is , where C is a constant independent of the system. 相似文献
15.
本文通过3,6-二肼基-1,2,4,5-四嗪(DHT)分别与高氯酸和硝酸反应得到2种高氮含能离子盐,并通过X-射线单晶衍射技术对它们的结构进行了表征。(DHT)(NO3)2(1)属于单斜晶系,C2/c空间群,晶胞参数:a=1.300 0(6) nm,b=0.834 9(3) nm,c=1.018 7(5) nm,β=118.89(5)°,Z=4;(DHT)(ClO4)2(2)属于正交晶系,P21212空间群,晶胞参数:a=0.980 4(4) nm,b=1.074 7(4) nm,c=0.532 5(2) nm,Z=2。采用DSC和TG-DTG技术研究了这两种含能离子盐的热分解机理,并对这两种含能离子盐的非等温动力学、爆热及感度进行了测试分析。研究表明这两种含能离子盐在敏感型含能材料领域具有潜在的应用前景。 相似文献
16.
Shuo Gu Tingting Mou Jian Chen Jing Wang Ying Zhang Meirong Cui Wenqian Hao Yue Sun Chengqin Zhang Tiantian Zhao Binbin Wei 《Journal of separation science》2022,45(10):1656-1671
Baihe-Dihuang Tang is a commonly prescribed remedy for depression. In this study, component screening with untargeted and targeted metabolomics was used to identify potential biomarkers for depression in chronic unpredictable mildly stressed rats. Using this novel identification method, the screening of organic acids, lily saponins, iridoids, and other ingredients formed the basis for subsequent metabolomics research. Baihe-Dihuang Tang supplementation in chronic unpredictable mild-stress-induced depression models, increased their body weight, sucrose preference, brain-derived neurotrophic factor deposition, and spatial exploring. Untargeted metabolomics revealed that Baihe-Dihuang Tang exerts its antidepressant effects by regulating the levels of lipids, organic acids, and its derivatives, and benzenoids in the brain, plasma, and urine of the depressed rats. Moreover, it also modulates the d -glutamine and d -glutamate metabolism and purine metabolism. Targeted metabolomics demonstrated significant reduction in l -glutamate levels in the brains of depressed rats. This could be a potential biomarker for depression. Baihe-Dihuang Tang alleviated depression by regulating the levels of l -glutamate, xanthine, and adenine in the brains of depressed rats. Together, these findings conclusively established the promising therapeutic effect of Baihe-Dihuang Tang on depression and also unraveled the underlying molecular mechanism of its potential antidepressant function. 相似文献
17.
In this study, flexible silk fibroin protein and biocompatible barium hexaferrite (BaM) nanoparticles were combined and electrospun into nanofibers, and their physical properties could be tuned through the mixing ratios and a water annealing process. Structural analysis indicates that the protein structure of the materials is fully controllable by the annealing process. The mechanical properties of the electrospun composites can be significantly improved by annealing, while the magnetic properties of barium hexaferrite are maintained in the composite. Notably, in the absence of a magnetic field, cell growth increased slightly with increasing BaM content. Application of an external magnetic field during in vitro cell biocompatibility study of the materials demonstrated significantly larger cell growth. We propose a mechanism to explain the effects of water annealing and magnetic field on cell growth. This study indicates that these composite electrospun fibers may be widely used in the biomedical field for controllable cell response through applying different external magnetic fields. 相似文献
18.
Nan Zhao Huawei Mou Yuguang Zhou Xinxin Ju Shoujun Yang Shan Liu Renjie Dong 《Molecules (Basel, Switzerland)》2021,26(4)
Developing a green and sustainable method to upgrade biogas wastes into high value-added products is attracting more and more public attention. The application of solid residues as a performance enhancer in the manufacture of biofilms is a prospective way to replace conventional plastic based on fossil fuel. In this work, solid digestates from the anaerobic digestion of agricultural wastes, such as straw, cattle and chicken manures, were pretreated by an ultrasonic thermo-alkaline treatment to remove the nonfunctional compositions and then incorporated in plasticized starch paste to prepare mulching biofilms by the solution casting method. The results indicated that solid digestate particles dispersed homogenously in the starch matrix and gradually aggregated under the action of a hydrogen bond, leading to a transformation of the composites to a high crystalline structure. Consequently, the composite biofilm showed a higher tensile strength, elastic modulus, glass transition temperature and degradation temperature compared to the pure starch-based film. The light, water and GHG (greenhouse gas) barrier properties of the biofilm were also reinforced by the addition of solid digestates, performing well in sustaining the soil quality and minimizing N2O or CH4 emissions. As such, recycling solid digestates into a biodegradable plastic substitute not only creates a new business opportunity by producing high-performance biofilms but also reduces the environmental risk caused by biogas waste and plastics pollution. 相似文献
19.
20.
2-硫代丁基-5-巯基-1,3,4-噻二唑Ag[I]修饰的钼硅酸盐纳米颗粒的制备及摩擦性能 总被引:1,自引:0,他引:1
以合成的2-硫代丁基-5-巯基-1,3,4-噻二唑为配体,在醇-水体系中制备了Keggin结构钼硅杂多阴离子有机衍生物的纳米颗粒,以透射电子显微镜、扫描电子显微镜、傅立叶变换红外光谱仪、热分析仪等测试手段对此纳米颗粒的形貌、组成和结构进行了表征,并在机械式四球长时抗磨损试验机上考察了其摩擦学性能.分散型实验结果表明化合物在有机溶剂中分散性能良好,红外光谱表明所合成的纳米颗粒具有杂多酸Keggin骨架结构无机核,透射电镜分析表明颗粒平均粒径约为10nm,热分析娃示分解温度范围为200~300℃.作为新型纳米润滑油添加剂,在最佳添加质量分数为0.05%,负荷300N,摩擦时间30min,转速1450r/min的条件下,与空白相比磨斑直径减小27.9%,摩擦系数减小15.3%. 相似文献