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81.
Hsin-Yun Chih Ying-Wei Chen Yi-Chun Hsieh Wei-Cheng Li Chia-Wei Liao Chun-Han Lin Ting-Ya Chiu Dr. Wei-Wen Tsai Dr. Chin-Wei Lu Dr. Chih-Hao Chang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16699-16711
A series of donor–acceptor–donor triazine-based molecules with thermally activated delayed fluorescence (TADF) properties were synthesized to obtain highly efficient blue-emitting OLEDs with non-doped emitting layers (EMLs). The targeted molecules use a triazine core as the electron acceptor, and a benzene ring as the conjugated linker with different electron donors to alternate the energy level of the HOMO to further tune the emission color. The introduction of long alkyl chains on the triazine core inhibits the unwanted intermolecular D –D/A–A-type π–π interactions, resulting in the intermolecular D–A charge transfer. The weak aggregation-caused quenching (ACQ) effect caused by the suppressed intermolecular D –D/A–A-type π–π interaction further enhances the emission. The crowded molecular structure allows the electron donor and acceptor to be nearly orthogonal, thereby reducing the energy gap between triplet and singlet excited states (ΔEST). As a result, blue-emitting devices with TH-2DMAC and TH-2DPAC non-doped EMLs showed satisfactory efficiencies of 12.8 % and 15.8 %, respectively, which is one of the highest external quantum efficiency (EQEs) reported for blue TADF emitters (λpeak<475 nm), demonstrating that our tailored molecular designs are promising strategies to endow OLEDs with excellent electroluminescent performances. 相似文献
82.
Chung‐Lun Wu Cheng‐Hsuan Hsieh Gong‐Ru Lin Wen‐Chun Chi Yi‐Jen Chiu Yuan‐Yao Lin Yung‐Jr Hung Min‐Hsiung Shih Ann‐Kuo Chu Chao‐Kuei Lee 《Annalen der Physik》2017,529(3)
A tantalum pentoxide‐based (Ta2O5‐based) micro‐ring all‐optical modulator was fabricated. The refractive index inside the micro‐ring cavity was modified using the Kerr effect by injecting a pumped pulse. The transmittance of the ring resonator was controlled to achieve all‐optical modulation at the wavelength of the injected probe. When 12 GHz pulses with a peak power of 1.2 W were coupled in the ring cavity, the transmission spectrum of the Ta2O5 resonator was red‐shifted by 0.04 nm because of the Kerr effect. The relationship between the modulation depth and gap of the Ta2O5 directional coupler is discussed. An optimized gap of 1100 nm was obtained, and a maximum buildup factor of 11.7 with 84% modulation depth was achieved. The nonlinear refractive index of Ta2O5 at 1.55 μm was estimated as 3.4 × 10?14 cm2/W based on the Kerr effect, which is almost an order of magnitude higher than that of Si3N4. All results indicate that Ta2O5 has potential for use in nonlinear waveguide applications with modulation speeds as high as tens of GHz.
83.
Simultaneous measurement of curvature and temperature based on PCF-based interferometer and fiber Bragg grating 总被引:2,自引:0,他引:2
Yan Zhou Wenjun Zhou Chi Chiu Chan Li-Yang Shao Xinyong Dong 《Optics Communications》2011,284(24):5669-5672
A sensor head consisting of a photonic crystal fiber (PCF)-based Mach-Zehnder interferometer (MZI) and a fiber Bragg grating (FBG) is proposed and experimentally demonstrated for simultaneous measurement of curvature and temperature. The MZI fabricated by splicing a short length of PCF between two single-mode fibers with the air-hole structure that completely collapsed near the splicing points, is sensitive to fiber bending and surrounding temperature, while the FBG is only sensitive to the later. Simultaneous measurement of curvature and temperature is therefore obtained. Sensitivities of 4.06 nm/m− 1 and 6.30 pm/°C are achieved experimentally for curvature and temperature, respectively. And the corresponding resolutions are 5.2 × 10− 4 m− 1 and 1.25 °C for curvature and temperature, respectively, based on the wavelength measurement resolution of 10 pm. 相似文献
84.
A highly sensitive miniature photonic crystal fiber refractive index sensor based on field mode excitation is presented. The sensor is fabricated by melting one end of a photonic crystal fiber into a rounded tip and splicing and collapsing the other end with a single-mode fiber. The rounded tip is able to induce cladding mode excitation, which resulted in an additional phase delay. Linear response of 262.28 nm/refractive index unit in the refractive index range of 1.337 to 1.395 is obtained for the physical length of a 953 μm sensor. The sensor is also shown to be insensitive to environmental temperature. 相似文献
85.
C.H. Chia C.T. Yuan S.L. Yang J.Y. Juang K.C. Chiu S.Y. Jeng 《Journal of luminescence》2008,128(1):123-128
A detailed photoluminescence investigation of the thermal redshift and broadening of the excitonic line of cubic CdSe film grown by molecular beam epitaxy is presented. Free excitonic emission from the cubic CdSe film was observed at low temperature. Temperature-dependent measurement was performed to obtain material parameters related to exciton-phonon interaction by fitting the experimental data to the phenomenological model. The relative contribution of both acoustic and optical phonon to the band gap shrinkage and exciton linewidth broadening are discussed. Exciton binding energy of 16±1.5 meV was determined from the Arrhenius analysis. 相似文献
86.
The role of Al5Ti3 and h-Al2Ti long-period superstructures on the plastic properties of TiAl at room temperature is investigated on five single crystals with aluminium content comprised between 54.7 at.%, and 62.5 at.%. After annealing at 1200°C for 1?h, the Al5Ti3 superstructure develops in the L10 (γ) matrix upon increasing Al concentration except for Ti–62.5 at.%Al where h-Al2Ti substitutes for Al5Ti3. The CRSS for <110]{111} first increases abruptly with the development of the Al5Ti3-type ordering. Then, the CRSS reaches a plateau at which dislocations assemble in groups of four to prevent extra anti-phase boundary (APB) from being engendered during glide throughout the Al5Ti3 phase. In Ti–62.5 at.%Al, the CRSS for ordinary slip further increases upon the precipitation of h-Al2Ti in the L10 phase, whereas it decreases when the crystal is fully transformed into single-phased Al5Ti3. <101] superlattice dislocations are primarily activated under both the [210] and [1?1?8.6] load orientations irrespective of the Al concentration, but the dislocation microstructure strongly depends on orientation as well as on the degree of Al5Ti3 ordering. In the [210] orientation, the frequency of the decomposition of <101] dislocations into 1/2<110] and 1/2<112] dislocations decreases abruptly with the development of Al5Ti3. This is interpreted in terms of the increased difficulty to move ordinary dislocations. Under the [1?1?8.6] orientation, the density of faulted dipoles diminishes remarkably with the development of Al5Ti3. This is consistent with the transformation of the low energy extrinsic stacking fault of the L10 phase into a higher energy complex extrinsic stacking fault. 相似文献
87.
Reagen Ying‐Tai Su Li‐Ko Chiu Shan‐Wei Weng Ying‐Shiun Chou Raymond Chien‐Chao Tsiang 《Journal of Polymer Science.Polymer Physics》2012,50(4):280-288
White polymeric light‐emitting diode (WPLED) based on a single polymer, poly(3‐hexylthiophene‐alt‐9,9‐dioctylfluorene) (PTAF), has been successfully demonstrated. This conjugated alternating copolymer, PTAF, comprises 50 mol % of 3‐hexylthiophene which is an orange‐red color chromophore and 50 mol % 9,9‐dioctylfluorene which is a bluish‐green color chromophore. It was synthesized by Suzuki cross‐coupling reaction and has a molecular weight of 15,021 and polydispersity of 1.36. Nanocomposite consisting PTAF and graphene nanosheets enhances the optoelectronic properties and the device fabricated with a configuration of ITO/PEDOT:PSS/(PTAF + 1% graphene)/Ca/Al shows two‐color white electroluminescence with CIE 1931 coordinates of (0.28, 0.34). The white luminescence from a single polymer affords the WPLED device a simple structure and low fabrication cost. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
88.
We present in this paper a finite difference solver for Maxwell's equations in non‐staggered grids. The scheme formulated in time domain theoretically preserves the properties of zero‐divergence, symplecticity, and dispersion relation. The mathematically inherent Hamiltonian can be also retained all the time. Moreover, both spatial and temporal terms are approximated to yield the equal fourth‐order spatial and temporal accuracies. Through the computational exercises, modified equation analysis and Fourier analysis, it can be clearly demonstrated that the proposed triple‐preserving solver is computationally accurate and efficient for use to predict the Maxwell's solutions. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
89.
This paper describes the structural properties and electrical characteristics of thin Dy2O3 dielectrics deposited on silicon substrates by means of reactive sputtering. The structural and morphological features of these films after postdeposition annealing were studied by X-ray diffraction and X-ray photoelectron spectroscopy. It is found that Dy2O3 dielectrics annealed at 700 °C exhibit a thinner capacitance equivalent thickness and better electrical properties, including the interface trap density and the hysteresis in the capacitance-voltage curves. Under constant current stress, the Weibull slope of the charge-to-breakdown of the 700 °C-annealed films is about 1.6. These results are attributed to the formation of well-crystallized Dy2O3 structure and the reduction of the interfacial SiO2 layer. 相似文献
90.
Kai HofenSiegfried Weber Chiu Ping Candace ChanPeter Majewski 《Applied Surface Science》2011,257(7):2576-2580
This paper describes three inexpensive and fast analytical methods to characterise grafted particle surfaces. The reaction of silica with (3-aminopropyl)triethoxysilane, (3-mercaptopropyl)trimethoxysilane and N-(phosphonomethyl)iminodiacetic acid hydrate, respectively, leads to NH2-, SO3H- or COOH-functionalised silica, which were characterised by X-ray photoelectron spectrometry and titration in nonaqueous media as well as with two titration methods in a water-based environment. In the work presented, factors influencing the titrations are pointed out and solutions are presented to overcome these limiting factors are shown. 相似文献