全文获取类型
收费全文 | 30782篇 |
免费 | 5780篇 |
国内免费 | 3269篇 |
专业分类
化学 | 21926篇 |
晶体学 | 350篇 |
力学 | 1802篇 |
综合类 | 136篇 |
数学 | 2990篇 |
物理学 | 12627篇 |
出版年
2024年 | 135篇 |
2023年 | 695篇 |
2022年 | 1204篇 |
2021年 | 1293篇 |
2020年 | 1394篇 |
2019年 | 1373篇 |
2018年 | 1165篇 |
2017年 | 1048篇 |
2016年 | 1596篇 |
2015年 | 1514篇 |
2014年 | 1947篇 |
2013年 | 2396篇 |
2012年 | 2860篇 |
2011年 | 2871篇 |
2010年 | 1870篇 |
2009年 | 1782篇 |
2008年 | 1992篇 |
2007年 | 1741篇 |
2006年 | 1630篇 |
2005年 | 1280篇 |
2004年 | 975篇 |
2003年 | 763篇 |
2002年 | 755篇 |
2001年 | 589篇 |
2000年 | 467篇 |
1999年 | 592篇 |
1998年 | 511篇 |
1997年 | 498篇 |
1996年 | 492篇 |
1995年 | 426篇 |
1994年 | 342篇 |
1993年 | 281篇 |
1992年 | 279篇 |
1991年 | 224篇 |
1990年 | 202篇 |
1989年 | 152篇 |
1988年 | 92篇 |
1987年 | 79篇 |
1986年 | 104篇 |
1985年 | 73篇 |
1984年 | 37篇 |
1983年 | 44篇 |
1982年 | 28篇 |
1981年 | 22篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1957年 | 4篇 |
1923年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 28 毫秒
901.
Let (C,E,s) be an extriangulated category with a proper class ξ of E-triangles.We study complete cohomology of objects in (C,E,s) by applying ξ-projective resolutions and ξ-injective coresolutions constructed in (C,E,s).Vanishing of complete cohomology detects objects with finite ξ-projective dimension and finite ξ-injective dimension.As a consequence,we obtain some criteria for the validity of the Wakamatsu tilting conjecture and give a necessary and sufficient condition for a virtually Gorenstein algebra to be Gorenstein.Moreover,we give a general technique for computing complete cohomology of objects with finite ξ-Gprojective dimension.As an application,the relations between ξ-projective dimension and ξ-Gprojective dimension for objects in (C,E,s) are given. 相似文献
902.
Zengshun Jiang Xingqi An Yuqin Zhang Xuan Liu Xifeng Qin Yanjie Zhao Huilin Wang Guiyuan Liu Hongsheng Song 《中国光学快报(英文版)》2021,(4):56-61
After the three-dimensional self-affine fractal random surface simulation, we use the optical scattering theory to calculate the deep Fresnel region speckle(DFRS) under consideration of the more strict shadowing effect. The evolution of DFRS with the scattering distance and the intensity probability distribution are studied. It is found that the morphology of the scatterer has an antisymmetric relationship with the intensity distribution of DFRS, and the effect of micro-lenses on the scattering surface causes the intensity probability distribution of DFRS to deviate from the Gaussian speckle in the high light intensity area. 相似文献
903.
Core-Excited Molecules by Resonant Intense X-Ray Pulses Involving Electron-Rotation Coupling
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
It has been reported that electron-rotation coupling plays a significant role in diatomic nuclear dynamics induced by intense VUV pulses [Phys. Rev. A 102(2020) 033114; Phys. Rev. Res. 2(2020) 043348]. As a further step, we present here investigations of the electron-rotation coupling effect in the presence of Auger decay channel for core-excited molecules, based on theoretical modeling of the total electron yield(TEY), resonant Auger scattering(RAS) and x-ray absorption spectra(XAS) for two showcases of CO and CH~+ molecules excited by resonant intense x-ray pulses. The Wigner D-functions and the universal transition dipole operators are introduced to include the electron-rotation coupling for the core-excitation process. It is shown that with the pulse intensity up to 10~(16) W/cm~2, no sufficient influence of the electron-rotation coupling on the TEY and RAS spectra can be observed. This can be explained by a suppression of the induced electron-rotation dynamics due to the fast Auger decay channel, which does not allow for effective Rabi cycling even at extreme field intensities,contrary to transitions in optical or VUV range. For the case of XAS, however, relative errors of about 10% and 30% are observed for the case of CO and CH~+, respectively, when the electron-rotation coupling is neglected.It is concluded that conventional treatment of the photoexcitation, neglecting the electron-rotation coupling,can be safely and efficiently employed to study dynamics at the x-ray transitions by means of electron emission spectroscopy, yet the approximation breaks down for nonlinear processes as stimulated emission, especially for systems with light atoms. 相似文献
904.
挥发化合物发生-原子荧光法测定水中痕量锌 总被引:2,自引:0,他引:2
研究了挥发化合物发生-原子荧光光谱法测定环境水中痕量锌的可行性,着重优化了硼氢化钾与锌的反应条件,包括仪器和试剂条件.研究发现:适量镍离子和钴离子的存在能增强锌的荧光强度.在选定的最佳试验条件下,荧光强度与锌的质量浓度在0~1 200μg·L-1范围内呈线性关系.对标准空白进行11次测定,方法检出限为0.53μg·L-1;对400μg·L-1锌进行11次测定,其相对标准偏差(RSD)为3.0%,平行测定8份水样,RSD为3.6%;分析了4种不同水样并做加入不同浓度锌(Ⅱ)标准溶液时的回收率试验,结果在98%~104%之间. 相似文献
905.
Aiming at classifying the polarities over aspects, aspect-based sentiment analysis (ABSA) is a fine-grained task of sentiment analysis. The vector representations of current models are generally constrained to real values. Based on mathematical formulations of quantum theory, quantum language models have drawn increasing attention. Words in such models can be projected as physical particles in quantum systems, and naturally represented by representation-rich complex-valued vectors in a Hilbert Space, rather than real-valued ones. In this paper, the Hilbert Space representation for ABSA models is investigated and the complexification of three strong real-valued baselines are constructed. Experimental results demonstrate the effectiveness of complexification and the outperformance of our complex-valued models, illustrating that the complex-valued embedding can carry additional information beyond the real embedding. Especially, a complex-valued RoBERTa model outperforms or approaches the previous state-of-the-art on three standard benchmarking datasets. 相似文献
906.
Zhuwei Wang Zhicheng Liu Lihan Liu Chao Fang Meng Li Jingcheng Zhao 《Entropy (Basel, Switzerland)》2022,24(5)
With the rapid development of wireless sensor technology, recent progress in wireless sensor and actuator networks (WSANs) with energy harvesting provide the possibility for various real-time applications. Meanwhile, extensive research activities are carried out in the fields of efficient energy allocation and control strategy design. However, the joint design considering physical plant control, energy harvesting, and consumption is rarely concerned in existing works. In this paper, in order to enhance system control stability and promote quality of service for the WSAN energy efficiency, a novel three-step joint optimization algorithm is proposed through control strategy and energy management analysis. First, the optimal sampling interval can be obtained based on energy harvesting, consumption, and remaining conditions. Then, the control gain for each sampling interval is derived by using a backward iteration. Finally, the optimal control strategy is determined as a linear function of the current plant states and previous control strategies. The application of UAV formation flight system demonstrates that better system performance and control stability can be achieved by the proposed joint optimization design for all poor, sufficient, and general energy harvesting scenarios. 相似文献
907.
Twin-field quantum key distribution (TF-QKD) has attracted considerable attention because it can exceed the basic rate-distance limit without quantum repeaters. Its variant protocol, sending or not-sending quantum key distribution (SNS-QKD), not only fixes the security vulnerability of TF-QKD, but also can tolerate large misalignment errors. However, the current SNS-QKD protocol is based on the active decoy-state method, which may lead to side channel information leakage when multiple light intensities are modulated in practice. In this work, we propose a passive decoy-state SNS-QKD protocol to further enhance the security of SNS-QKD. Numerical simulation results show that the protocol not only improves the security in source, but also retains the advantages of tolerating large misalignment errors. Therefore, it may provide further guidance for the practical application of SNS-QKD. 相似文献
908.
A newly-developed numerical algorithm, which is called the new Generalized-α (G-α) method, is presented for solving structural dynamics problems with nonlinear stiffness. The traditional G-α method has undesired overshoot properties as for a class of α-method. In the present work, seven independent parameters are introduced into the single-step three-stage algorithmic formulations and the nonlinear internal force at every time interval is approximated by means of the generalized trapezoidal rule, and then the algorithm is implemented based on the finite difference theory. An analysis on the stability, accuracy, energy and overshoot properties of the proposed scheme is performed in the nonlinear regime. The values or the ranges of values of the seven independent parameters are determined in the analysis process. The computational results obtained by the new algorithm show that the displacement accuracy is of order two, and the acceleration can also be improved to a second order accuracy by a suitable choice of parameters. Obviously, the present algorithm is zero-stable, and the energy conservation or energy decay can be realized in the high-frequency range, which can be regarded as stable in an energy sense. The algorithmic overshoot can be completely avoided by using the new algorithm without any constraints with respect to the damping force and initial conditions.The English text was polished by Keren Wang. 相似文献
909.
Simplified electrochemical atom transfer radical polymerization (seATRP) using CuII–N-propyl pyridineimine complexes (CuII(NPPI)2) is reported for the first time. In aqueous solution, using oligo(ethylene glycol) methyl ether methacrylate (OEGMA), standard electrolysis conditions yield POEGMA with good control over molecular weight distribution (Đm < 1.35). Interestingly, the polymerizations are not under complete electrochemical control, as monomer conversion continues when electrolysis is halted. Alternatively, it is shown that the extent and rate of polymerization depends upon an initial period of electrolysis. Thus, it is proposed that seATRP using CuII(NPPI)2 follows an electrochemically-triggered, rather than electrochemically mediated, ATRP mechanism, which distinguishes them from other CuIIL complexes that have been previously reported in the literature.Simplified electrochemical atom transfer radical polymerization (seATRP) using CuII-pyridineimine complexes is reported and follows a previously unreported electrochemically triggered mechanism. 相似文献
910.
研究了振动波在含有环向表面裂纹的无限长圆柱壳中的传播特性.圆柱壳体的振动用Flügge方程来描述.运用线弹性断裂力学的理论,考虑到裂纹的张开、滑移和撕裂3种模式以及它们相互之间的耦合,利用分布的线弹簧来模拟裂纹并建立了裂纹所在区域的局部柔度矩阵,得到由此引起的附加位移和壳体中内力之间的关系.在入射波已知的情况下,根据裂纹两侧区域的位移和内力的连续性条件得到了反射和透射波的幅值系数.分析了入射波通过裂纹后的透射、反射系数与激励频率和裂纹尺寸之间的关系.为基于振动功率流方法识别圆柱壳表面损伤提供了理论基础. 相似文献