Scaling Behavior between Heat Capacity and Thermal Expansion in Solids

We experimentally analyze the heat capacity and thermal expansion of reference solids in a wide temperature range from several Kelvin to melting temperature,and establish a universal double-linear relation between the experimental heat capacity C_p and thermal expansion β,which is different from the previous models.The universal behavior between heat capacity and thermal expansion is important to predict the thermodynamic parameters at constant pressure,and is helpful for understanding the nature of thermal properties in solids.     

Optical properties of two-dimensional perovskites

The optical properties of two-dimensional (2D) perovskites recently receive numerous research focus thanks to the strong quantum and dielectric confinement effects. In addition to the strong excitonic effect at room temperature, 2D perovskites also have appealing features that their optical properties can be flexibly tuned by alternating organic or inorganic layers. Particularly, 2D chiral perovskites and 2D perovskites based heterostructures are emerging as new platforms to extend their functionalities. To optimize performance of 2D perovskites-based optoelectronic devices, it is critical to understand the fundamentals and explore the strategies to engineer their optical properties. This review begins with an introduction to the excitons and self-trapped excitons of 2D perovskites. Subsequently, inorganic/organic layer effects on optical properties and 2D perovskites based heterostructures are discussed. We also discussed the nonlinear optical properties of 2D perovskite. We are looking forward to that this review can stimulate more efforts to understand and optimize the optical properties of 2D perovskites.     

原子系统中偶极-偶极相互作用对量子存储支撑熵不确定度的调控研究

本文研究了Markovian过程和non-Markovian过程两种情况下,原子系统中偶极-偶极(D-D)相互作用和失谐量对两原子系统量子存储支撑(QMA)熵不确定度的调控作用.与Markovian过程相比,在non-Markovian过程中,由于库环境的记忆效应使得具有D-D相互作用的两原子系统QMA熵不确定度的演化行为呈现出振荡上升现象,且熵不确定度的上升趋势得到减缓,从而抑制了由系统量子噪声引起的退相干效应.此外,D-D相互作用对两原子系统QMA熵不确定度具有显著的调控能力,且D-D相互作用比失谐量的调控能力更强.     

强激光干扰下运动目标热损伤效应的有限元研究

为对空中飞行目标实施合理有效的强激光干扰,需要综合考虑采用的干扰方式、干扰效果以及考虑光斑偏移对干扰效果的影响。以热传导理论为基础,建立了激光辐照下移动目标温度场模型,采用伽辽金法建立了有限元分析模型,采用了等效比热容的方法处理材料的相变过程;并以Ansys软件为仿真平台,对目标在高斯分布的强激光作用下的温度场和热应力进行了综合仿真分析。结果表明,光斑与目标辐照区域的相对偏移对目标表面温度影响较大,对目标纵深破坏效应相对较小,应力变化主要发生在激光辐照区域,应力最大处也会随热源的移动而变化。     

Raman and optical absorption spectroscopic investigation of Yb-Er codoped phosphate glasses containing SiO_2

Yb-Er codoped Na2O-Al2O3-P2O5-xSiO2 glasses containing 0 - 20 mol% SiO2 were prepared successfully. The addition of SiO2 to the phosphate glass not only lengthens the bond between pS＋ and non-bridging oxygen but also reduces the number of P=O bond. In contrast with silicate glass in which there is only four-fold coordinated Si4＋, most probably there coexist [SiO4] tetrahedron and [SiO6] oetahedron in our glasses. Within the range of 0 - 20 mol% SiO2 addition, the stimulated emission cross-section of Era＋ ion only decreases no more than 10%. The Judd-Ofelt intensity parameters of Er3＋, Ω2 does not change greatly, but Ω4 and Ω6 decrease obviously with increasing SiO2 addition, because the bond between Er3＋ and O2- is more strongly eovalently bonded.     

激光单分子探测技术的研究

文中介绍利用激光激发分子荧光的方法探测液体中单个染料分子的新技术，以及作者自行设计和研制的激光单分子探测谱仪。通过探测“光子爆发”，把单个染料分子的荧光同很强的背景杂散光区别开来。进一步用８２ＭＨｚ高重复频率的锁模激光器和时间门符合技术，成功地消除了Ｒａｍａｎ散射光。目前该谱仪达到的检测限为灵敏区内仅有～７个Ｒ６Ｇ分子。     

高斯光束非线性“热像”效应研究

高功率激光系统中非线性“热像”强度可能达到光学元件损伤阀值，从而对系统的安全运行造成威胁.以往的非线性“热像”现象研究都是基于无限大平面光波背景，但实际系统中传输的是有限束宽光束.本文以高斯光束为例，基于无像差自聚焦理论分析了有限束宽光束的“热像”形成规律.结果表明，高斯光束“热像”的强度与位置在光束腰斑较小时与平面光波情况有明显不同，但光束腰斑较衍射物大得多时，高斯光束可以近似当作平面光波处理.     

医用硬性内窥镜畸变的评定基础和方法

建立医用硬性内窥镜畸变的评定基础和方法,用视轴对称的球面Z视场为模型来模拟体腔凹面特征,以建立内窥镜物像共轭的分析基础;运用光学原理并结合ISO9039:1994“光学和光学仪器光学系统质量评价———畸变的测定”的定义原则,并根据理论畸变的临床要求确定畸变定义;采用主光线追迹原理推导不同球面Z形状的畸变换算通式。创立了医用硬性内窥镜以单位相对畸变表述的定义和表达式,并导出变换视场面的畸变换算通用公式和测试方法。本文建立的畸变评定基础和方法适用于医用硬性内窥镜的标准应用。     

半导体桥等离子体温度的原子发射光谱法测量

半导体桥生成的等离子体由于温度高、尺度小、持续时间短等特点,对其温度的瞬态测量是个难题.本文采用高速数字存贮示波器应用原子发射光谱双谱线法对半导体桥等离子体温度进行了实时瞬态测量,并对在22μF电容下不同充电电压对半导体桥等离子体温度的影响进行了系统的研究,得到了22μF电容下等离子体最高温度与充电电压的关系式Tmax=700.6 115.2U.     

磁场中多原子极性晶体中体极化子的基态能量

研究磁场中多原子极性晶体中体极化子的性质,采用线性组合算符法,分别导出强,弱耦合情形下体极化子的基态能量。