Influence of nonlinear dispersion on modulation instability of coherent and partially coherent ultrashort pulses in metamaterials

The combination of dispersive magnetic permeability with nonlinear polarization leads to a series of nonlinear dispersion terms in the propagation equations for ultrashort pulses in metamaterials. Here we present an investigation of modulation instability (MI) of both coherent and partially coherent ultrashort pulses in metamaterials to identify the role of nonlinear dispersion in pulse propagation. The Wigner–Moyal equation for partially coherent ultrashort pulses and the nonlinear dispersion relation for MI in metamaterials are derived. Combining the standard MI theory with the unique properties of the metamaterial, the influence of the controllable first-order nonlinear dispersion, namely self-steepening, and the second-order nonlinear dispersion on both coherent and partially coherent MI, in both negative-index and positive-index regions of the metamaterial for all physically possible cases is analyzed in detail. For the first time to our knowledge, we demonstrate that the role of the second-order nonlinear dispersion in MI is equivalent to that of group-velocity dispersion (GVD) to some extent, and thus due to the role of the second-order nonlinear dispersion, MI may appear in the otherwise impossible cases, such as in the normal GVD regime. PACS 42.25.Kb; 42.65.Sf; 78.20.Ci     

[5‐(p‐alkoxy)phenyl‐10, 15, 20‐tri‐phenyl] porphyrin and their rare earth complex liquid crystalline

Three series of porphyrin liquid crystalline compounds, [5‐(p‐alkoxy)phenyl‐10, 15, 20‐tri‐phenyl] porphyrin and their rare earth complexes (Tb (III), Dy (III), Er (III), Yb (III)), with a hexagonal columnar discotic columnar(Col_h) phase have been synthesized. These compounds were characterized by elemental analysis, molar conductances, UV‐visible spectra, infrared spectra, luminescence spectra, and cyclic voltammetry. These compounds exhibit more than one mesophases, which transition points of temperature change from ?33.6 to 16.0 °C, and transition points of temperature for isotropic liquid also increase from 4.9 to 38.2 °C, with increasing chain length. Their surface photovoltage (SPV) response have also been investigated by the means of surface photovoltage spectroscopy (SPS) and field‐induced surface photovoltage spectroscopy (EFISPS). It was found that their SPV bands are analogous with the UV‐visible absorption spectra and derived from the same transition. Copyright © 2007 John Wiley & Sons, Ltd.     

The solid–liquid interface energy of organic crystals

A simple thermodynamic model, originally developed for metals based on the Gibbs–Thomson equation and related considerations for homogeneous nucleation, has been extended to predict the solid–liquid interface energy γ_sl of organic crystals. The model predictions correspond to available experimental and other theoretical results for 38 organic crystals. Copyright © 2007 John Wiley & Sons, Ltd.     

Preparation of hybrid film with superhydrophobic surfaces based on irregularly structure by emulsion polymerization

A superhydrophobic surface originated from quincunx-shape composite particles was obtained by utilizing the encapsulation and graft of silica particles to control the surface chemistry and morphology of the hybrid film. The composite particles make the surface of film form a composite interface with irregular binary structure to trap air between the substrate surface and the liquid droplets which plays an essential role in obtaining high water contact angle and low water contact angle hysteresis. The water contact angle on the hybrid film is determined to be 154 ± 2° and the contact angle hysteresis is less than 5°. This is expected to be a simple and practical method for preparing self-cleaning hydrophobic surfaces on large area.     

同步辐射X射线成像光束线劳厄双晶单色器设计

上海光源X射线成像光束线采用多极扭摆器(wiggler)作为辐射光源, 提出一种劳厄双弯晶单色器的设计方案. 计算结果显示, 可获得固定出口的平行单色光束, 能量调谐范围覆盖19—120keV, 在33keV时, 输出光子通量及通量密度分别为1.9×10¹³phs/s和3.8×10¹⁰phs/s/mm². 分析了劳厄晶体的聚焦及单色化性能, 计算了输出光子通量及单色器的热负载情况. 与传统的双平晶方案相比, 本设计在获得高通量和解决热负载等方面有明显的优越性, 并能有效控制热形变.     

Effect of preparation and metal content on the introduction of Fe in BEA zeolite, studied by DR UV-vis, EPR and Mössbauer spectroscopy

Fe-containing SiBEA zeolites were prepared by a two-step postsynthesis method: creation of vacant T-sites by dealumination of tetraethylammonium BEA zeolite with nitric acid and then impregnation of the resulting SiBEA zeolite with an aqueous solution of Fe(NO₃)₃. X-ray diffraction shows that iron is incorporated in SiBEA at lattice sites. The presence of Fe in its oxidation state +3 and at isolated tetrahedral sites for low metal content, was demonstrated by diffuse reflectance UV-vis, EPR and Mössbauer spectroscopy. For high iron content, diffuse reflectance UV-vis and Mössbauer spectra revealed the additional presence of extra-lattice FeO_x oligomers and superparamagnetic Fe-oxyhydroxide. Mössbauer spectroscopy identified superparamagnetic Fe-oxyhydroxide as the main phase when basic conditions are used for the preparation.     

Quantum Tricritical Point in the Spin-Boson Model with an Ohmic Bath

The dynamics of the spin-boson model with an Ohmic bath at finite temperature is studied by a variational calculation. Numerical solution of the self-consistent equation derived from the variational method shows that the transition from incoherent to coherent phases is discontinuous. It indicates that （T = 0, s = 1） is a tricritical point, i.e. the transition changes from continuous to discontinuous by tuning from T = 0 to T≠ 0. The discontinuous transition at finite temperature is analysed by Landau theory and the relation to the experimental observation on the coherent state is also discussed.     

Photoresponse of the In0.3Ga0.7N metal-insulator-semiconductor photodetectors

In0.3Ga0.7N metal-insulator-semiconductor （MIS） and metal-semiconductor （MS） surface barrier photodetectors have been fabricated. The In0.3Ga0.7N epilayers were grown on sapphire by metalorganic chemical vapour deposition （MOCVD）. The photoresponse and reverse current-voltage characteristics of the In0.3Ga0.7N MIS and MS photodetectors were measured. A best zero bias responsivity of 0.18 A/W at 450 nm is obtained for the In0.3Ga0.7N MIS photodetector with 10 nm Si3N4 insulator layer, which is more than ten times higher than the In0.3Ga0.7N MS photodetector. The reason is attributed to the decrease of the interface states and increase of surface barrier height by the inserted insulator. The influence of the thickness of the Si3N4 insulator layer on the photoresponsivity of the MIS photodetector is also discussed.     

光纤量子密码网络

 数字通信和数字信号处理领域的快速发展直接推动了20世纪后半叶兴起的信息革命。今天的数字信息系统仍然只在经典物理的范畴。每一个比特的信息都能完全的被经典器件描述，比如说一个晶体管或者微处理器的输入电压高低来代表0或者1。然而，信息也能通过量子力学的方式来处理和传输，这就产生了全新的量子信息科学。量子信息科学的一个典型应用就是量子密码术，在过去的十几年中发展十分迅速，美国和欧洲甚至都已经有比较成熟的商业产品。那么，什么是量子密码术，它的基本工作原理是什么，量子密码网络又是解决什么问题的。希望通过本文的叙述，读者能有大致的了解。     

Quantum secure direct communication and deterministic secure quantum communication

In this review article, we review the recent development of quantum secure direct communication (QSDC) and deterministic secure quantum communication (DSQC) which both are used to transmit secret message, including the criteria for QSDC, some interesting QSDC protocols, the DSQC protocols and QSDC network, etc. The difference between these two branches of quantum communication is that DSQC requires the two parties exchange at least one bit of classical information for reading out the message in each qubit, and QSDC does not. They are attractive because they are deterministic, in particular, the QSDC protocol is fully quantum mechanical. With sophisticated quantum technology in the future, the QSDC may become more and more popular. For ensuring the safety of QSDC with single photons and quantum information sharing of single qubit in a noisy channel, a quantum privacy amplification protocol has been proposed. It involves very simple CHC operations and reduces the information leakage to a negligible small level. Moreover, with the one-party quantum error correction, a relation has been established between classical linear codes and quantum one-party codes, hence it is convenient to transfer many good classical error correction codes to the quantum world. The one-party quantum error correction codes are especially designed for quantum dense coding and related QSDC protocols based on dense coding.