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131.
K. Ardhaoui J. Rogez A. Ben Chérifa M. Jemal P. Satre 《Journal of Thermal Analysis and Calorimetry》2006,86(2):553-559
Lanthanum-bearing silicate-oxyapatites or britholites, Ca10–xLax(PO4)6–x(SiO4)xO with 1≤x≤6, have been synthesized by solid state reaction
at high temperature. They were characterized by X-ray diffraction and IR spectroscopy.
Using two microcalorimeters, the heat of solution of these compounds have
been measured at 298 K in a solution of nitric and hydrofluoric acid. A strained
least squares method was applied to the experimental results to obtain the
solution enthalpies at infinite dilution, and the mixing enthalpy in two steps.
In the first step the mixing enthalpy obtained is referenced to the britholite
monosubstituted and to the oxysilicate. The mixing enthalpy referenced to
the oxyapatite and to the oxysilicate is then extrapolated. In order to determine
the enthalpies of formation of all the terms of the solution, thermochemical
cycles were proposed and complementary experiments were performed. The results
obtained show a decrease of the enthalpy of formation with the amount of Si
and La introduced in the lattice. This was explained by the difference in
the bond energies of (Ca–O, P–O) and (La–O, Si–O). 相似文献
132.
J. Kvasil I. N. Mikhailov R. Ch. Safarov B. Choriev 《Czechoslovak Journal of Physics》1978,28(8):843-856
Some generalizations of the model for odd nuclei suggested by Kerman are considered. The effects of phonon admixtures on matrix elements of Coriolis interaction are studied. Several schemes are considered for studying the role of non-adiabatic effects in the even-even core.One of the authors B. Ch. thanks L. A.Malov and V. O.Nesterenko for many discussions of some questions connected with the determination of the phonon-quasiparticle admixtures. 相似文献
133.
The transitions of relativistic electrons in a magnetic field with the emission of an antineutrino-neutrino pair are considered. Probabilities are obtained for electron transitions to the ground state and weakly excited states. It is shown that in the case of an ultrastrong magnetic field (HHo=m2c3/e=4.41·1013 G) such transitions made a considerable contribution to the total probability of the process.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 110–114, March, 1978.In conclusion, the authors express their profound gratitude to A. A. Sokolov for his attention to our work. 相似文献
134.
G. Dlubek J. Stejny Th. Lüpke D. Bamford K. Petters Ch. Hübner M. A. Alam M. J. Hill 《Journal of Polymer Science.Polymer Physics》2002,40(1):65-81
High‐quality positron lifetime measurements (70 million total counts) are reported for polyethylenes (PEs) of different crystallinities (Xc = 3–82%). The specific volumes of the crystalline and amorphous phases (Vc and Va, respectively) were estimated from density and wide‐angle X‐ray scattering (WAXS) experiments. Some samples (those with low values of Xc) were branched PEs, and those with high values of Xc were linear PEs for which Xc was varied with changes in the crystallization temperature. Both Vc and Va increase with decreasing Xc in the range 0% ≤ Xc ≤ 56% (the branched PEs) but are constant for Xc ≥ 56% (the linear PEs). The lifetime spectra were analyzed with the MELT and LIFSPECFIT routines. Artifacts that can appear in the spectrum analysis were checked via an analysis of computer‐generated spectra. Four lifetime components appeared in all of the PEs; the two long‐lived ones are attributed to pick‐off annihilation of ortho‐positronium (o‐Ps) in crystalline regions (τ3) and in holes of the amorphous phase (τ4). With increasing Xc, τ3 decreases from about 1.2 to 1 ns, τ4 decreases from 3.0 to 2.5 ns, and the intensity I4 decreases from 29 to 0%. An increase in I3 from 6 to 12% was observed. A comparison with simulations shows that the true I3 value approaches 0 for Xc → 0%. The decrease in I4 is weaker than the increase in Xc; this leads to the conclusion that the apparent specific o‐Ps yield in the amorphous phase I4Xc increases with Xc. Possible reasons for this surprising results are discussed. The fractional free hole volume [h = (Va ? Vocc)/Va, where Vocc is the crystalline occupied volume] was estimated from density and WAXS results. Between Xc = 0 and 56%, h decreases from 0.151 to 0.090, but it does not change further above Xc = 56%. The mean size (v) of the local free volumes (holes) estimated from τ4 decreases from 200 to 150 Å3. The number density of holes (Nh) calculated from these values (Nh = h/v) also decreases from 0.8 to 0.6 nm?3 in the range 0% ≤ Xc ≤ 56%. The values of Va, Vc, h, and Nh increase with an increasing degree of branching but do not vary for linear PEs. The possible influence of a crystalline–amorphous interfacial phase (three‐phase model) on the observed lifetime parameters is also discussed. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 40: 65–81, 2002 相似文献
135.
Summary The retention, enantionselectivity and enantiomeric elution order of racemic propranolol (PP) and its ester derivatives (O-acetyl,-propionyl,-butyrul and-valeryl PP) on an 1-acid glycoprotein (AGP)-bonded column have been investigated by changing eluent composition (eluent pH, buffer concentration, type and content of organic modifier). The retention of these cationic solutes, PP and its ester derivatives, was influenced by eluent pH, ionic strength and organic modifier content. The enantioselectivity was dependent on eluent pH and type of organic modifier. Reversal of the enantiomeric elution order of ester derivatives of PP (O-propionyl-butyryl) and-valeryl PP) occurred around eluent pH 6–7. These results suggst that chiral recognition or binding properties may be altered by the change in eluent composition, espeically eluent pH and type of organic modifier. 相似文献
136.
Staszczuk P. Sternik D. Chądzyński G. W. 《Journal of Thermal Analysis and Calorimetry》2003,71(1):173-182
Using thermo-analytical and sorptometric methods physicochemical properties and especially surface heterogeneity of HgBa2Ca2Cu3O8+, (Hg-1223) was investigated. The desorption energy distribution was derived from mass loss Q-TG and differential mass loss Q-DTG curves of thermodesorption in quasi-isothermal conditions of pre-adsorbed n-octane and water vapour. It is shown that the superconducting Hg-1223 phase is highly sensitive to water vapours. The mechanism of water adsorption depends largely on the activation time. By water vapour saturation in a period of 90 min, physisorption takes place. Prolonged periods result in a chemical decomposition. From nitrogen ad- and desorption isotherms the fractal dimension of superconductors were calculated. A new approach is proposed to calculate fractal dimension from Q-TG curves.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
137.
The kinetics of decomposition of hydrogen peroxide have been studied on mixed Fe(III)–Al(III) hydroxide and oxide catalysts. While iron hydroxide possesses considerable catalytic activity, aluminium hydroxide has very little activity. The rate of decomposition on mixed hydroxides increases with increasing concentration of aluminium hydroxide up to about 1.5 mol% and decreases thereafter. The mixed oxides possess negligible activity compared to the corresponding hydroxides. The energy of activation, as calculated from the Arrhenius equation, is 10.1 kcal/mol for sample S4, containing 1.52 mol% of alumina. The rate of decomposition of S4 increases with increasing pH up to 6.8 and decreases thereafter. The rate is first order in all these cases. A suitable mechanism is suggested.
Fe(III)–Al(III). , . , 1,5 , . . , , 10,1 / S4, 1,52 . S4 pH 6,8, . . .相似文献
138.
Z. F. Ch. Kachani 《Fresenius' Journal of Analytical Chemistry》1965,213(6):427-430
Zusammenfassung Es wurde festgestellt, daß die Farbe einer Actinomycin C-Lösung in sehr engem Zusammenhang mit der Konzentration dieser Substanz in der Lösung steht. Die photometrisch ermittelte Farbabnahme geht mit dem durch mikrobiologischen Test bestimmten Aktivitätsverlust in vieler Hinsicht parallel. Bei der Aktivitätsabnahme spielt die Art des Lösungsmittels eine wichtige Rolle. Die stärkste Aktivitätsminderung nach dem Erhitzen wurde in bidest. Wasser, die geringste Aktivitätsabnahme in Glykokollpuffer beobachtet.
Summary The concentration of active actinomycin C in a solution can be determined quite simply by a photometric method. Comparison of results showed good agreement between the microbiological tests and the photometric method. Actinomycin C suffers most loss of activity by heating when dissolved in distilled water and least when dissolved in glycine buffer.相似文献
139.
Several definitions of the pressure are introduced for one-component systems and shown to be nonequivalent in the presence of a rigid neutralizing background. Relations between these pressures are derived for finite and infinite systems; these relations depend on the asymptotic behavior of the force at infinity, with the Coulomb force at the borderline between different properties. It is argued that only one of those definitions is physically acceptable and its properties are discussed in relation to the asymptotic behavior of the force. It is seen in particular that a knowledge of the state of the infinite system is not sufficient to determine its thermodynamic properties. The results are illustrated by some typical examples.For example, for two-dimensional systems with three-dimensional Coulomb interaction see refs. 2–4. 相似文献
140.
J. Ch. Pomerol 《Mathematical Programming》1980,19(1):352-355
We give a new minisup theorem for noncompact strategy sets. Our result is of the type of the Matthies-Strang-Christiansen minimax theorem where the hyperplane should be replaced by any closed convex set. As an application, we derive a slight generalization of the Matthies-Strang-Christiansen minimax theorem. 相似文献