原位氧化还原沉淀水热合成法制备LixMn2O4尖晶石

Li xMn2O4尖晶石是新一代的锂离子二次电池正极材料 [1], 其合成方法对材料的电化学性质影响很大[2].常规合成大多采用高温固相反应法, 此法具有反应温度高, 反应时间长, 容易产生缺陷和产物不纯净等缺点, 导致所合成的锂离子二次电池正极材料的性能较差. 目前用水热合成法制备电池正极材料Li xMn2O4尖晶石尚未见文献报道. 本文在常规水热合成法的基础上采用原位氧化还原沉淀水热合成法 [3]制备前驱物, 该法合成条件更温和, 而且使材料的综合性能得到了改善和提高.      

Theoretical study of structure and stability of fullerene derivative: C50O

A total of eight possible isomers of C₅₀O, an oxide of fullerene C₅₀ (D_5h), have been investigated by B3LYP/3‐21G calculations. The isomer, which has an annulene‐like structure with oxygen bridging across a [5,6] type C? C bond at the site between the pole and the equatorial belt, is found being the ground state of C₅₀O. Four isomers are relatively more stable and the energy differences between them are not large. This result indicates that more than one C₅₀O isomer will coexist once C₅₀O is synthesized. The relative stabilities of the C₅₀O isomers may be determined mainly by the strain release and by the formation of the cyclic phenylene substructure at the equatorial belt of the cage. The calculated nucleus independent chemical shifts (NICS) of the C₅₀O isomers will be useful because from them one can expect outstanding NMR properties that can lead to their identification and characterization. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2005     

Facile Total Synthesis of (±)‐Nimbiol

A facile total synthesis of (±)‐nimbiol 1 has been achieved. In order to decrease the dioxo byproduct 2a , an improved oxidation system of CrO₃/H₂O/HOAc/NaOAc was used.     

A New Method to Investigate the Clustering Phenomena in Supercritical Fluids

EstimationoflocaldensityofsolventaboutthesoluteSolvatochromicbehaviorsofspectroscopicprobesarewidelyusedtoestimatethesol-ventstrengthofsupercriticalfluids(SCF,).i-3lnthiswork,thesolvatochrondcshiftofthen-n*transitionbandforacetone(O.o37mo1.L-')insupercrihcal(SC)CO2wasde-terminedbyUVspectroscopytostUdythesolvationeffect.TheMcRae-BaylissexpressionbasedonthedielectriccontinUUInmodelgivestherelahonshipbetWeenso1vatochromicshiftandpo1arizabilityofnonPolarsolvents4-5asfollows:wherevisthewave…     

Cover Picture: Highly Regioselective Sequential 1,1‐Dihydrosilylation of Terminal Aliphatic Alkynes with Primary Silanes (Chin. J. Chem. 5/2019)

The cover picture shows that sequential 1,1‐dihydrosilylation of terminal aliphatic alkynes with primary silanes enabled by one earth‐abundant cobalt catalyst has been developed. This protocol is operationally simple using readily available aliphatic alkynes, including simple acetylene and complex drug derivative, for efficient access to valuable gem‐bis(dihydrosilyl)alkanes in highly regioselective and atom‐economic manners. Corresponding asymmetric transformations are achieved with excellent enantioselectivities. More details are discussed in the article by Lu et al. on page 457–461.

     

The Reaction and Applied Study of the Amide and P_2S_5

It is usually reported that reaction between carbonyl and P2S5 produce thiono group compound. The Products from carbonyl after ammonolysis and hydrazinolysis have the very import applied value in the synthesize of heterocyclic compound. Sulfuration reation if a nucleophilic attack, SPS2 anionsid obtained from P2S5 in the organic sovent, rather easier than thereationsof scheeren’s reagent. The reation mechanism is as follows: The reation speed has something todo with the electronegative of…     

Simple and controllable synthesis of highly dispersed Pt-Ru/C catalysts by a two-step spray pyrolysis process

A carbon supported Pt-Ru catalyst with uniform distribution and small average size of the Pt-Ru particles was synthesized using a two-step spray pyrolysis (SP) method; the electrocatalytic activity of the prepared catalyst for methanol oxidation is better than that of the standard commercial catalyst.     

二吡啶四硝基酞菁钴的合成及光谱—电化学性质研究

本文报道了以钼酸铵为催化剂,将4—硝基邻苯二甲酸酐、脲和氯化铵混合,于220℃加热合成四硝基酞菁钴,将此配合物溶于吡啶,于115℃加热反应6天合成了二吡啶四硝基酞菁钻配合物。并对二吡啶四硝基酞菁钴的氧化还原半波电势、电解氧化还原产物的电子吸收光谱进行了研究。