Investigation of self-adaptive algebraic tomography for gas reconstruction in larger temperature range by multiple wavelengths absorption spectroscopy

We develop a self-adaptive algebraic tomography algorithm （SAATA） to investigate the simultaneons reconstruction of concentration and temperature distributions in larger temperature range from two views. The simplified optical arrangement with fewer projections is realized by extension of spectral information at multiple wavelengths, resulting in great potential in applications of practical combustion diagnosis. Tile results show SAATA can perform much better reconstructions in 300 3000 K temperature range than genetic simulated annealing algorithm and least-square orthogonal-triangular decomposition method with two- wavelength scheme. More phantoms are created to demonstrate the capability of SAATA to capture the peaks and adapt for both flat and sharp temperature distributions. Meanwhile, the advantage of high stability ensures better reconstruction performance at noise levels from 0.1% to 10% in projections.     

基于光子数目比较的激光测距法

提出了一种新颖的激光测距方法。该方法避开了传统激光测距法中使用复杂辅助电子设备对脉冲计时或比较相位差的过程,而主要通过光学手段分析和提取待测距离信息,最终通过比较大量光子数目的方法求得待测距离。并利用单轴晶体的双折射和全内双反射性质,用特殊结构的单块LiNbO3晶体设计了实施该方法的主体装置。结果表明,该激光测距法同目前普遍使用的激光测距法相比,不但简化了结构,而且有很高的测距精度,从而为激光测距开拓了一种新的思路。     

脉冲激光频域干涉技术在超快动力学物理中的应用

介绍了一种具有fs时间分辨力的超短脉冲激光频域干涉测试技术,详细论述了该技术的工作原理和系统构成,指出传输时间差和相位差是影响频域干涉条纹周期的主要因素。采用脉冲激光频域干涉仪测量了200 nm厚度铝膜在波长800 nm、单脉冲能量0.7 mJ、脉宽35 fs脉冲激光作用下的运动速度剖面。在单次飞秒脉冲激光作用下,铝膜自由面的运动速度峰值可达960 m/s,速度剖面的上升前沿小于5.77 ps,表明脉冲激光频域干涉技术可用于测量材料在超快脉冲激光作用下的冲击动力学参数。     

A biosensor based on graphene nanoribbon with nanopores: a first-principles devices-design

A biosensor device,built from graphene nanoribbons(GNRs) with nanopores,was designed and studied by firstprinciples quantum transport simulation.We have demonstrated the intrinsic transport properties of the device and the effect of different nucleobases on device properties when they are located in the nanopores of GNRs.It was found that the device’s current changes remarkably with the species of nucleobases,which originates from their different chemical compositions and coupling strengths with GNRs.In addition,our first-principles results clearly reveal that the distinguished ability of a device’s current depends on the position of the pore to some extent.These results may present a new way to read off the nucleobases sequence of a single-stranded DNA(ssDNA) molecule by such GNRs-based device with designed nanopores     

An appraisal of the Suzuki cross-coupling reaction for the synthesis of novel fluorescent coumarin derivatives

We report the chemical design and development of 3-aryl-substituted 7-alkoxy-4-methylcoumarins with enhanced fluorogenic properties. The 3-aryl substituents are installed via an optimized Suzuki–Miyaura cross-coupling (SMC) reaction between a 7-alkoxy-3-bromo-4-methylcoumarin and aryl boronic MIDA esters using Pd(OAc)₂/XPhos in a catalytic system with K₂CO₃ in aqueous THF. Under these conditions, an exocyclic ester functionality is found to be unaffected. Subsequent saponification revealed a carboxylic acid functionality that is suitable for conjugation reactions. Evaluation of their fluorescence properties indicated that the installed 3-heteroaryl substituent, particularly benzofuran-2-yl, resulted in a significant red shift of both the excitation and emission wavelengths.     

Purification and Characterization of the Glucoside 3-Dehydrogenase Produced by a Newly Isolated Sphingobacterium faecium ZJF-D6 CCTCC M 2013251

A soluble glucoside 3-dehydrogenase (G3DH) was purified from a newly isolated Sphingobacterium faecium ZJF-D6 CCTCC M 2013251. The enzyme was purified to 35.71-fold with a yield of 41.91 % and was estimated by sodium dodecyl sulphate–polyacrylamide gel electrophoresis with a molecular mass of 62 kDa. The sequences of two peptides of the enzyme were all contained in a GMC family oxidoreductase (EFK55866) by mass spectrometry analysis. The optimal pH of the enzyme was around 6.2. The enzyme was stable within a pH range of 5.0–6.6 and was sensitive to heat. G3DH from S. faecium exhibited extremely broad substrate specificity and well regioselectivity to validoxylamine A. The enzyme was completely inhibited by Hg₂Cl₂ and partly inhibited by Cu²⁺, Fe²⁺, Ca²⁺, and Cd²⁺. The apparent K _m values for D-glucose, sucrose, and validoxylamine were calculated to be 1.1, 1.7, and 2.1 mM, respectively. With this purified enzyme, 3-keto sucrose was prepared at pH 5.0, 30 °C for 10 h with a yield of 28.7 %.