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941.
Zhengzheng Zhou Henry H. Y. Tong Liang Li Fanny L. Y. Shek Yang Lv Ying Zheng 《Crystal Research and Technology》2015,50(7):538-548
This study performed a solid‐state characterization of ursolic acid (UA) crystalline forms, a poorly water‐soluble triterpene with anticancer activity. Two new polymorphs (form I, II), two new solvates (propanol and isopropanol solvates), and a known ethanol solvate were determined and elucidated using a combination of multi‐techniques, including X‐ray single crystal and powder diffraction, Fourier transform infrared spectroscopy (FT‐IR), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). A colorless single crystal of UA was grown from a propanol solution, and its crystalline structure was determined through X‐ray single crystal diffraction. It was determined that the propanol solvate was crystallized in the orthorhombic space group P212121 with unit‐cell parameters a = 7.17200 (8) Å, b = 12.24100 (16) Å, c = 33.8950 (4) Å and Z = 4. The ethanol solvate and propanol solvate were isomorphous crystals. The results of the thermal analysis demonstrate that form I is a meta‐stable form, while form II is a stable form that is monotropically related. 相似文献
942.
Wenrui Chen Ziyu Lv Peng Xiong Prof. Dr. Taolei Sun 《Angewandte Chemie (International ed. in English)》2014,53(8):2124-2129
For chiral gels and related applications, one of the critical issues is how to modulate the stereoselective interaction between the gel and the chiral guest precisely, as well as how to translate this information into the macroscopic properties of materials. Herein, we report that this process can also be modulated by nonchiral solvents, which can induce a chiral‐interaction reversion for organogel formation. This process could be observed through the clear difference in gelation speed and the morphology of the resulting self‐assembly. This chiral effect was successfully applied in the selective separation of quinine enantiomers and imparts “smart” merits to the gel materials. 相似文献
943.
Dr. Weiqiang Lv Dr. Xuemei Yang Dr. Wei Wang Yinghua Niu Dr. Zhongping Liu Prof. Weidong He 《Chemphyschem》2014,15(13):2688-2691
In the field of oriented‐attachment crystal growth, one‐dimensional nanocrystals are frequently employed as building blocks to synthesize two‐dimensional or large‐aspect‐ratio one‐dimensional nanocrystals. Despite recent extensive experimental advances, the underlying inter‐particle interaction in the synthesis still remains elusive. In this report, using Ag as a platform, we investigate the van der Waals interactions associated with the side‐by‐side and end‐to‐end assemblies of one‐dimensional nanorods. The size, aspect ratio, and inter‐particle separation of the Ag precursor nanorods are found to have dramatically different impacts on the van der Waals interactions in the two types of assemblies. Our work facilitates the fundamental understanding of the oriented‐attachment assembling mechanism based on one‐dimensional nanocrystals. 相似文献
944.
The chitosan-microparticles reinforced cellulose biocomposite sponges regenerated from ionic liquid were prepared and characterized. Fourier transform infrared (FTIR) spectroscopy confirmed that the cellulose dissolved in 1-allyl-3-methylimidazolium chloride without derivatization. Chitosan particles as reinforcement were incorporated into the cellulose matrix. FTIR spectra indicated hydrogen bonding between hydroxyl groups of cellulose and chitosan. The biocomposite sponges showed uniform three-dimensional interconnected porous structures. The breaking strength of the sponges increased significantly, from 0.09 to 0.32 MPa with the addition of 1.0 wt% chitosan. The sponges also demonstrated excellent antibacterial activity against S. aureus and E. coli with the average inhibition zone diameters >2 mm and the inhibition rate higher than 80 %. Furthermore, the biocomposite sponges exhibited good moisture penetrability and high porosity. The water uptake ability of the sponge was >25 times of its weight in water with a fast swelling. The chitosan/cellulose composite sponge is expected to be a promising material for potential applications as wound dressing. 相似文献
945.
Determination of bisphenol A, 4‐octylphenol,and 4‐nonylphenol in soft drinks and dairy products by ultrasound‐assisted dispersive liquid–liquid microextraction combined with derivatization and high‐performance liquid chromatography with fluorescence detection 下载免费PDF全文
Tao Lv Xian‐En Zhao Shuyun Zhu Fei Qu Cuihua Song Jinmao You Yourui Suo 《Journal of separation science》2014,37(19):2757-2763
A novel hyphenated method based on ultrasound‐assisted dispersive liquid–liquid microextraction coupled to precolumn derivatization has been established for the simultaneous determination of bisphenol A, 4‐octylphenol, and 4‐nonylphenol by high‐performance liquid chromatography with fluorescence detection. Different parameters that influence microextraction and derivatization have been optimized. The quantitative linear range of analytes is 5.0–400.0 ng/L, and the correlation coefficients are more than 0.9998. Limits of detection for soft drinks and dairy products have been obtained in the range of 0.5–1.2 ng/kg and 0.01–0.04 μg/kg, respectively. Relative standard deviations of intra‐ and inter‐day precision for retention time and peak area are in the range of 0.47–2.31 and 2.76–8.79%, respectively. Accuracy is satisfactory in the range of 81.5–118.7%. Relative standard deviations of repeatability are in the range of 0.35–1.43 and 2.36–4.75% for retention time and peak area, respectively. Enrichment factors for bisphenol A, 4‐octylphenol, and 4‐nonylphenol are 170.5, 240.3, and 283.2, respectively. The results of recovery and matrix effect are in the range of 82.7–114.9 and 92.0–109.0%, respectively. The proposed method has been applied to the determination of bisphenol A, 4‐octylphenol, and 4‐nonylphenol in soft drinks and dairy products with much higher sensitivity than many other methods. 相似文献
946.
PAN BingCai WAN ShunLi ZHANG ShuJuan GUO QingWei XU ZhengCheng LV Lu ZHANG WeiMing 《中国科学:化学(英文版)》2014,57(5):763-771
Tl(I)in water even at a trace level is fatal to human beings and the ecosystem.Here we fabricated a new polymer-supported nanocomposite(HMO-001)for efficient Tl(I)removal by encapsulating nanosized hydrous manganese dioxide(HMO)within a polystyrene cation exchanger(D-001).The resultant HMO-001 exhibited more preferable removal of Tl(I)than D-001 and IRC-748,an iminodiacetic chelating polymer,particularly in the presence of competing Ca(II)ions at greater levels in solution.Such preference was ascribed to the Donnan membrane effect caused by D-001 as well as the specific interaction between Tl(I)and HMO.The adsorbed Tl(I)was partially oxidized into insoluble Tl(III)by HMO at acidic pH,while negligible oxidation was observed at circumneutral pH.The exhausted HMO-001 was amenable to efficient regeneration by binary NaOH-NaClO solution for at least 10-cycle batch runs without any significant capacity loss.Fixed-bed column test of Tl(I)-contained industrial effluent and natural water further validated that Tl(I)retention on HMO-001 resulted in a conspicuous concentration drop from 1.3 mg/L to a value lower than 0.14 mg/L(maximum concentration level for industrial effluent regulated by US EPA)and from 1–4?g/L to a value lower than 0.1?g/L(drinking water standard regulated by China Health Ministry),respectively. 相似文献
947.
Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong π–π Interactions 下载免费PDF全文
Dr. Xiaoxia Lv Dr. Liangjun Li Xiaoming Sun Prof. Hongyu Zhang Jinjun Cai Chao Wang Prof. Sifu Tang Prof. Xuebo Zhao 《化学:亚洲杂志》2014,9(3):901-907
The microporous coordination polymer [Co(H2L)(bipy)0.5] ? 2 H2O ( 1 , bipy=4,4′‐bipyridine) was synthesized on the basis of the V‐shaped flexible diphosphonate ligand (2,4,6‐trimethyl‐1,3‐phenylene)bis(methylene)diphosphonic acid (H4L) and the auxiliary bipy ligand under hydrothermal conditions. The structure of this compound was characterized by single‐crystal X‐ray diffraction. By joining the diphosphonate ligands and bipy through tetrahedral [CoO3N] clusters, a 2D square grid layered network was formed. Further stacking of these layers on the basis of π–π interactions resulted in a pseudo‐3D microporous network with 1D channels running through the a axis. Gas sorption studies for CO2, H2, CH4, N2, and O2 on this coordination polymer were performed, and the results revealed interesting dynamic and hysteresis sorption behavior toward H2 at low temperature. 相似文献
948.
The longitudinal wave propagating in an elastic rod with a variable cross-section owns wide engineering background, in which the longitudinal wave dissipation determines some important performances of the slender structure. To reproduce the longitudinal wave dissipation effects on an elastic rod with a variable cross-section, a structure-preserving approach is developed based on the dynamic symmetry breaking theory. For the dynamic model controlling the longitudinal wave propagating in the elast... 相似文献
949.
Glycine, as a kind of commercially available and inexpensive ligand, is used to prepare an air-stable and water-soluble catalyst used in Sonogashira reaction in our study. In the presence of 1% [PdCl2(NH2CH2COOH)2] as catalyst, excellent catalytic activity towards the Sonogashira coupling of aryl iodides with terminal alkynes without using any additive such as Cu(I)-cocatalyst is observed in a mixture of water and acetone (3/3 mL) under air at 60 °C with NaOH as a base, giving products in good to excellent yields. 相似文献
950.
Y. Z. Song K. X. Wei J. S. Lv 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2013,87(13):2272-2278
DFT calculations were performed for diphenyl sulfide and diphenyl sulfone. The electrochemistry of diphenyl sulfide on the gold electrode was investigated by cyclic voltammety and the results show that standard electrode potential for redox couple diphenyl sulfone/diphenyl sulfide is 1.058 V, which is consistent with that of 1.057 calculated at B3LYP/6-31++G(d,p)-IEFPCM level. The front orbit theory and Mulliken charges of molecular explain well on the oxidation of diphenyl sulfide in oxidative desulfurization. According to equilibrium theory the experimental equilibrium constant in the oxidative desulfurization of H2O2, is 1.17 × 1048, which is consistent with the theoretical equilibrium constant is 2.18 × 1048 at B3LYP/6-31++G(d,p)-IEFPCM level. 相似文献