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91.
Inside Cover: Regulating Molecular Recognition with C‐Shaped Strips Attained by Chirality‐Assisted Synthesis (Angew. Chem. Int. Ed. 43/2015)
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92.
Christian R. Samanamu Charles S. Weinert 《Journal of organometallic chemistry》2011,696(23):3721-3726
The formation of 3-aminocrotononitrile and 4-amino-2,6-dimethylaminopyrimidine has been observed during the course of the hydrogermolysis reaction between a germanium amide and a germanium hydride, either as the free amines or bound to germanium as ligands consisting of their conjugate bases. These species arise from the dimerization or trimerization of acetonitrile, and have only been detected when germanium amides having substantial steric bulk at the germanium center are employed in the reaction. The isolation of germanium-bound 3-aminocrotononitrile compounds suggests that α-germyl nitrile species R3GeCH2CN that result from the reaction of the germanium amides R3GeNMe2 with CH3CN solvent also can further react with CH3CN to generate the 3-aminocrotononitrile and 4-amido-2,6-dimethylaminopyrimidine species. The two germanes Ph3Ge[NHC(CH3)CHCN] and 2,6-dimethyl-4-(triphenylgermylamino)pyrimidine have been prepared and structurally characterized, and the conversion of Ph3GeCH2CN to Ph3Ge[NHC(CH3)CHCN] and 2,6-dimethylamino-4-(triphenylgermylamino)pyrimidine as well as the conversion of Ph3Ge[NHC(CH3)CHCN] to 2,6-dimethyl-4-(triphenylgermylamino)pyrimidine in acetonitrile solvent has been observed using 1H NMR spectroscopy. 相似文献
93.
Patrícia Los Weinert Jo?o Roberto Fernandes Leonardo Pezza Helena Redigolo Pezza 《Analytical sciences》2007,23(12):1383-1389
A sensitive flow-injection (FI) procedure with spectrophotometric detection in a micellar medium is proposed for the determination of novalgin. The method is based on the instantaneous formation of a red-orange product (lambda(max) = 510 nm) after the reaction between novalgin and p-dimethylaminocinnamaldehyde (p-DAC) in a dilute acid medium. The sensitivity of this reaction was increased by a factor of 5.6 in the presence of sodium dodecyl sulfate (SDS). Experimental design methodologies were used to optimize the chemical and FI variables. The calibration curve was linear in the range of 1.45 x 10(-6) to 2.90 x 10(-5) mol L(-1) with an excellent correlation coefficient (r = 0.9999). The detection limit was 1.31 x 10(-7) mol L(-1) (n = 20, RSD = 2.0%). No interferences were observed from the common excipients. The results obtained by the proposed method were favorably compared with those given by the iodometric reference method at 95% confidence level. 相似文献
94.
Formation of [Bi11]3−, A Homoatomic,Polycyclic Bismuth Polyanion,by Pyridine‐Assisted Decomposition of [GaBi3]2−
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Dipl.‐Chem. Bastian Weinert Armin Rainer Eulenstein Dr. Rodica Ababei Prof. Dr. Stefanie Dehnen 《Angewandte Chemie (International ed. in English)》2014,53(18):4704-4708
Until now, polycyclic bismuth polyanions have not been known—thus discriminating bismuth from its lighter congeners. However, the synthesis of [K([2.2.2]crypt)]3(Bi11)?2 py?tol, allows us to present the first structurally characterized homoatomic, polycyclic bismuth polyanion, which exhibits the [P11]3? “ufosan” structure. It was obtained upon treatment of [K([2.2.2]crypt)]2(GaBi3)?en with the solvent pyridine. The binary Zintl anion [GaBi3]2? decomposes under oxidative coupling of pyridine molecules and release of H2 to form the title compound. The unprecedented reaction, its products and by‐products were investigated by means of spectroscopy, spectrometry, and DFT studies. All findings reveal the specific reaction conditions to be crucial for the formation of the [Bi11]3? ion—and indicate the possibility of the generation and isolation of further, large bismuth polyanions. 相似文献
95.
Marcelo Lazzarotto Patrícia Los Weinert Márcio Lazzarotto 《Journal of inclusion phenomena and macrocyclic chemistry》2014,80(3-4):313-322
The Gibbs energy of extraction experiments of ionophoric calixarenes with alkali metals from the literature have been correlated with electronic parameters of their “monomeric” structures calculated by AM1, PM3 and PM7 algorithms: energies of molecular orbitals and charge densities of oxygen and nitrogen atoms. We observed general correlations of the extraction constants with the charge on the carbonyl oxygen and specific correlations with MO-energy using the covalent term of the Klopman–Salem equation. The correlations for calixarenes with 5 and 6 phenolic units were very poor, and we attributed to the structural flexibility, which allow different optimized conformations for metal binding. 相似文献
96.
We present evidence for a nonsingular origin of the Universe with intial conditions determined by quantum physics and relativistic
gravity. In particular, we establish that the present temperature of the microwave background and the present density of the
Universe agree well with our predictions from these intial conditions, after evolution to the present age using the Einstein-Friedmann
equation. Remarkably, the quantum origin for the Universe naturally allows its evolution at exactly the critical density.
We also discuss the consequences of these results to some fundamental aspects of quantum physics in the early Universe. 相似文献
97.
98.
Using a non-resonant transient grating technique the mobility and recombination lifetime of free carriers in type I and type II QW heterostructures is measured. For the lattice-matched type II CaxSr1−xF2/GaAs structures the diffusion coefficient as well as the diffraction efficiency is found to be affected by carrier separation into different layers. For GaAs/GaAlAs superlattices a strong influence of the barrier parameters on the inplane diffusion of heavy holes is observed. 相似文献
99.
100.
E. Asmus und H. Weinert 《Fresenius' Journal of Analytical Chemistry》1970,249(3):179-181
Zusammenfassung Zur extraktionsphotometrischen Zinnbestimmung in Mo-haltigen Stählen wird Zinn nach Lösen der Stahlprobe in einem Gemisch aus Schwefelsäure und Perhydrol als SnJ4 mit Benzol extrahiert, anschließend in eine wäßrige Lösung überführt und mit 3-Pyridylnuoron photometrisch bestimmt. Bei einer Einwaage von 1000 mg lassen sich noch Gehalte von 3 · 10–4% messen, ohne daß Molybdän stört. Die Standardabweichungen betrugen ± 0,001 bis ± 0,00002%.
Für die Durchführung dieser Arbeit wurden dankenswerterweise Forschungsmittel aus dem ERP-Sondervermögen bereitgestellt.Dem Verbande der Chemischen Industrie und der Deutschen Forschungsgemeinschaft, die diese Arbeit unterstützt haben, danken wir bestens. 相似文献
Extractive-photometric determination of tin in Mo-containing steels with 3-pyridylfluorone
The steel sample is dissolved in a mixture of sulphuric acid and hydrogen peroxide. Tin is extracted as SnI4 with benzene and determined photometrically with 3-pyridylnuorone. 3×10–4% of Sn can still be determined in a 1000 mg sample without interference of molybdenum. Standard deviations were within the range of ± 0.001 to ± 0.00002%.
Für die Durchführung dieser Arbeit wurden dankenswerterweise Forschungsmittel aus dem ERP-Sondervermögen bereitgestellt.Dem Verbande der Chemischen Industrie und der Deutschen Forschungsgemeinschaft, die diese Arbeit unterstützt haben, danken wir bestens. 相似文献