全文获取类型
收费全文 | 315篇 |
免费 | 33篇 |
国内免费 | 41篇 |
专业分类
化学 | 195篇 |
晶体学 | 6篇 |
力学 | 20篇 |
数学 | 53篇 |
物理学 | 115篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 8篇 |
2021年 | 18篇 |
2020年 | 30篇 |
2019年 | 13篇 |
2018年 | 6篇 |
2017年 | 7篇 |
2016年 | 12篇 |
2015年 | 19篇 |
2014年 | 10篇 |
2013年 | 20篇 |
2012年 | 28篇 |
2011年 | 30篇 |
2010年 | 16篇 |
2009年 | 18篇 |
2008年 | 8篇 |
2007年 | 16篇 |
2006年 | 21篇 |
2005年 | 12篇 |
2004年 | 6篇 |
2003年 | 7篇 |
2002年 | 4篇 |
2001年 | 8篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 7篇 |
1997年 | 9篇 |
1996年 | 12篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1987年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有389条查询结果,搜索用时 203 毫秒
21.
铋及其化合物具有相对价廉、低毒性、低放射性等特点,已应用于医药、催化、化妆品和电子技术等领域。本文回顾了近10多年来有机铋化学的研究状况,主要从以下4个方面进行综述:(1)新型有机铋化合物的合成途径与结构特征;(2)有机铋化合物作为交联偶合、氧化、芳基化和其它反应的试剂;(3)作为催化剂;(4)作为生物医药用于溃疡、肿瘤和放射治疗等。文中着重于从分子水平关联新型有机铋化合物的结构与其化学和生物活性之间关系。此外,还介绍了有机铋化学研究领域的不足和今后的发展趋势。 相似文献
22.
非即变相位共轭反馈对半导体激光器动态特性的影响 总被引:2,自引:1,他引:2
从四波混频产生相位共轭的物理原因出发,定义了相位共轭镜(PCM)的响应时间.建立起非即变相位共轭反馈条件下半导体激光器的外腔模型。以响应时间及频率失调为参变量,对其分岔及噪声等动态行为进行数值分析。结果表明,不考虑噪声影响时,增加相位共轭镜响应时间会使混沌带出现的次数和范围得到较大的抑制,当响应时间增大到1.5ns时,混沌带消失,半导体激光器保持稳定的单周期状态;考虑噪声影响后,随若响应时间的相对强度噪声(RIN)可减小几dB甚至十几dB,产生突变需要的反馈量也增大一个数量级以上,且其频谱的峰值向高频方向移动;另外,由于共轭反馈引起的频率失调低于半导体激光器激射频率3个数量级以上.它只对分岔特性有影响.对相对强度噪声的影响几乎为零。 相似文献
23.
Simultaneous determination of cucurbitacin IIa and cucurbitacin IIb of Hemsleya amabilis by HPLC–MS/MS and their pharmacokinetic study in normal and indomethacin‐induced rats
下载免费PDF全文
![点击此处可从《Biomedical chromatography : BMC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Shougang Wang Xiaohui Guan Xiuhong Zhong Zhiping Yang Weili Huang Baoyang Jia Tao Cui 《Biomedical chromatography : BMC》2016,30(10):1632-1640
A selective and sensitive HPLC–MS/MS method was developed for the simultaneous determination of cucurbitacin IIa (cuIIa) and cucurbitacin IIb (cuIIb), the major bioactive cucurbitacins of Hemsleya amabilis, in rat plasma using euphadienol as internal standard (IS). After liquid–liquid extraction with dichloromethane, separation was achieved on a Syncronis HPLC C18 column (150 mm × 4.6 mm, 5 μm) using an isocratic mobile phase system consisting of acetonitrile–water (85:15, v/v) at a flow rate of 0.6 mL/min with a split ratio of 1:2. Detection was performed on a TSQ Quantum Ultra mass spectrometer equipped with an positive‐ion electrospray ionization source. The lower limits of quantification (LLOQs) were 0.25 and 0.15 ng/mL for cuIIa and cuIIb, respectively. The intra‐ and inter‐day precision was <11.5% for the LLOQs and each quality control level of the analytes, and accuracy was between ?9.1 and 7.6%. The extraction recoveries of the analytes and IS from rat plasma were all >87.1%. The method was fully validated and applied to compare the pharmacokinetic profiles of the two cucurbitacins in rat plasma after oral administration of H. amabilis extract between normal and indomethacin‐induced rats. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
24.
<正>The optical performance of thin film polarizers is highly sensitive to the layer thicknesses of thin film.The thicknesses of the sensitive layers are optimized in order to gain broader polarizing zone in such case when the total layer thickness does not increase.An automatic layer thickness control system is established,and errors caused by different monitoring methods are analyzed.With this thickness control system,thin-film polarizers with T_p higher than 98%and T_p/T_s higher than 200:1(T_p and T_s are transmissions for p- and s-polarizations,respectively) with the bandwidth of 11 nm are prepared.Using the system allows for optimum repeatability of three successive runs. 相似文献
25.
Two vertical-cavity surface-emitting lasers(VCSELs) are mutually coupled through a partially transparent mirror (PTM) placed in the pathway. The PTM plays the role of external mirror,which controls the feedback strength and coupling strength.We numerically simulate this system by establishing a visible SIMULINK model.The results demonstrate that the anticipation synchronization is achieved and it can tolerate some extent frequency detuning.Moreover,the system shows similar chaos-pass filtering effect on unidirectionally coupled system even both VCSELs are modulated.This system allows simultaneously bidirectional secure message transmission on public channels. 相似文献
26.
Solid-phase synthesis of photochromic spiropyrans 总被引:2,自引:0,他引:2
[reaction: see text] A convenient solid-phase synthesis of spiropyrans is described. A succinate linker was employed, which allows base-catalyzed cleavage of the desired photochromophore derivatized with a succinimide. Excellent yields and purities were obtained for the compounds that comprise a library of 23 spiropyrans. Opening of the succinimide ring in spiropyran could be realized under mild conditions. 相似文献
27.
Samples La1−aAgaMnO3 (0.05?a?0.50) were sol–gel fabricated. A part of Ag was found to dissociate and run off the samples in sintering process when sintering temperature exceeds 700 °C, resulting in a composite of La1−xAgxMnO3 and MnO2/Mn2O3. The magnetic and transport properties of the composite have been studied. The sample with the nominal composition La0.7Ag0.3MnO3 was found to show the greatest magnetoresistance in the sample group. Detailed analysis on average Mn valence reveals a composite of (La0.985Ag0.015MnO3)0.776[(MnO2)0.590(Mn2O3)0.410]0.224. Its MR ratio at room temperature exceeds 24% under a field of 1.8 T. A conductivity leap has been observed around a=0.30. It suggests a kind of field-induced fluctuation in percolation in the samples investigated. 相似文献
28.
大埋深粘土三轴高压卸载变形与强度特征 总被引:1,自引:0,他引:1
以取自山东巨野矿区埋深近 4 30~ 6 0 0m的深部粘土样为例 ,分析测试了土的常规物理力学性质参数。考虑该埋深土的天然应力水平及其在煤矿建井开挖中的卸载应力变化 ,在三轴伺服仪上 ,进行三向等压分别达 11MPa、12MPa、14MPa下的卸除围压、保持轴压的三轴高压卸载试验 ,分析了深部粘土三轴高压卸载变形和强度特点 ,得到了相关力学参数。成果丰富了土的高压卸载力学性研究 ,并为巨野矿区煤矿立井建设提供了工程地质基础参数 相似文献
29.
Ling Ding Xiaofeng Gao Weili Wu Wonjun Lee Xu Zhu Ding-Zhu Du 《Optimization Letters》2011,5(2):297-306
In this paper, we study a minimum connected dominating set problem (CDS) in wireless networks, which selects a minimum CDS
with property that all intermediate nodes inside every pairwise shortest path should be included. Such a minimum CDS (we name
this problem as SPCDS) is an important tache of some other algorithms for constructing a minimum CDS. We prove that finding
such a minimum SPCDS can be achieved in polynomial time and design an exact algorithm with time complexity O(δ
2
n), where δ is the maximum node degree in communication graph. 相似文献
30.
Using local search method, this paper provides a polynomial time approximation scheme for the minimum vertex cover problem on \(d\) -dimensional ball graphs where \(d \ge 3\) . The key to the proof is a new separator theorem for ball graphs in higher dimensional space. 相似文献