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排序方式: 共有906条查询结果,搜索用时 15 毫秒
41.
利用高效液相色谱(HPLC)法同时检测石化废水中丙烯酸、对甲基苯磺酸、甲基丙烯酸。 水样调节pH=1.6,经0.45 μm醋酸纤维滤膜过滤后直接进行色谱分析。 色谱条件:流动相为体积比93∶7的磷酸盐缓冲溶液(pH=3)和乙腈,流速1.0 mL/min,ZORBAX-SB-C18色谱柱,柱温30 ℃,MWD检测器,检测波长195 nm,进样量10 μL。 丙烯酸、对甲基苯磺酸、甲基丙烯酸的最低检出限分别为0.030、0.028和0.050 mg/L;样品测定的相对标准偏差分别为1.83%、0.69%和0.84%;样品加标回收率96%~112%。 相似文献
42.
高速铁路的出现,使得轮轨交通技术达到更高的层次.速度提升不仅对列车的牵引动力与动力学性能提出更高要求.而且,列车与线路、气流等运行环境的耦合作用加剧,并直接影响到了列车的运行品质和安全性.在高速列车发展初期,研究关注的是如何保证高速列车能高速、平稳和安全运行.随着运行速度的提高,系统间耦合加强,服役模拟也越来越受到重视... 相似文献
43.
The book-embedding problem arises in several area, such as very large scale integration (VLSI) design and routing multilayer printed circuit boards (PCBs). It can be used into various practical application fields. A book embedding of a graph G is an embedding of its vertices along the spine of a book, and an embedding of its edges to the pages such that edges embedded on the same page do not intersect. The minimum number of pages in which a graph G can be embedded is called the pagenumber or book-thickness of the graph G. It is an important measure of the quality for book-embedding. It is NP-hard to research the pagenumber of book-embedding for a graph G. This paper summarizes the studies on the book-embedding of planar graphs in recent years. 相似文献
44.
Jiamei Wei Jie Chen Jiechao Xu Long Cao Hongmei Deng Weihua Sheng Hui Zhang Weiguo Cao 《Journal of fluorine chemistry》2012
1,3-Dipolar cycloadditions of methyl 2-perfluoroalkynoates with various azides have been examined, leading to a simple metal-free synthetic protocol for the synthesis of perfluoroalkylated 1,2,3-triazoles. The regiochemical results demonstrated that the cycloaddition was controlled by FMO (the frontier molecular obitals) interaction and steric hindrance in transition states. 相似文献
45.
A simple method was proposed to prepare nanosized Si composite anode materials for lithium-ion (Li-ion) batteries. The preparation
started with the shock-type ball milling of silicon in liquid media of polyacrylonitrile (PAN)/dimethylformamide (DMF) solution,
forming slurry where the nano-Si particles were uniformly dispersed, followed by the drying of the slurry to remove DMF. The
nanosized Si composite anode material was obtained after the pyrolysis of the mixture at 300 °C where the pyrolyzed PAN provided
a conductive matrix to relieve the morphological change of Si during cycling. As-prepared composite presented good cyclability
for lithium storage. The proposed process paves an effective way to prepare high performance Si, Sn, Sb and their alloys based
composite anode materials for Li-ion batteries. 相似文献
46.
A previous study on the deleterious effect of triphenyltin chloride (TPTCl) on the alga Spirulina subsalsa reported on four physiological and biochemical indices (or parameters): growth rate, chlorophyll content, phycocyanin content and nitrate reductase activity. In the present study, further research was performed to confirm the findings reported in the previous paper, using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The SEM images show significant changes in the screw‐pitch of S. subsalsa, suggesting that TPTCl may damage the inheritance characteristics of S. subsalsa. The TEM images illustrate that the external pectin theca, limiting membrane and inter photosynthetically active lamella in the S. subsalsa cell are those targets that can be easily damaged. Reversible and irreversible cell damage (cell necrosis) are also observed. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
47.
Circulators play a significant role in radar and microwave communication systems.This paper proposes a broadband and highly efficient plasmonic circulator,which consists of spoof surface plasmon polaritons(SSPPs)waveguides and ferrite disks to support non-reciprocal mode coupling.The simulated performance of symmetrically designed circulator shows that it has an insertion loss of roughly 0.5 dB while the isolation and return loss is more than 12 dB in the frequency range of 6.0 GHz–10.0 GHz(relative bandwidth of 50%).Equivalent circuit model has been proposed to explain the operating mechanism of the plasmonic circulator.The equivalent circuit model,numerical simulations,and experimental results are consistent with each other,which demonstrates the good performance of the proposed plasmonic circulator. 相似文献
48.
Wide-Angle Ultra-Broadband Metamaterial Absorber with Polarization-Insensitive Characteristics 下载免费PDF全文
An ultra-wideband metamaterial absorber is developed,which is polarized-insensitive and angular-stable.Three layers of square resistive films comprise the proposed metamaterial.The optimal values of geometric parameters are obtained,such that the designed absorber can achieve an ultra-broadband absorption response from 4.73 to 39.04 GHz(relative bandwidth of 156.7%)for both transverse electricity and transverse magnetic waves.Moreover,impedance matching theory and an equivalent circuit model are utilized for the absorption mechanism analysis.The compatibility of equivalent circuit calculation results,together with both full-wave simulation and experimental results,demonstrates the excellent performance and applicability of the proposed metamaterial absorber. 相似文献
49.
Chuanlei Liu Kurt Ungar Dylan Pierce Ian Hoffman Weihua Zhang 《Journal of Radioanalytical and Nuclear Chemistry》2017,312(3):471-478
In assistance of radionuclide measurements at Canada’s Comprehensive Nuclear-Test-Ban Treaty (CTBT) laboratory, a Geant4 Monte Carlo application has been developed in simulating a broad-energy germanium detector and calculating detection efficiencies. The detector model was optimized in a reliable and non-biased manner through simultaneous tuning on gap distance and detector dimension, and was validated over various realistic measurement scenarios. All work is based on a series of experiments which covers the typical energy range of gamma radiation in environmental analysis, and considers the variety of the CTBT sample type, dimension and distance-to-detector. In all cases, the predicted efficiencies are consistent with the empirical ones within 5%, with a typical deviation of 3% in majority. 相似文献
50.
The density functional method is used to study the structure, electronic properties, static linear polarizabilities, and optical absorption spectra of two seven‐membered unconventional fullerene derivatives C58F17CF3 and C58F18. It is calculated that three sites chosen to locate the CF3 are isoenergetic. The energy gaps of C58F18 and C58F17CF3 are much larger than that of C58, indicating the fluorination and trifluoromethylation of C58 can remarkably enhance the kinetic stability. The density of states explore that the influence of CF3 to the energy levels is mainly distributed in the energy range from ?10 to ?2 eV. However, when the CF3 substitutes for F in C58F18, the bond lengths, energy gaps, static linear polarizabilities, and optical absorption spectra all show small variety. 相似文献