One-pot copper-catalyzed synthesis of 2-substituted benzothiazoles from 2-iodoanilines,benzyl chlorides and elemental sulfur

An efficient one-pot three-component reaction of 2-iodoanilines, benzyl chlorides and elemental sulfur to form 2-substituted benzothiazoles in satisfactory yields (up to 98%) has been described. The reaction tolerated a wide range of functional groups on the aromatic ring. And heterocycle methylene chlorides substrates were also found to be compatible.     

Iridium-catalyzed annulation between 1,2-diarylethanone and 3-aminopropanol toward site-specific 2,3-diaryl pyridines

An iridium-catalyzed annulation between 1,2-diarylethanone and 3-aminopropanol was developed, leading to site specific 2,3-diarylpyridines in moderate yields. 3-Aminopropanol served as both a four-atom component and solvent during this procedure, releasing water as a clean by-product. The reaction may proceed with sequential imine formation, alcohol oxidation and intramolecular cyclization by Knoevenagel reaction.     

Suppression of the Charge Density Wave State in Two-Dimensional 1T-TiSe2 by Atmospheric Oxidation

Two-dimensional (2D) metallic transition-metal dichalcogenides (TMDCs), such as 1T-TiSe₂, have recently emerged as unique platforms for exploring their exciting properties of superconductivity and the charge density wave (CDW). 2D 1T-TiSe₂ undergoes rapid oxidation under ambient conditions, significantly affecting its CDW phase-transition behavior. We comprehensively investigate the oxidation process of 2D TiSe₂ by tracking the evolution of the chemical composition and atomic structure with various microscopic and spectroscopic techniques and reveal its unique selenium-assisting oxidation mechanism. Our findings facilitate a better understanding of the chemistry of ultrathin TMDCs crystals, introduce an effective method to passivate their surfaces with capping layers, and thus open a way to further explore the functionality of these materials toward devices.     

斜拉桥拉索的风（雨）激振及控制

目前，国内建造了大量的斜拉桥。随着斜拉桥跨度的增大，拉索的风致振动及风雨激振问题越来越突出。本文总结了国际上的有关研究，特别是拉索风雨激振及控制研究的成果，提出了这一领域中有重要意义的研究方向。     

松质骨弹性模量计算的均匀化方法

对松质骨建立了六种单胞微观结构模型，采用均匀化方法和有限元方法计算松质骨的宏观等效弹性模量。给出了六种单胞模型的松质骨弹性模量与材料密度(体分比）的关系，与实验数据进行了对比，分析了不同微观结构模型在不同骨骼中的应用。结果表明，本文方法及六种单胞模型可以对松质骨微观结构和材料性能进行有效的模拟计算。同时本文又着重对松质骨的宏观等效弹性模量与体分比的指数关系进行了探讨。     

某大型水电枢纽坝基埋藏型岩溶发育特征及深层承压水研究

作者在现场工程地质勘察、试验基础上, 对我国西南某大型水电枢纽坝基所遇特殊的复杂埋藏型岩溶、承压水问题进行了研究, 弄清了坝基岩溶、承压水形成条件及发育特性, 对坝址选择及工程处理的决策具有重要意义。     

水中爆炸冲击波作用下混凝土墩动态响应初步分析

用水下爆炸冲击分析（ＵＳＡ）方法,在假设条件下,数值模拟了混凝土结构物水中爆炸冲击波作用下的加速度及压力响应,是对浅层水中爆炸流－固耦合动力学问题数值解的初步尝试。