全文获取类型
收费全文 | 21606篇 |
免费 | 4201篇 |
国内免费 | 3230篇 |
专业分类
化学 | 15803篇 |
晶体学 | 299篇 |
力学 | 1336篇 |
综合类 | 302篇 |
数学 | 2592篇 |
物理学 | 8705篇 |
出版年
2024年 | 55篇 |
2023年 | 387篇 |
2022年 | 750篇 |
2021年 | 762篇 |
2020年 | 911篇 |
2019年 | 895篇 |
2018年 | 769篇 |
2017年 | 732篇 |
2016年 | 1016篇 |
2015年 | 1094篇 |
2014年 | 1332篇 |
2013年 | 1642篇 |
2012年 | 1977篇 |
2011年 | 2069篇 |
2010年 | 1490篇 |
2009年 | 1499篇 |
2008年 | 1615篇 |
2007年 | 1412篇 |
2006年 | 1322篇 |
2005年 | 1097篇 |
2004年 | 919篇 |
2003年 | 700篇 |
2002年 | 708篇 |
2001年 | 604篇 |
2000年 | 473篇 |
1999年 | 420篇 |
1998年 | 328篇 |
1997年 | 332篇 |
1996年 | 287篇 |
1995年 | 241篇 |
1994年 | 224篇 |
1993年 | 161篇 |
1992年 | 115篇 |
1991年 | 131篇 |
1990年 | 111篇 |
1989年 | 76篇 |
1988年 | 78篇 |
1987年 | 64篇 |
1986年 | 46篇 |
1985年 | 33篇 |
1984年 | 29篇 |
1983年 | 28篇 |
1982年 | 27篇 |
1981年 | 18篇 |
1980年 | 16篇 |
1979年 | 6篇 |
1976年 | 6篇 |
1975年 | 8篇 |
1959年 | 5篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 19 毫秒
161.
镧系离子与L-羟脯氨酸、DL-瓜氨酸配位作用研究 总被引:2,自引:0,他引:2
稀土与体内广泛存在的生物配体氨基酸的配位作用,尤其是三元体系的研究对于阐明稀土元素在体内的存在形态及探索稀土生物效应具有重要意义.羟脯氨酸和瓜氨酸均是人体中存在的重要氨基酸,它们在人体血浆中的浓度与必需的氨基酸相近[‘j.稀土与氨基酸配位作用的研究已有较多报道「’‘,但模拟生理条件下稀土离子与羟脯氨酸、瓜氨酸的二元、三元配合物的PH电位法研究尚未见报道.本文报道在模拟生理条件下(37C,0·15mol/LNaCI)湖系离子(Pm和Lu除外)与上述2种氨基酸的二元及三元配合物PH电位法研究结果.1实验部分1.1试剂和仪… 相似文献
162.
163.
大肠杆菌有限生长的微量热及非线性动力学研究 总被引:2,自引:0,他引:2
The finite growth of Escherichia coli was studied by using a LKB 2277 BioActivity Mollitor. We found that the finite growth is a nonliear dynamic process. The nonlinear dynamic behaviour in the finite growth process and the nonlinear dynamic models describing the process were discovered and established. The curve of logistic map corresponding to the finite growth thermogram of Escherichia coli was obtained and the nonlinear dynamic parameters were calculated by means of a computer. Moreover, we also discussed the nonlinear dynamic characters of Escherichia colt in its finite growth process. 相似文献
164.
Yanfeng Zhao Nengsheng Ye Rongli Zhang Xue Feng Guoan Luo Yiming Wang 《Frontiers of Chemistry in China》2007,2(4):422-427
High-resolution two-dimensional gel electrophoresis (2-DE), followed by computer-assisted image analysis was used to screen
protein patterns of normal and infarcted myocardial tissues for quantitative and qualitative differences in protein expression.
In the gels of pH 5–8 immobilized pH gradient (IPG) strips, 851 protein spots were detected in normal myocardial tissue and
1 032 protein spots were resolved in infarcted myocardial tissue. Thirteen protein spots only expressed in normal myocardial
tissue, and 14 protein spots only expressed in infarcted myocardial tissue. Results also showed that 49 protein spots displayed
quantitative changes in expression between normal and infarcted myocardial tissue. Eleven protein spots were subjected to
mass spectrometry (MS) analysis and seven proteins were identified by peptide mass fingerprinting (PMF). These proteins may
be involved in cardiovascular injury, and could play an important role in the treatment of coronary heart disease.
__________
Translated from Chemical Journal of Chinese Universities, 2006, 8(27): 1467–1471 [译自: 高等学校化学学报] 相似文献
165.
0 IntroductionMetallosupramolecular oligomers and polymerscan result from the interaction of metal ions with ap-propriate multidentate ligands designed for multinucle-ar binding[1,2], and there are considerable interests in thedesign of species containing known numbers of metalions in defined spatial arrangements. The electronic andphotophysical properties of oligopyridine complexes oftransition-metal ions make their incorporation particu-larlyattractive and the possibilityofinter-metallic ele… 相似文献
166.
A New Asterosaponin from the Starfish Culcita novaeguineae 总被引:1,自引:0,他引:1
HaiFengTANG YangHuaYI LingLI PengSUN DaZhengZHOU BaoShuLIU 《中国化学快报》2005,16(5):619-622
A new asterosaponin named novaeguinoside A, along with a known saponin, asteronyl pentaglycoside sulfate, was isolated from the starfish Culcita novaeguineae. The new compound was identitied to be sodium 6α-O-{β-D-fucopyranosyl-(1→2)-β-D-fucopyranosyl-(1→4)-[β-D-quinovopyranosyl-(1→2)]-β-D-xylopyranosyl-(1→3)-[β-D-quinovopyranosyl}-5α-pregn-9(11)-en-20-one-3β-yl-sulfate by extensive spectral analysis and chemical evidence. 相似文献
167.
168.
169.
170.
There have been remarkable progresses in manipulating heterogeneous catalysts' nanostructures in the past decade. The concept of single atom alloy (SAA) was firstly proposed in 2012 when researchers successfully stabilized single Pd atoms on the Cu(111) surface. However, earlier work in 2009, which focused on replacing one Au atom with a Pd atom in thiolate protected Au25 nanoclusters, could also be considered as the pioneer work of single atom alloy. Both kinds of single atom alloys exhibited the potential of maximum utilization of scarce elements and attractive catalytic performances. The well‐defined structures of SAA catalysts make accurate modeling possible, which further realizes the rational design of single atom alloy catalysts. In this review, we summarize the research trajectory of single atom alloys as well as recent achievements in this field. We also introduce several commonly adopted characterization methods for SAA catalysts such as scanning tunneling microscopy (STM), temperature programmed reaction (TPR), extended X‐ray absorption fine structure (EXAFS) spectra, matrix assisted laser desorption/ionization mass spectrum (MALDI‐MS) and differential pulse voltammetry (DPV). Through discussing recent progresses in SAA catalysts, we propose that future researches in this filed should be focused on exploring new kinds of metal nanocrystals and controlling the nanostructure of SAA even more precisely. 相似文献