白光荧光粉Ca9.95-xNa0.75K0.25(PO4)7:Eu2+0.05,Mn2x+的制备及其发光特性

高温固相法合成了Ca9.95-xNa0.75 K0.25 (PO4)7∶Eu0.052+,Mn2+x(x=0,0.1,0.2,0.3,0.4,0.5,0.6和0.7)荧光粉,研究了其相组成和荧光发射性能.结果表明,由于样品中存在着晶体结构相似的双相,使得Eu2+的5d-4f跃迁辐射出峰值分别位于491和540 nm宽谱...     

对甲氧基苯甲醛肟晶体结构、红外光谱及分子间相互作用的实验与理论研究

从实验和理论两个方面研究了Z型和E型对甲氧基苯甲醛肟晶体的熔点、 结构、 红外光谱和分子间相互作用. 在E型和Z型晶体中, 对甲氧基苯甲醛肟分子分别呈二聚体重复单元和双链Zigzag结构排列. 研究结果表明, 电荷分布变化引起的静电相互作用差别、 形成氢键的方式和强度以及晶体中分子排列方式导致的范德华作用不同是造成Z型和E型对甲氧基苯甲醛肟固体熔点、 红外光谱等物理性质差别的根本原因.     

Electrooxdation of Tricarbonyl(N,N-Diphenylcyclohexadienecarboxamide)Iron Complexes. Reversibility of Electron Transfer and Free Energy Change

Qualitative and quantitative criteria of irreversibility of electron transfer in cyclic voltammetry (CV) of tricarbonyl(N,N-diphenylcyclohexadienecarboxamide)iron complexes were investigated. The measurement of the heterogeneous rate constants for electron transfer according to CV data over an extended range of free energy change ( ΔG) for these complexes are described. Kinetic analyses of the electrochemical technique demonstrates that when the applied potential exceeds the standard potential E°, the experimental rate constant k_e represents an accurate measurement of the intrinsic rate constant k₁ for electron transfer. However, as the applied potential is less than E°, the reversibility of the electron-transfer process becomes increasingly more important, and the rate constants for reverse electron transfer k_-t and decomposition k₂ of the electrogenerated intermediate have to be taken into account.     

Offline Calibration of BES Ⅱ Muon Detector

The Structure of BES Ⅱ μ Detector and its original offline calibration method is introduced, The calibration method is improved after careful study of the basic principle of various offline calibration method and the main reasons which caused the z position resolution of the μ Detector worsened. Using the improved offline calibration method, the z position resolution of the μ Detector is improved about 20 % compared with the previous method.     

Metamaterial absorbers realized in an X-band rectangular waveguide

In this paper,we demonstrate six types of metamaterial absorbers(MMAs) by measuring their absorptivities in an X-band(8-12 GHz) rectangular waveguide.Some of the MMAs have been demonstrated previously by using the free space measurement method,and the others are proposed firstly in this paper.The measured results show that all of the six MMAs exhibit high absorptivities above 98%,which have similar absorbing characteristics to those measured in the free space.The numerically obtained surface current densities for each MMA show that the absorbing mechanism is the same as that under the free space conditions.Such a demonstration method is superior to the conventional free space measurement method due to the small-scale test samples required,the simple measure device,and its low cost.Most importantly,the proposed method opens a way to enable MMAs to be used in microwave applications such as matched terminations.     

THE BES ON-LINE DATA ANALYSIS SYSTEM

The paper briefly describes the hardware configuration and software components of the BES (Beijing Spectromenter) on-line data acquisition system,and summarizes the development of this system we completed in the recent two years.A successful run of the on-line system has been performed in the BES'S cosmic ray test.     

一种基于开口空心球的声学超材料

提出了一种基于局域共振的开口空心球(spilt hollow spheres,SHS)模型,数值计算和声学透射实验结果表明基于该模型的声学超材料可以实现负的弹性模量.为了说明SHS的局域共振性质,研究了微结构SHS几何尺寸(例如开口孔径d和空心球直径D)变化时材料的透射性质,结果表明SHS的几何尺寸的改变对声学超材料的透射吸收峰频率有显著影响.另外,还研究了SHS不同排列方式对透射行为的影响,发现单层样品中SHS单元数目以及晶格常数的变化不会引起谐振频率的变化,但是随着SHS单元数目或者样品 关键词： 开口空心球(SHS) 声学超材料 吸收峰 等效弹性模量     

Effective long-range attraction between protein molecules in solutions studied by small angle neutron scattering

Small angle neutron scattering intensity distributions taken from cytochrome C and lysozyme protein solutions show a rising intensity at a very small wave vector Q, which can be interpreted in terms of the presence of a weak long-range attraction between protein molecules. This interaction has a range several times that of the diameter of the protein molecule, much greater than the range of the screened electrostatic repulsion. We show evidence that this long-range attraction is closely related to the type of anion present and ion concentration in the solution.     

Incorporating intermicellar interactions in the fitting of SANS data from cationic wormlike micelles

Small-angle neutron scattering (SANS) from cationic wormlike micellar solutions composed of hexadecyltrimethylammonium bromide (CTABr) and hexadecylpyridinium bromide (CPyBr) in deuterated water was studied at 40 degrees C as a function of surfactant and salt concentrations. Two scattering functions of semiflexible chains incorporating excluded volume effects, with and without the intermicellar interactions, were used in SANS data model fitting. Two needed changes were made in the well-accepted models. Extensive and systematic SANS data analysis suggests the robustness of these corrected scattering functions when the intermicellar interactions are included. The influence of the headgroups and ionic strength on the contour length and micellar flexibility of these two systems was demonstrated on the basis of the quantitative structural information obtained from the model fitting. Micellar flexibility was found to depend on surfactant concentration, even when intermicellar interactions were taken into account, despite predictions to the contrary.     

A Study on the Luminescence and Energy Transfer of Single-Phase and Color-Tunable KCaY(PO(4))(2):Eu(2+),Mn(2+) Phosphor for Application in White-Light LEDs

Novel single-phased white light-emitting KCaY(PO(4))(2):Eu(2+),Mn(2+) phosphors for light-emitting diode (LED) applications were synthesized by conventional solid-state reaction. The emission hue could be controlled by tuning the Eu(2+)/Mn(2+) ratio via the energy transfer; the the emission hue of KCaY(PO(4))(2):Eu(2+),Mn(2+) varied from blue (0.1853, 0.2627) to white-light (0.3350, 0.3203) and eventually to purple (0.3919, 0.2867). The mechanism of energy transfer from a sensitizer Eu(2+) to an activator Mn(2+) in KCaY(PO(4))(2):Eu(2+),Mn(2+) phosphors was demonstrated to be an electric dipole-quadrupole interaction. Combining a NUV 405-nm chip and a white-emitting KCaY(PO(4))(2):1%Eu(2+),4%Mn(2+) phosphor produced a white-light NUV LED, demonstrating CIE chromaticity coordinates of (0.314, 0.329) and a color temperature of 6507 K.