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71.
Generalized Parton Distributions (GPDs) provide a way to access total angular momenta of partons and give a multidimensional picture of the nucleon structure.Deeply Virtual Compton Scattering (DVCS) is the most direct exclusive process to study GPDs.Different azimuthal cross-section asymmetries with respect to beam helicity,beam charge,and target polarization have been measured in the HERMES experiment.A recoil detector was installed at HERMES to directly detect the recoil proton. 相似文献
72.
Novel Ag-SiO2-MgO-Al2O3 catalyst prepared by sol-gel method showed extremely high activity and selectivity (both equal to 100%) in the direct dehydrogenation of methanol to anhydrous formaldehyde. 相似文献
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75.
Two controlled remote state preparation protocols via the Brown state as the entangled channel are proposed. One prepares an arbitrary two-qubit state, and the other prepares an arbitrary three-qubit state. It is worth mentioning that Hurwitz matrix equation plays a key role in the construction of measurement basis. Comparing with the previous protocols, the novel schemes have no restriction on the coefficients of the prepared state while keeping the same success probability 50 %. It means that the application of the proposed schemes are more extensive in practice. Moreover, we discuss the special complex coefficient ensembles with unit success probability. 相似文献
76.
过氧多酸盐[NBu4]3[M(O2)W5O18]的合成及表征 总被引:1,自引:0,他引:1
过渡金属过氧化合物是一类性能良好的催化剂,在有机合成中得到广泛的应用[1,2].过氧多酸催化过氧化氢氧化有机物的反应,近年来倍受重视[3~5]. 相似文献
77.
Cu/ZrO2催化剂中的氢和水逆溢流效应及其对甲醇分解反应的影响 总被引:1,自引:0,他引:1
应用漫反射红外和质谱在线技术对H2, H2O及甲醇在ZrO2及Cu/ZrO2上的程序升温脱附(TPD)及程序升温反应(TPSR)行为进行了研究. 结果表明, Cu/ZrO2催化剂中铜锆组分间表现出显著的氢和水组分“逆溢流”效应. 对Cu/ZrO2催化体系中ZrO2表面线式及桥式羟基物种浓度随还原预处理温度变化的进一步分析表明, 由于氢和水“逆溢流效应”的存在, 使得Cu/ZrO2在较低的还原温度下活化的同时, 在铜锆界面处形成较丰富的氧阴离子和氧空穴活性位, 而后者的形成与存在直接影响并决定了甲醇在Cu/ZrO2催化剂上的低温催化分解行为. 相似文献
78.
报道了稀土配位催化剂对环硫氯丙烷(CMT)与环氧丙烷(PO)的共聚合,许多稀土化合物与三异丁基铝组成的催化体系都能使两者共聚;尤为突出的是Y(P204)3-Al(i-Bu)3-H2O催化体系对此共聚反应具有优良的优良的催化活性,最大催化效率达6000g/molY,分子量较(η达1.0dl/g)产率在50%以上,应用IR、NMR、GPC等手段对共聚物进行一表征,测理CMT(1)与PO(2)的共聚率分 相似文献
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Two supramolecular complexes, [Cu(L)(H2O)2(beta-CD)](ClO4)2.10.5H2O.CH3OH (1) and [Cu(L)(H2O)2(beta-GCD)](HClO4)(ClO4)2.10H2O (2) (L = 4-(4'-tert-butyl-benzyl)diethylenetriamine, beta-CD = beta-cyclodextrin, and beta-GCD = mono-6-deoxy-6-guanidinocycloheptaamylose cation), have been synthesized. The structure of 1 has been characterized by X-ray crystallography. The 4-tert-butyl-benzyl of [Cu(L)(H2O)2]2+ moiety in 1 as a guest inserts into the hydrophobic cavity of the beta-CD as a host along the primary hydroxyl side. On the basis of the structure data of 1, complex 2 was modeled, which showed that the distance between the Cu and C atom of the guanidinium is 5.2 A, comparable to the corresponding distance in bovine erythrocyte Cu, Zn-SOD (5.9 A) (SOD = superoxide dismutase). Apparent inclusion stability constants of the host and the guest were measured to be 0.66 (+/-0.01) x 104 and 1.15 (+/-0.03) x 104 M-1 for 1 and 2 respectively. The electronic absorption bands and electronic reflection bands of each complex are almost the same, indicating an identical structure of the complex in aqueous solution and in solid state. The two complexes showed quasi-reversible one-electron Cu(II)/Cu(I) redox waves with redox potentials of -0.345 and -0.338 V for 1 and 2, respectively. Their SOD-like activities (IC50) were measured to be 0.30 +/- 0.01 and 0.17 +/- 0.01 microM by xanthine/xanthine oxidase-NBT assay. The enhanced SOD activity of 2 by approximately 40% compared with 1 suggests that the guanidyl cation in the host of the supramolecular system of 2 can effectively mimic the side chain of Arg141 in the enzyme, which is known to be essential for high SOD activity possibly through steering of the superoxide substrate to and from the active copper ion. 相似文献