高效蛋白质浓缩剂的制备及浓缩作用的研究

采用自由基水溶液聚合方法合成了超高分子量的丙烯酸（钠）聚合物。该聚合物具有高达几十倍至上千倍的吸水能力，通过适当控制聚合物的交联度使其成为具有一定孔径的网状物，可用于生物大分子，如：蛋白质溶液或其它生物提取液的浓缩。试验了用反透析法浓缩胰蛋白酶的方法，与直接加入浓缩法相比，能够更好地保持酶的活性。与传统的浓缩方法相比，用该方法浓缩蛋白质具有效率高，浓缩剂用量少的优点。     

CexGdyTb1-x-yP5O14晶体生长及其光谱

采用蒸发溶液法从磷酸溶液中生长出一系列CexGdyTb1-x-yP5O14晶体.测定了它们的结构.它们属于单斜晶系,空间群P21/c.测定了Ce0.9Gd0.1P5O14、Ce0.9Tb0.1P5O14和La0.8Gd0.1Tb0.1P5O14等晶体的光谱.首次观察到,将Gd加入CexTb1-xP5O14晶体中形成.CexGdyTb1-x-yP5O14时阻碍了Ce3+→Tb3+的能量传递,导致Ce3+的发射峰增强,Tb3+的5D4-FJ发射峰减弱、而5D3-7FJ发射峰增强.     

HBTMPTP与伯胺N1923对稀土元素(Ⅲ)的协同萃取

研究了二（2，4，4-三甲基戊基）单硫代膦酸（HBTMPTP，HL）和伯胺N1923的正己烷溶液从硫酸介质中对稀土元素（Ⅲ）的协同萃取．并以La（Ⅲ）为例，用斜率法、恒摩尔法和饱和法确定了协萃配合物的组成为（RNH3）3L2La（SO4）2，计算了协萃配合物的生成常数及热力学函数，观测了协萃配合物的IR谱．     

Electronic Structure and Magnetic Properties of SmCo7-xZrx

The electronic structure and magnetism of SmCo_7-xZr_x alloy are investigated using the spin-polarized MS-X. method. The results show that a few of electrons are transferred to the Sm(5d⁰) orbital due to orbital hybridization between Sm and Co atoms. The exchange interactions between 3d and 5d electrons are more important than the polarization effects of the conductive electrons, thus it is the main reason resulting in the long-range ferromagnetic order in SmCo_7-xZr_x. The Curie temperature of SmCo_7-xZr_x is generally lower than that of corresponding pure Co, which may be explained by the weaker average coupling strength between Co lattices due to some negative couplings mainly occurring of 2e site. The calculated results for the Sm₅Co₃₂Zr₂ cluster may lead to a better understanding of why SmCo_7-xZr_x is stable phase. Since the spin-up DOS peak of d electrons at E_F arises and the bonding of electrons at E_F strengthens with increasing Zr concentration, which results in the internal energy of the system decrease, the stable ferromagnetic order forms in SmCo_7-xZr_x.     

Cyclic BSEC of block size 3

Balanced sampling plans excluding contiguous units (or BSEC) were first introduced by Hedayat, Rao and Stufken in 1988. In this note, we discuss constructions of these designs having cyclic automorphisms. We use Langford sequences to construct all possible cyclic BSEC (or CBSEC) with block size 3 and λ = 1,2, which establishes the necessary and sufficient conditions for such designs. Some constructions of the balanced sampling plan avoiding adjacent units, a generalization of BSEC, are also given for fixed λ.     

Behaviors of the positive temperature coefficient of resistance of poly(styrene‐co‐n‐butylacrylate) filled with Ni‐plated core‐shell polymeric particles

Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007     

Isolation and Structure Elucidation of Nortriterpenoids from Schisandra rubriflora

Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1.     

吹气孔直径对RH精炼过程钢液流动和混合特性的影响

针对90t RH精炼装置,以水力学模拟研究了吹气孔直径对真空循环精炼过程中钢液流动和混合特性的影响.模型和原型的相似比为15.模型吹气孔直径分别为0.8 mm和1.2 mm.结果表明,1.2 mm孔径下环流量和主要工艺参数间的关系为Ql Q80.26Du0.69Dd0.80;在给定的吹气量和插入管内径下,增大吹气孔直径并不显著改变精炼过程中钢液流动特征,环流量随吹气孔直径的增大而略有增大,其关系式为Ql=2.40Q 0.23gD0.72u D0.88d d0.13in;相应地,混合时间稍有缩短;0.8和1.2 mm孔径下,τm与搅拌能密度的关系分别为τm ε5和τm ε0.49.     

Chemical Speciation of Amphoteric Ions on Semi‐Dry Scrubber Residue and Bag‐House Ash from MSWI

Two series of size‐fractionated combusted residues, a bag‐house ash and a scrubber residue, from a municipal solid waste incinerator (MSWI) were prepared and extracted by means of sequential chemical extraction (SCE) procedures proposed by Tessier. Concentrations of water‐soluble phase, exchangeable phase, carbonated phase, Fe/Mn oxide phase, organic matter phase, and residual phase bound amphoteric metals (Pb and Zn) were obtained, and have been compared with those of single batch extraction of toxic characteristic leaching procedure (TCLP). In each size fraction of baghouse ash or scrubber residue, lead or zinc shows a common phenomena that the TCLP value is always lower than the content of the water‐soluble fraction. For lead, baghouse ash has a significant size‐dependent distribution on the water‐soluble phase to perform a size‐dependent test of lead in the TCLP test. The zinc TCLP data having less size dependence might be due to that neither the baghouse ash nor the scrubber residue has a size‐dependent distribution on the water‐soluble zinc phase.     

投资组合保险CPPI策略研究

随着期权理论应用的发展,投资组合保险在国外已成为一种盛行的资产配置策略, 常数比例投资组合保险策略(CPPI)以其模型简单、参数的设置又能充分反映投资人不同的风险偏好、而且易于实施,成为大型安全型基金的基金经理首选的投资策略.本文研究并推广了CPPI策略,找出CPPI与期权的关系,讨论了借贷限制对(CPPI策略的影响,最后对CPPI策略在中国市场的可投资性进行了评测.