In vivo tibial lead measurement to assess the health hazard of Venezuelan workers

Gamma-ray induced X-ray emission (GIXE) technique for elemental lead in-vivo tibial measurement using a large volume hyper pure germanium detector is presented with the most convenient source-sample-detector geometry. The system operates advantageously when several parameters are considered for a lower dead time operation. The detection limit (DL) is better that 3.5 μg/g of Ca. Results of in-vivo average tibial lead concentration for some of the monitored groups are: control 7 μg of lead per g of Ca; gasoline filling attendants 6 μg/g of Ca; custom office workers near the DL; industrial workers range from DL up to 84±3 μg/g of Ca, suggesting that lead accumulation in the bone does not represent a major health risk This revised version was published online in August 2006 with corrections to the Cover Date.     

Taylor-Galerkin algorithms for viscoelastic flow: Application to a model problem

Coupled and decoupled Taylor-Galerkin algorithms are considered for viscoelastic flow and a model problem—transient startup Poiseuille flow in a channel under a fixed pressure gradient. All algorithms reproduce the steady-state solutions and are stable at high elasticity numbers (E). For a fixed mesh, the coupled and decoupled versions (TGC and TGD) give exceptional time-accuracy at low elasticity numbers [to within O(1%) at E = 1] and reasonable accuracy at high elasticity numbers [to within O(10%) at E = 10, 100]. By definition, the decoupled false-transient scheme (TGF), which uses different time scales for velocity and stress time stepping, provides a poor transient history. Where the main requirement is to compute a steady-state algorithm efficiency is crucial. The TGF scheme attains a steady state between six to eight times faster than does the TGC scheme, and the latter is over twice as fast as the TGD form. © 1994 John Wiley & Sons, Inc.     

A New Flow Instrument for Conductance Measurements at Elevated Temperatures and Pressures: Measurements on NaCl(aq) to 458 K and 1.4 MPa

A new flow electrical conductance instrument was constructed and tested on dilute NaCl solutions up to 458 K, and on more concentrated solutions (maximum 0.436 mol⋅kg⁻¹) at 373 K. The results of the new instrument agreed with those of previous authors within the estimated experimental errors. The model of Bernard et al. (J. Phys. Chem. 96, 3833–3840 (1992), MSA) was found to represent the high-temperature results without introducing an ion-pairing equilibrium constant. The Fuoss–Hsia conductance equation as given by Fernandez-Prini was found to represent the dilute concentrations with Λ° (NaCl) as the only adjustable parameter. It was found that Λ° (NaCl) could be expressed as a function of solvent viscosity and density by using three parameters found by regression of literature results between 278.15 and 523 K. This equation along with the FHFP theory permits the equivalent conductivity of dilute sodium chloride solutions to be calculated within the accuracy of the existing experimental measurements.     

Superheated water eluent capillary liquid chromatography

A capillary scale reverse phase liquid chromatography (LC) system using a super hot water eluent is described. The system, constructed in-house from readily available components, has been shown to operate at temperatures as high as 370 °C and pressures in excess of 10 000 psi. The capability of the system is demonstrated with the separation of a mixture of polar and non-polar benzene derivatives on polybutadiene and elemental carbon modified zirconia packings with or without temperature gradients. Six benzene derivatives can be separated in 2 min.