全文获取类型
收费全文 | 496篇 |
免费 | 8篇 |
国内免费 | 4篇 |
专业分类
化学 | 217篇 |
晶体学 | 2篇 |
力学 | 20篇 |
数学 | 53篇 |
物理学 | 216篇 |
出版年
2018年 | 3篇 |
2016年 | 4篇 |
2015年 | 10篇 |
2013年 | 17篇 |
2012年 | 15篇 |
2011年 | 13篇 |
2010年 | 10篇 |
2009年 | 13篇 |
2008年 | 18篇 |
2007年 | 19篇 |
2006年 | 27篇 |
2005年 | 20篇 |
2004年 | 15篇 |
2003年 | 13篇 |
2002年 | 22篇 |
2001年 | 12篇 |
2000年 | 14篇 |
1999年 | 11篇 |
1998年 | 6篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 12篇 |
1994年 | 23篇 |
1993年 | 23篇 |
1992年 | 31篇 |
1991年 | 8篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 4篇 |
1985年 | 11篇 |
1984年 | 8篇 |
1983年 | 10篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1973年 | 4篇 |
1972年 | 3篇 |
1969年 | 2篇 |
1968年 | 3篇 |
1933年 | 2篇 |
1930年 | 2篇 |
1919年 | 2篇 |
排序方式: 共有508条查询结果,搜索用时 31 毫秒
71.
72.
73.
74.
Felix Barz Joseph G. Gordon Michael R. Philpott Michael J. Weaver 《Chemical physics letters》1982,91(4):291-295
The intensity of surface-enhanced Raman scattering (SERS) from thiocyanate and chloride adsorbed on silver electrodes is shown to depend critically on whether the electrode is illuminated during the oxidation-reduction cycle used to pretreat the electrode. The value and magnitude of the photoeffect is dependent upon the type of surface vibrational mode, the adsorbate and the wavelength of the radiation during the ORC. The effects are attributed to the production of SERS active clusters of Ag atoms by photoreduction of the Ag(I) phase films during the ORC. 相似文献
75.
The theory of linear collective motion is developed by the method of canonical transformations, recovering, as special cases, the earlier results of Casimir, Bohr-Mottelson, and Villars. In the approximation of constant Eckart-frame vectors, the kinetic energy Hamiltonian is shown to commute with the invariant operators of the collective motion symmetry group CM(3). The collective motion approach of Tomonaga, and the symmetry approach of Gell-Mann, are discussed and shown to be essentially equivalent, and to be properly contained in the CM(3) structure. The invariant operators of CM(3) are determined and shown to imply two invariants for nuclear collective motion: the volume Λ and the vortex-spin v. Representations of CM(3) are obtained and related to wavefunctions of the generator-coordinate form. 相似文献
76.
77.
Adam NE Alexander JP Berkelman K Cassel DG Crede V Duboscq JE Ecklund KM Ehrlich R Fields L Galik RS Gibbons L Gittelman B Gray R Gray SW Hartill DL Heltsley BK Hertz D Jones CD Kandaswamy J Kreinick DL Kuznetsov VE Mahlke-Krüger H Meyer TO Onyisi PU Patterson JR Peterson D Phillips EA Pivarski J Riley D Ryd A Sadoff AJ Schwarthoff H Shi X Shepherd MR Stroiney S Sun WM Urner D Wilksen T Weaver KM Weinberger M Athar SB Avery P Breva-Newell L Patel R Potlia V Stoeck H Yelton J Rubin P Cawlfield C 《Physical review letters》2006,96(8):082004
We observe signals for the decays psi(3770) --> XJ/psi from data acquired with the CLEO detector operating at the CESR e+ e- collider with square root of s = 3773 MeV. We measure the following branching fractions Beta(psi(3770) --> XJ/psi and significances: (189 +/- 20 +/- 20) x 10(-5) (11.6sigma) for X = pi+ pi-, (80 +/- 25 +/- 16) x 10(-5) (3.4sigma) for X = pi0 pi0, and (87 +/- 33 +/- 22) x 10(-5) (3.5sigma) for X = eta, where the errors are statistical and systematic, respectively. The radiative return process e+ e- --> gamma psi(2S) populates the same event sample and is used to measure Gamma ee[psi(2S)] = (2.54 +/- 0.03 +/- 0.11) keV. 相似文献
78.
Nelsen SF Weaver MN Luo Y Pladziewicz JR Ausman LK Jentzsch TL O'Konek JJ 《The journal of physical chemistry. A》2006,110(41):11665-11676
Sixty-five electron-transfer reactions including 27 new 0, +1 couples have been added to our data set of cross-reactions between 0 and +1 couples, bringing it to 206 reactions involving 72 couples that have been studied by stopped-flow kinetics in acetonitrile containing supporting electrolyte at 25 degrees C, formal potentials determined by cyclic voltammetry, and analyzed using Marcus cross-rate theory. Perhaps surprisingly, a least-squares analysis demonstrates that intrinsic rate constants exist that predict the cross-rate constants to within a factor of 2 of the observed ones for 93% of the reactions studied, and only three of the reactions have a cross-rate constant that lies outside of the factor of 3, that corresponds to a factor of 10 uncertainty in the rate constant for an unknown couple. Many triarylamines, which have very high intrinsic reactivity, are included among the newly studied couples. The enthalpy contribution to the Marcus reorganization energy, lambda'v, has been calculated for 46 of the couples studied, at the (U)B3LYP/6-31+G (or for the larger and lower barrier compounds, at the less time-consuming (U)B3LYP/6-31G) level. In combination with a modified Levich and Dogodnadze treatment that assumes that the rate constant is proportional to (KeHab2/lambda1/2) exp[-DeltaG/RT], this allows estimation of the electronic coupling (Hab) at the transition state for intermolecular electron transfer, (more properly H'ab, the product of the square root of the encounter complex formation constant times Hab) for these couples. Although the principal factor affecting intermolecular electron-transfer rate constants is clearly lambda, H'ab effects are easily detectable, and the dynamic range in our estimates of them is over a factor of 600. 相似文献
79.
Lockard JV Valverde G Neuhauser D Zink JI Luo Y Weaver MN Nelsen SF 《The journal of physical chemistry. A》2006,110(1):57-66
Excited state mixed valence (ESMV) occurs in molecules in which the ground state has a symmetrical charge distribution but the excited state possesses two or more interchangeably equivalent sites that have different formal oxidation states. Although mixed valence excited states are relatively common in both organic and inorganic molecules, their properties have only recently been explored, primarily because their spectroscopic features are usually overlapped or obscured by other transitions in the molecule. The mixed valence excited state absorption bands of 2,3-di-p-anisyl-2,3-diazabicyclo[2.2.2]octane radical cation are well-separated from others in the absorption spectrum and are particularly well-suited for detailed analysis using the ESMV model. Excited state coupling splits the absorption band into two components. The lower energy component is broader and more intense than the higher energy component. The absorption bandwidths are caused by progressions in totally symmetric modes, and the difference in bandwidths is caused by the coordinate dependence of the excited state coupling. The Raman intensities obtained in resonance with the high and low energy components differ significantly from those expected based on the oscillator strengths of the bands. This unexpected observation is a result of the excited state coupling and is explained by both the averaging of the transition dipole moment orientation over all angles for the two types of spectroscopies and the coordinate-dependent coupling. The absorption spectrum is fit using a coupled two-state model in which both symmetric and asymmetric coordinates are included. The physical meaning of the observed resonance Raman intensity trends is discussed along with the origin of the coordinate-dependent coupling. The well-separated mixed valence excited state spectroscopic components enable detailed electronic and resonance Raman data to be obtained from which the model can be more fully developed and tested. 相似文献
80.