Radiation-Induced Polymerization of Tetrafluoroethylene in Solution

Polymerization of tetrafluoroethylene in monochlorodifluoromethane was carried out at low temperatures with -prays from a ⁶⁰Co source. An activation energy of 4.3 kcal/mole was obtained for the in-source polymerization, and this is higher than that of bulk polymerization, 2.7 kcal/mole. It was found that a remarkable postpolymerization takes place even if the reaction system is in liquid state. A kinetic treatment for the postpolymerization is described.     

Synthesis and Enzymatic Degradation of Nylon 66 Copolymers with Poly(Ethyleneglycol)s

Abstract

Nylon 66 (N66) copolymers were prepared by melt polycondensation of adipic acid and hexamethylenediamine with 5–80 mol% poly(ethylene glycol) (PEG), where the molecular weight (MW) of PEG was 200–1000. The reduced specific viscosity of the copolymers was increased by the copolymerization. The crystallinity and melting temperature (T _m) of N66 components decreased with increasing PEG content, but T _m depression of copolymers at the same mole content decreased with increasing MW of PEG, suggesting that the copolymer structures are not of the random type but of the block type at the higher MW of PEG. The water absorption increased with increasing PEG content, and its increase was much higher at the higher MW of PEG. The enzymatic degradation was estimated by the weight loss of copolymer films in the buffer solution with and without a lipase at 37°C. The weight loss was enhanced appreciably by the presence of a lipase, and increased abruptly at higher PEG content, which was correlated to water absorption and the concentration of ester linkages. The enzymatic degradation of these N66 copolymers was much higher than that of previously reported PET copolymers with PEG. The abrupt increase of weight loss by alkali hydrolysis was fairly comparable to that of water absorption.     

Improving robustness of filtered-x least mean p-power algorithm for active attenuation of standard symmetric-α-stable impulsive noise

The paper concerns active control of impulsive noise having peaky distribution with heavy tail. Such impulsive noise can be modeled using non-Gaussian stable process for which second order moments do not exist. The most famous filtered-x least mean square (FxLMS) algorithm for active noise control (ANC) systems is based on the minimization of variance (second order moment) of error signal, and hence, becomes unstable for the impulsive noise. In order to improve the robustness of adaptive algorithms for processes having distributions with heavy tails (i.e. signals with outliers), either (1) a robust optimization criterion may be used to derive the adaptive algorithm or (2) the large amplitude samples may be ignored or replaced by an appropriate threshold value. Among the existing algorithms for ANC of impulsive noise, one is based on the minimizing least mean p-power (LMP) of the error signal, resulting in FxLMP algorithm (approach 1). The other is based on modifying; on the basis of statistical properties; the reference signal in the update equation of the FxLMS algorithm (approach 2). In this paper we propose two solutions to improve the robustness of the FxLMP algorithm. In first proposed algorithm, the reference and the error signals are thresholded before being used in the update equation of FxLMP algorithm. As another solution to improve the performance of FxLMP algorithm, a modified normalized step size is proposed. The computer simulations are carried out, which demonstrate the effectiveness of the proposed algorithms.     

Upper limit on gravitational wave backgrounds at 0.2 Hz with a torsion-bar antenna

We present the first upper limit on gravitational wave (GW) backgrounds at an unexplored frequency of 0.2 Hz using a torsion-bar antenna (TOBA). A TOBA was proposed to search for low-frequency GWs. We have developed a small-scaled TOBA and successfully found Ω(gw)(f)<4.3×10(17) at 0.2 Hz as demonstration of the TOBA's capabilities, where Ω(gw)(f) is the GW energy density per logarithmic frequency interval in units of the closure density. Our result is the first nonintegrated limit to bridge the gap between the LIGO band (around 100 Hz) and the Cassini band (10(-6)-10(-4) Hz).     

Explicit upper bound of the solution-free region for a Diophantine equation over number fields

Lithuanian Mathematical Journal - It is known that there exist only finitely many trivial solutions of a certain Diophantine equation over number fields except for the case the rational number...     

Role of vacuum ultraviolet irradiation in plasma‐induced graft polymerization in the pore‐filling polymerization of porous materials

The role of vacuum ultraviolet (VUV) rays contained in the plasma during plasma‐induced graft polymerization in the pores of a porous high‐density polyethylene (HDPE) substrate was investigated through the separation of the VUV rays from the plasma with LiF, CaF₂, and quartz filters. Two characteristic phenomena, the effect of the solvent on the grafting rate and the graft polymerization in the pores of the porous substrate, were observed in the VUV‐induced graft polymerization process. These results provided clear evidence that VUV rays in the plasma played an important role in the formation of grafted layers in the pores of the HDPE substrate. The relationship between the penetration depth of the VUV rays and the distribution of the grafted layer inside the substrate was examined. The calculated penetration depth of the VUV rays (and hence the distribution of radicals) and the distribution of the grafted layer were not consistent. However, this inconsistency could be explained by the fact that the effective density of the radicals that could react with the monomer to grow the grafting polymer was very low because of the steric hindrance of the grafted chains. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2068–2074, 2005     

Phase transition in Pd_(40)Ni_(10)Cu_(30)P_(20) bulk metallic glass under HP & HT

Bulk metallic glass (BMG) can be regarded as a metallic solid with a frozen-in melt structure which lacks atomic periodicity. Generally, BMG is not in an internal equilib- rium state (IES) but may change to the IES when it obtains an appropriate energy to overcome the energy barrier. High pressure and temperature can be a driving force to cause various transitions in amorphous materials, such as a transition from the amor- phous to the crystalline[1―8] or from the crystalline to the amorp…     

Photonic Boolean logic gates based on DNA aptamers

We designed a pair of DNA-based logic gates that sense single-stranded DNAs and aptamer ligands to produce fluorescence outputs according to Boolean logic functions AND and OR.     

Direct observation of the solvent reorientation dynamics in the "twisted" intramolecular charge-transfer process of cyanophenyldisilane-water cluster by transient infrared spectroscopy

The solvent reorientation dynamics of the intramolecular charge-transfer (ICT) process of the (p-cyanophenyl)pentamethyldisilane-H(2)O (CPDS-H(2)O) cluster was investigated by transient infrared (IR) absorption spectroscopy. Transient IR bands of two distinct charge-transfer (CT) states appeared in both the OH and the CN-stretching vibration regions. Analyses of the IR spectra and the time profiles of the transient bands revealed that the ICT process of the CPDS-H(2)O cluster proceeds in two steps. The first step is a transition from a photo-prepared locally excited (LE) state to the CT state, which is accompanied by a minor reorientation of the H(2)O moiety. In contrast, the second step is an extensive reorientation process of the H(2)O molecule in the CT state. These two reorientation processes exhibit very distinct pico- and nano-second time scales. In the latter case, a relatively slow time constant of 2 ns was related to a large geometric change in the orientation.