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51.
A. R. Ware K. J. Odell J. P. Martin 《Journal of Radioanalytical and Nuclear Chemistry》1998,228(1-2):5-13
This paper describes the development and validation of analytical procedures for the separation and determination of90Sr,90Y,238Pu,239/240Pu,241Am,241Cm and243/244Cm in liquid effluents and environmental samples. The procedures use supported reagents for extraction chromatography (reversed phase partition chromatography) that enable the separation of the analytes from a large number of other radionuclides present. 相似文献
52.
A. H. Ware 《Fresenius' Journal of Analytical Chemistry》1928,73(11):425
Ohne Zusammenfassung 相似文献
53.
Young G. Shin Steve A. Jones Stan C. Murakami Nageshwar Budha Joseph Ware Harvey Wong Michael H. Buonarati Brian Dean Cornelis E. C. A. Hop 《Biomedical chromatography : BMC》2013,27(1):102-110
A liquid chromatography–tandem mass spectrometric (LC‐MS/MS) method was developed and validated for the determination of GDC‐0152 in human plasma to support clinical development. The method consisted of a solid‐phase extraction for sample preparation and LC‐MS/MS analysis in the positive ion mode using TurboIonSprayTM for analysis. d7‐GDC‐0152 was used as the internal standard. A linear regression (weighted 1/concentration2) was used to fit calibration curves over the concentration range of 0.02–10.0 ng/mL for GDC‐0152. There were no endogenous interference components in the blank human plasma tested. The accuracy at the lower limit of quantitation was 99.3% with a precision (%CV) of 13.9%. For quality control samples at 0.0600, 2.00 and 8.00 ng/mL, the between‐run %CV was ≤8.64. Between‐run percentage accuracy ranged from 98.2 to 99.6%. GDC‐0152 was stable in human plasma for 363 days at ?20°C and for 659 days at ?70°C storage. GDC‐0152 was stable in human plasma at room temperature for up to 25 h and through three freeze–thaw cycles. In whole blood, GDC‐0152 was stable for 12 h at 4°C and at ambient temperature. This validated LC‐MS/MS method for determination of GDC‐0152 was used to support clinical studies. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
54.
55.
A. H. Ware J. A. Shawl F. Böck und G. Lock 《Fresenius' Journal of Analytical Chemistry》1930,81(8-9):324-326
Ohne Zusammenfassung 相似文献
56.
Carbohydrates are growing important renewable raw material for surfactant industry. The development of surfactants based on carbohydrate and vegetable oils is the result of the product concept based on the exclusive use of natural resources. Sugar based surfactants are gaining increased attention due to advantage with regard to performance, health of consumer and environmental compatibility compared to some standard product. Alkylpolyglycoside (APG) is nonionic surfactant prepared from renewable raw materials namely glucose and fatty alcohol. Such products are expected to exhibit surface‐active properties due to the presence of the hydrophilic sugar moiety and the hydrophobic fatty alcohol residues. This article deals with the synthesis of alkylpolyglycoside and the study their surface active properties. APG was prepared by using fatty alcohol varying in chain length from C8‐C18. Effect of alkyl chain length of APG on the basic characteristics such as surface tension, interfacial tension, lime soap dispersing power, detergency, foaming, and wetting were studied. Alkylpolyglycoside prepared from octanol, decanol, and dodecanol are water soluble and shows good surface active properties where as those prepared from long chain fatty alcohols were water insoluble and, therefore, not evaluated for their surface active properties. Incorporation of APG in toilet soap was studied. 相似文献
57.
Cristina Legido‐Quigley Cinzia Stella Francisco Perez‐Jimenez Jose Lopez‐Miranda Jose Ordovas Jonathan Powell Frans van‐der‐Ouderaa Lisa Ware John C. Lindon Jeremy K. Nicholson Elaine Holmes 《Biomedical chromatography : BMC》2010,24(7):737-743
The effects of sample preparation and chromatographic method differences on the classification and recovery of metabolic biomarkers from UPLC‐MS measurements on urine samples of humans exposed to different dietary interventions have been investigated. Eight volunteers consumed three high‐fat meals (rich in saturated, monounsaturated and polyunsaturated fatty acids, respectively) in randomized order with a washout period in between. For each participant, urine samples were obtained prior to and at three timed intervals after each meal. Samples were processed either by dilution (1 : 4) or by liquid–liquid extraction and then run under two different gradient conditions. For each analysis method, a total of 96 observations (eight participants, four time points, three diets) were measured. The total ion count chromatograms were analyzed using partial‐least‐squares discriminant analysis. All three dietary classes could be discriminated irrespective of sample preparation and chromatographic method. However, the main discriminating metabolites varied according to sample preparation, indicating that sample treatment and chromatographic conditions influence the ability to extract biomolecular information. Diluted samples showed higher m/z compounds (ca 400 u) while liquid–liquid extraction samples showed low m/z at the same retention time span. Optimized methods for metabolite identification (e.g. organic acids) were statistically inferior to global screening for mixed compound identification, confirming that multiple compound class‐based metabolic profiles are likely to give superior metabonomic (diagnostic) classification, although great care has to be taken in the interpretation in relation to matrix effects. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
58.
Roland BK Flora WH Selby HD Armstrong NR Zheng Z 《Journal of the American Chemical Society》2006,128(20):6620-6625
The reaction between the previously reported site-differentiated cluster solvate [Re(6)(mu(3)-Se)(8)(PEt(3))(5)(MeCN)](SbF(6))(2) (1) with pyridyl-based ditopic ligands 4,4'-trimethylenedipyridine (2), 1,2-bis(4-pyridyl)ethane (3), and (E)-1,2-bis(4-pyridyl)ethene (4) afforded cluster complexes of the general formula [Re(6)(mu(3)-Se)(8)(PEt(3))(5)(L)](SbF(6))(2) (5-7), where L represents one of the pyridyl-based ligands. Reacting these cluster complex-based ligands with the fully solvated cluster complex [Re(6)(mu(3)-Se)(8)(MeCN)(6)](SbF(6))(2) (8) produced dendritic arrays of the general formula {Re(6)(mu(3)-Se)(8)[Re(6)(mu(3)-Se)(8)(PEt(3))(5)(L)](6)}(SbF(6))(14) (9-11), each featuring six circumjacent [Re(6)(mu(3)-Se)(8)(PEt(3))(5)](2+) units bridged to a [Re(6)(mu(3)-Se)(8)](2+) core cluster by the pyridyl-based ligands. Electrochemical studies using a thin-layer electrochemical cell revealed cluster-based redox events in these cluster arrays. For 9 (L = 2), one reversible oxidation event corresponding to the removal of 7 electrons was observed, indicating noninteraction or extremely weak interactions between the clusters. For 10 (L = 3), two poorly resolved oxidation waves were found. For 11 (L = 4), two reversible oxidation events, corresponding respectively to the removal of 1 and 6 electrons, were observed with the 1-electron oxidation event occurring at a potential 150 mV more positive than the 6-electron oxidation. These electrochemical studies suggest intercluster coupling in 11 via through-bond electronic delocalization, which is consistent with electronic spectroscopic studies of this same molecule. 相似文献
59.
Shape–memory polymers (SMPs) are smart materials that can be designed to retain a metastable state and upon activation, recover a preprogrammed shape. In this study, poly(methyl acrylate) (PMA) is blended with poly(ethylene glycol) diacrylate (PEGDA) of various molecular weights in various concentrations and subsequently exposed to ionizing radiation. PEGDA sensitizes the radiation crosslinking of PMA, lowering the minimum absorbed dose for gelation and increasing the rubbery modulus, after crosslinking. Minimum dose for gelation, as determined by the Charlesby–Pinner equation, decreases from 25.57 kGy for unblended PMA to 2.06 kGy for PMA blended with 10.00 mole% PEGDA. Moreover, increase in the blend concentration of PEGDA increases the crosslinking density of the resulting networks. Sensitizer length, namely Mn of PEGDA, also affects crosslinking and final mechanical properties. Increase in the length of the PEGDA molecule at a constant molar ratio increases the efficacy of the molecule as a radiation sensitizer as determined by the increase in gel fraction and rubbery modulus across doses. However, at a constant weight ratio of PEGDA to PMA, shorter PEGDA chains sensitize more crosslinking because they have more reactive ends per weight fraction. Sensitized samples of PMA with PEGDA were tested for shape–memory properties and showed shape fixity of greater than 99%. Samples had a glass transition temperature near 28 °C and recovered between 97% and 99% of the induced strain when strained to 50%. 相似文献
60.
A. R. Ware 《Czechoslovak Journal of Physics》2006,56(1):D739-D741
Summary There is a need to raise profile of nuclear and radiochemistry in this “Nuclear Age” to share courses/facilities for education
& training and to establish funding for E & T needs of modern industry and society in general. 相似文献