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151.
Hallett AJ Baber RA Orpen AG Ward BD 《Dalton transactions (Cambridge, England : 2003)》2011,40(36):9276-9283
The tricarbonyl [Mn(CO)(3){HC(pz')(3)}][PF(6)] 1(+)[PF(6)](-) (pz' = 3,5-dimethylpyrazolyl) reacts with a range of P-, N- and C-donor ligands, L, in the presence of trimethylamine oxide to give [Mn(CO)(2)L{HC(pz')(3)}](+) {L = PEt(3)3(+), P(OEt)(3)4(+), P(OCH(2))(3)CEt 5(+), py 6(+), MeCN 7(+), CNBu(t)8(+) and CNXyl 9(+)}. The complex [Mn(CO)(2)(PMe(3)){HC(pz')(3)}](+)2(+) is formed by reaction of 7(+) with PMe(3). Complexes 2(+) and 6(+) were structurally characterised by X-ray diffraction methods. Reaction of 7(+) with half a molar equivalent of 4,4'-bipyridine gives a purple compound assumed to be the bridged dimer [{HC(pz')(3)}Mn(CO)(2)(μ-4,4'-bipy)Mn(CO)(2){HC(pz')(3)}](2+)10(2+). The relative electron donating ability of HC(pz')(3) has been established by comparison with the cyclopentadienyl and tris(pyrazolyl)borate analogues. Cyclic voltammetry shows that each of the complexes undergoes an irreversible oxidation. The correlation between the average carbonyl stretching frequency and the oxidation potential for complexes of P- and C-donor ligands is coincident with the correlation observed for [Mn(CO)(3-m)L(m)(η-C(5)H(5-n)Me(n))]. The data for complexes of N-donor ligands, however, are not coincident due to the presence of a node (and phase change) between the metal and the N-donor in the HOMO of the complex as suggested by preliminary DFT calculations. 相似文献
152.
The octanuclear coordination cage [Ni(8)(L(14Naph))(12)](BF(4))(16) has the core structure of a 'cuneane'--a toplogical isomer of a cube--with a metal ion at each of the eight vertices and bridging ligand spanning each of the twelve edges; this is the only possible 8-vertex polyhedron other than a cube that will form a cage in which each metal is connected to three others. 相似文献
153.
D'Autry W Wolfs K Hoogmartens J Adams E Van Schepdael A 《Journal of chromatography. A》2011,1218(26):4034-4038
Gas chromatography-mass spectrometry is a well established analytical technique. However, mass spectrometers with electron ionization sources may suffer from signal drifts, hereby negatively influencing quantitative performance. To demonstrate this phenomenon for a real application, a static headspace-gas chromatography method in combination with electron ionization-quadrupole mass spectrometry was optimized for the determination of residual dichloromethane in coronary stent coatings. Validating the method, the quantitative performance of an original stainless steel ion source was compared to that of a modified ion source. Ion source modification included the application of a gold coating on the repeller and exit plate. Several validation aspects such as limit of detection, limit of quantification, linearity and precision were evaluated using both ion sources. It was found that, as expected, the stainless steel ion source suffered from signal drift. As a consequence, non-linearity and high RSD values for repeated analyses were obtained. An additional experiment was performed to check whether an internal standard compound would lead to better results. It was found that the signal drift patterns of the analyte and internal standard were different, consequently leading to high RSD values for the response factor. With the modified ion source however, a more stable signal was observed resulting in acceptable linearity and precision. Moreover, it was also found that sensitivity improved compared to the stainless steel ion source. Finally, the optimized method with the modified ion source was applied to determine residual dichloromethane in the coating of coronary stents. The solvent was detected but found to be below the limit of quantification. 相似文献
154.
CdTe and CdTe-based Cd(1-x)Zn(x)Te (CZT) alloys are important semiconductor compounds that are used in a variety of technologies including solar cells, radiation detectors, and medical imaging devices. Performance of such systems, however, is limited due to the propensity of nano- and micro-scale defects that form during crystal growth and manufacturing processes. Molecular dynamics simulations offer an effective approach to study the formation and interaction of atomic scale defects in these crystals, and provide insight on how to minimize their concentrations. The success of such a modeling effort relies on the accuracy and transferability of the underlying interatomic potential used in simulations. Such a potential must not only predict a correct trend of structures and energies of a variety of elemental and compound lattices, defects, and surfaces but also capture correct melting behavior and should be capable of simulating crystalline growth during vapor deposition as these processes sample a variety of local configurations. In this paper, we perform a detailed evaluation of the performance of two literature potentials for CdTe, one having the Stillinger-Weber form and the other possessing the Tersoff form. We examine simulations of structures and the corresponding energies of a variety of elemental and compound lattices, defects, and surfaces compared to those obtained from ab initio calculations and experiments. We also perform melting temperature calculations and vapor deposition simulations. Our calculations show that the Stillinger-Weber parameterization produces the correct lowest energy structure. This potential, however, is not sufficiently transferrable for defect studies. Origins of the problems of these potentials are discussed and insights leading to the development of a more transferrable potential suitable for molecular dynamics simulations of defects in CdTe crystals are provided. 相似文献
155.
156.
M. B. Rane K. Kondaiah A. R. Middleton G. T. Wernimont S. L. Archangelowa M. Stschigol N. Dubinski L. W. N. Godward A. M. Ward A. D. Worobjewa P. Wukolow A. Reich N. A. Tananajew F. P. Dwyer R. H. Bullard J. S. Knapper K. A. Craig G. C. Chandlee W. I. Kosakow L. Szebellédy M. Ajtai M. Uljanitschew M. S. Platonow N. F. Kriwoschlykow A. A. Marakajew M. J. Petrow K. M. Rauner 《Analytical and bioanalytical chemistry》1939,117(3-4):118-132
157.
John Pattinson Gibb Kay Sexton David Watson W. J. Ward T. Egleston O. Pufahl und K. A. Åkerblom 《Fresenius' Journal of Analytical Chemistry》1886,25(1):255-258
Ohne Zusammenfassung 相似文献
158.
A. L. Ward W. H. Fulweiler und J. B. Firth 《Fresenius' Journal of Analytical Chemistry》1936,106(4-6):219-220
Ohne Zusammenfassung 相似文献
159.
160.
J. A. Muller C. Reinhardt C. Fischbach A. Siebenschub V. Stanek N. M. Randall K. Bogoluboff H. Wdowiszewski F. Garrat D. J. Demorest J. R. Cain H. E. Walters F. C. T. Daniels A. J. Field A. Terni P. Malaguti B. S. Evans L. W. Winkler O. L. Barnebey G. L. Kelley J. A. Wiley E. Little J. Costa M. Gröger H. O. Ward P. Slawik W. Hild und F. Simion 《Fresenius' Journal of Analytical Chemistry》1923,63(9):348-359
Ohne Zusammenfassung 相似文献