Charged particle multiplicity distributions at 200 and 900 GeV c.m. energy

Multiplicity distributions of charged particles produced in non single-diffractive collisions between protons and antiprotons at centre of mass energies of 200 and 900 GeV are presented. The data were recorded in the UA5 streamer chambers at the CERN Collider, which was operated in a pulsed mode between the two energies. A new method to correct for acceptance limitations and inefficiencies based on the principle of maximum entropy has been used. Multiplicity distributions in full phase space and in intervals of pseudorapidity are presented in tabular form. The violation of KNO scaling in full phase space found by the UA5 group at an energy of 546 GeV is confirmed also at 200 and 900 GeV. The shape of the 900 GeV distribution in full phase space is narrower in the peak region than at 200 GeV but exhibits a pronounced high multiplicity tail. The negative binomial distribution fits data at 200 GeV in all pseudorapidity intervals and in small intervals at 900 GeV. In large intervals at 900 GeV, however, the negative binomial distribution. Fits to the partially coherent laser distribution are also presented as well as comparisons with predictions of the Dual Parton, the Fritiof and the Pythia models.     

A study of molecular motion in a liquid-crystalline copolyester by broad-line nuclear magnetic resonance

Broad-line nuclear magnetic resonance (NMR) measurements have been carried out for the proton resonance in an oriented liquid-crystalline copolyster prepared from 4-hydroxybenzoic acid (HBA) and 2-hydroxy-6-naphthoic acid (HNA). The Second moments were determined as a function of the angle γ between the specimen orientation direction and the static magnetic field. The low-temperature NMR results are consistent with a rigid structure of random copolymer chains arranged on a hexagonal lattice. As the temperature is raised the NMR signal changes and can be modeled very satisfactorily by considering that there is free rotation of the benzene ring residues about the 1-4 substitution direction. At more elevated temperatures the observed NMR spectra are consistent with rotation of both HBA and HNA groups.     

Effect of crown-ether surfactants on flame atomic absorption and flame emission signals of some monovalent cations

Two surface-active and one surface-inactive 18-crown-6 derivatives were synthesized and evaluated for their abilities to enhance flame atomic absorption and flame emission signals of monovalent cations. Enhancement of potassium signals were noted for the surface-active compounds but not for the surface-inactive compound. The critical micelle concentration was determined and compared to the degree of enhancement. Surfactant-induced signal enhancements are not due to the slight or moderate decrease in the size of the aerosol first produced in the nebulizing chamber. Additional mechanistic considerations are discussed.     

Molecular orientation in biaxially oriented sheets of poly(ethylene terephthalate) II. Correlation of orientation averages with measured mechanical compliances

The aggregate model is extended to examine the relationship between mechanical anisotropy and molecular orientation in one-way drawn sheets of poly(ethylene terephthalate). It is assumed that both the aggregate and the unit of structure have orthorhombic symmetry. On the basis of a number of detailed assumptions regarding the appropriate application of the model, calculated bounds are obtained for the elastic constants that are in reasonable agreement with the experimental values. The implications of these results with regard to molecular orientation are considered, and it is concluded that both the chain orientation and orientation around the chain axis are important in determining the mechanical anisotropy.     

Spot Self-Replication and Dynamics for the Schnakenburg Model in a Two-Dimensional Domain

The dynamical behavior of multi-spot solutions in a two-dimensional domain Ω is analyzed for the two-component Schnakenburg reaction–diffusion model in the singularly perturbed limit of small diffusivity ε for one of the two components. In the limit ε→0, a quasi-equilibrium spot pattern in the region away from the spots is constructed by representing each localized spot as a logarithmic singularity of unknown strength S _j for j=1,…,K at unknown spot locations x _j ∈Ω for j=1,…,K. A formal asymptotic analysis, which has the effect of summing infinite logarithmic series in powers of −1/log ε, is then used to derive an ODE differential algebraic system (DAE) for the collective coordinates S _j and x _j for j=1,…,K, which characterizes the slow dynamics of a spot pattern. This DAE system involves the Neumann Green’s function for the Laplacian. By numerically examining the stability thresholds for a single spot solution, a specific criterion in terms of the source strengths S _j , for j=1,…,K, is then formulated to theoretically predict the initiation of a spot-splitting event. The analytical theory is illustrated for spot patterns in the unit disk and the unit square, and is compared with full numerical results computed directly from the Schnakenburg model.