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941.
Three new polyoxygenated briarane-type diterpenoids, briaexcavatolides X-Z (1-3), have been isolated from the gorgonian coral Briareum excavatum. The structures, including the relative configurations of briaranes 1-3, were elucidated by spectroscopic methods, particularly in 1D and 2D NMR experiments. The configuration of briarane 1 was further supported by molecular mechanics calculations. 相似文献
942.
943.
Shu-Lin Ma Zong-Hui Jiang Dai-Zheng Liao Shi-Ping Yan Geng-Lin Wang 《Transition Metal Chemistry》1994,19(5):531-533
Summary Two novel trinuclear complexes were prepared, namely [Cu2(oxae)2(H2O)2M] (ClO4)2, [oxae = N,N-bis(2-aminoethyl) oxamido dianion; M = Co and Ni]. Based on elemental analyses, conductivity measurements and i.r. spectra, the complexes are proposed to have extended oxamidobridged structures. The magnetic susceptibility of [Cu2-(oxae) 2(H2O)2Co](ClO4)2 were measured over the 4–300 K range and the observed data were successfully simulated by an equation based on the spin Hamiltonian, =–2J(1·2·2·3). The exchange integral, J, was found to be equal to –29.2 cm–1, indicating an antiferromagnetic spin-exchange interaction between the adjacent metal ions. 相似文献
944.
XIE Mao-Song YANG Xu CHEN Wen-Heng TAO Long-Xiang WANG Xuc-Lin XU Gui-Fen 《天然气化学杂志》1996,5(3):210-221
IntroductionMethancisthcmaJorcomponcntofnaturalgasanditscatalyticconvcrsiontodcsiredchemicalproductsorliquidfiJcIisnotonl}'apromisingapproachtotheutilizationofnaturalgasrcsourccbutalsoagrcatsubjcctforcatalysissciencctt'hichdcaIst"iththcactivationofsmallmolcculesThcx"orldrcscrvcofnaturalgashasbccnexplorcdasaboutl382562xl()8m3IllTheMTGprocessdcvclopedbythcMobilcorpcangctliquidfuelfrommethancthroughsteamreformingofmethanctoproduccsynthcsisgaswhichisassociatedt'ithamaJorityofthecostsofthcprocc… 相似文献
945.
946.
In this study, a rapid and sensitive high performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS) determination of primary As species in fish tissues and urine is reported. The separation was achieved on an Altima C18 column with a mobile phase containing citric acid and hexanesulfonic acid (pH 4.5). As(V), monomethylarsonic acid (MMA), As(III), dimethylarsinic acid (DMA) and arsenobetaine (AsB) were separated in less than 4 min with retention times of 83, 99, 130, 166 and 208 s, respectively. This separation of five species in less than 4 min should be attractive to those interested in As speciation. The quantification limits were 44, 56, 94, 64, 66 ng l(-1) and the relative standard deviations (R.S.D.) for day-to-day injections of As at 2 mug l(-1) were 2.0, 3.1, 2.4, 3.8 and 4.0%. The procedure was tested using two reference materials (DORM-2 dogfish muscle tissue, NIST SRM 2670 Freeze-dried Urine, normal level) and then applied to real-world samples. The results obtained demonstrate the suitability of the procedure for screening and quantification at physiological levels of primary As species in biological samples. 相似文献
947.
用统计模拟分光光度法测定复方消咳新片4个组分含量。按均匀设计表制备合成样品,绘制溶液的UV-VIS吸收曲线,获得有限但足够的实验数据,用逐步回归法构造反映该复方制剂组分在灵敏波长的吸光度-组分含量经验关系的“最优”数学模型,用改进单纯形法寻优,求出未知样品的各组分含量。磺胺甲基异恶唑、甲氧苄胺嘧啶、盐酸溴已新、枸橼酸维静宁的回收率分别为1003%、1004%、999%、990%,标准差分别为091%、14%、12%、39%。 相似文献
948.
Fe(110)面上直接在室温时吸附的CO同先在170 K吸附然后升温到室温的CO吸附有所不同. 前者有解离而后者无解离; 另外, 前者的饱和吸附量比后者低. 这可以用前者发生了解离来解释. 根据以上结果, 提出了以下的设想, Fe(110)面上的CO解离除了需要足够的热能而外, 还需要在表面的吸附位上有邻近的其它未被覆盖Fe原子的存在, 即需要一定的表面结构. 相似文献
949.
缬草根化学成分的研究 总被引:7,自引:0,他引:7
本文报道了湖南花坦县产的缬草根的化学成分,用气相色谱-色谱-计算机联用和波谱技术鉴定了缬草根中的44个组分,其中乙酸里哪醇酯,2-蒈烯,马拶铃烯,瓦伦烯,香橙烯,愈创木烯,异尼醇,乙酸金合欢酯,邻苯二甲酸二异辛酯,6,13-二甲基-十四烷酸和2-甲基十六烷酸甲酯等化合物是在缬草根中首次发现的,对缬草根中的氨基酸和微量元素也进行了测定。 相似文献
950.
穿过液膜的自发电势振荡 总被引:2,自引:0,他引:2
An artificial membrane consisting of pricramic acid in nitrobenzene was used as an oil phase imposed between two aqueous phases. The right one contained trimethyl-slearylammonium chloride and aicohol; and the left contained sucrose solution (or H_2O). We found that this system exhibited rhythmic oscillation of electrical potential. The amplitude of the oscillations was between 20—150 mV. The oscillations were observed even when ethyl alcohol was absent in the aqueous of trimethylslearylammonium Chloride, and the increase in amplitude of oscillation with time was found to be less in the presence of sucrose. Some of the expremental results have been explained. 相似文献