BF3-doped polyaniline: A novel conducting polymer

We review the unusual structural, transport and magnetic properties of highly conducting polyaniline, doped with boron trifluoride. Our studies establish the unique conducting state of this system, which is in distinct contrast with the conventional proton-doped polyaniline samples.     

Solution and solid-state NMR characterization of poly(p-phenylene terephthalamide)

NMR spectroscopy has been used to characterize poly(p-phenylene terephthalamide) in the solid state and in solution in sulfuric acid. Solid-state ¹³C NMR spectra illustrate that the chain structure is highly ordered in the solid state and is of lower symmetry than in solution. Solid-state ¹³C and ¹H NMR results show that only very limited motion takes place over the temperature range of ?170 to +200°C. High-resolution NMR spectra can be observed only in very dilute isotropic solutions because it is the overall rotational motion of the polymer, not segmental motion, that averages the nuclear spin interactions to their isotropic values. These results demonstrate that previous solution NMR studies that were interpreted as reflecting the presence of isotropic and anisotropic high-molecular-weight polymer phases over a wide range of concentrations actually are representative of polymer degradation.     

Representation of Cubic Lattices by Symmetric Implication Algebras

In this paper a cubic lattice L(S) is endowed with a symmetric implication structure and it is proved that L(S) \ {0} is a power of the three-element simple symmetric implication algebra. The Metropolis–Rota’s symmetries are obtained as partial terms in the language of symmetric implication algebras.     

Studies on the method of total synthesis of koumine: I. 4-Substituted 1,2-dihydropyridine derivatives and their function as a conjugated diene in Diels-Alder reaction

A route to the total synthesis of koumine has been suggested. Five 4-substituted 1, 2-d hydropyridine derivatives, which are supposed to be a conjugated diene of Diels-Alder reaction to produce the isoquinuclidine ring of koumine, have been synthesized. Only two of them were found to be able to undergo the Diels-Alder reaction. The stereochemistry of the reaction product has also been examined.     

Cathodoluminescence study of extended defects in hydrothermal ZnO crystals

Understanding the luminescence of ZnO is very important for some applications. In spite of the many studies carried out, there are still some points concerning the origin of some of the luminescence emissions in ZnO crystals that require additional study; in particular, the role of extended defects remains to be a matter of controversy. We present here a cathodoluminescence analysis of the defects generated by Vickers indentation in hydrothermal HTT crystals. Special emphasis was paid to the luminescence band peaking around 3.3 eV. The origin of this band is a matter of controversy, since it has been related to different causes, extended defects being one of the candidates for this emission. The CL images were acquired around crystal defects. It is observed that the 3.3 eV emission is enhanced around the crystal defects; though it is also observed, but weaker, out of the defect regions, which suggests that there exist two luminescence emissions peaking very close to 3.3 eV. The two emissions, one related to structural defects and the other to the LO phonon replica of the free excitonic band, appear very close each other and their relative intensity should determine the shape of the spectrum.     

On perfectly normal dense subspaces of products

Let M be a separable metric space consisting of more than one point. We construct perfectly normal dense subspaces Z⊂Mc² and (under additional set-theoretic assumption) Y⊂Mc which are not collectionwise Hausdorff.     

Photoemission studies of oxygen adsorbed on a LiAl(1 1 0) alloy surface: Role of Li segregation

We investigated that the effect of the number of segregated Li atoms on the rate of oxidation on a LiAl alloy surface. Oxygen molecules adsorbed on the LiAl alloy react with the surface atoms to form stable oxides. The segregated Li atoms at reconstructed surfaces (c(2×2) and (2×1)) enhance the oxidation rate and form stable LiAlO_x and Li₂O. The degree of enhancement of oxidation by segregated Li atoms varies as a function of O₂ exposure and annealing temperature, where the latter is directly related to the mode of surface reconstruction by Li segregation.     

Markarian 8星系的包层辐射

使用美国甚大天线阵(VLA).对Markarian 8星系进行了多频观测.多频VLA观测表明,Markarian 8星系有三个主要的射电子成份,它们浸在一个弥漫的星系包层中.包层的射电谱是陡的非热谱.本文根据VLA观测确定了包层的物理参量,并讨论了包层中相对论性电子的可能起因.本文估计了包层非热辐射所要求的超新星爆发率.     

Generation of red light at 660 nm by frequency doubling a Nd:YAG laser with periodically-poled stoichiometric LiTaO<Subscript>3</Subscript>

High power red light was generated from a periodically-poled stoichiometric LiTaO₃ (PPSLT) by single-pass frequency doubling of a diode-side-pumped, Q-switched Nd:YAG laser at 1319 nm. An average power of 2.4 W of the 660 nm red light was obtained at the fundamental power of ∼5.4 W with the conversion efficiency up to 44.4% and with low fluctuation down to 2%. The high efficiency and stability at the red output indicate that it is a practical method to construct a reliable compact red laser. PACS 42.70.Mp; 42.79.Nv; 42.55.Xi