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排序方式: 共有363条查询结果,搜索用时 15 毫秒
51.
Bernabé L. Rivas Julio Sánchez S. Amalia Pooley Luis Basaez Eduardo Pereira Christophe Bucher Guy Royal Eric Saint Aman Jean-Claude Moutet 《Macromolecular Symposia》2010,296(1):416-428
Arsenic species can be removed from aqueous solutions using the liquid-phase polymer-based retention, LPR, technique. The LPR technique removes ionic species by functional groups of water-soluble polyelectrolytes (WSP) and then using a ultrafiltration membrane that does not let them pass through the membrane, thus separating them from the solution. The ability of WSP with groups (R)4N+X− to remove arsenate ions using LPR was studied. The interaction and arsenate anion retention capacity depended on: pH, the quaternary ammonium group's counter ion, and the ratio polymer: As(V), using different concentrations of As(V). Water-soluble polychelates were also used for one-step retention of As(III) in solution. The complex of poly(acrylic acid)-Sn, 10 and 20 wt-% of metal gave a high retention of As(III) species at pH 8, although the molar ratio polychelate: As(III) was 400:1. The enrichment method was used to determine the maximum retention capacity (C) for arsenate anions in aqueous solutions at pH 8. In similar conditions, the values of C were 142 mg g−1 for P(ClAETA) and 75 mg g−1 for P(SAETA). The combined treatment of arsenic aqueous solutions by electrocatalytic oxidation (EO) to convert the species of As(III) to As(V) with the LPR technique quantitatively removed arsenic. 相似文献
52.
Adler SS Afanasiev S Aidala C Ajitanand NN Akiba Y Al-Jamel A Alexander J Aoki K Aphecetche L Armendariz R Aronson SH Averbeck R Awes TC Babintsev V Baldisseri A Barish KN Barnes PD Bassalleck B Bathe S Batsouli S Baublis V Bauer F Bazilevsky A Belikov S Bjorndal MT Boissevain JG Borel H Brooks ML Brown DS Bruner N Bucher D Buesching H Bumazhnov V Bunce G Burward-Hoy JM Butsyk S Camard X Chand P Chang WC Chernichenko S Chi CY Chiba J Chiu M Choi IJ Choudhury RK Chujo T Cianciolo V Cobigo Y 《Physical review letters》2006,96(22):222301
Deuteron-gold (d+Au) collisions at the Relativistic Heavy Ion Collider provide ideal platforms for testing QCD theories in dense nuclear matter at high energy. In particular, models suggesting strong saturation effects for partons carrying small nucleon momentum fraction (x) predict modifications to jet production at forward rapidity (deuteron-going direction) in d+Au collisions. We report on two-particle azimuthal angle correlations between charged hadrons at forward/backward (deuteron/gold going direction) rapidity and charged hadrons at midrapidity in d+Au and p+p collisions at square root of sNN=200 GeV. Jet structures observed in the correlations are quantified in terms of the conditional yield and angular width of away-side partners. The kinematic region studied here samples partons in the gold nucleus with x~0.1 to ~0.01. Within this range, we find no x dependence of the jet structure in d+Au collisions. 相似文献
53.
Parametric excitation or pumping is an effective method to create large oscillations by periodically altering a physical parameter of the governing dynamics. Precisely tuned pumping frequencies can lead to exponentially growing oscillations limited only by nonlinear effects like axial stretching of transversely vibrating string. It is demonstrated that a tuned passive dynamical system amplifies the otherwise limited transverse vibrations amplitudes of a nonlinear string considerably and thus increasing the selectivity of the system. This effect becomes more noticeable for shorter wavelengths where nonlinear stretching limits the obtainable vibration amplitudes severely. The present work analyses a passive dynamical system connected to one end of a taught string which parametrically couples its axial motion to transverse vibration. Analysis shows that a specific selection of parameters can reduce the limiting effect of nonlinear stretching thus allowing one to excite high-order modes with small external forces. The result can possibly affect other disciplines where effective parametric amplification is necessary. 相似文献
54.
Afanasiev S Aidala C Ajitanand NN Akiba Y Alexander J Al-Jamel A Aoki K Aphecetche L Armendariz R Aronson SH Averbeck R Awes TC Azmoun B Babintsev V Baldisseri A Barish KN Barnes PD Bassalleck B Bathe S Batsouli S Baublis V Bauer F Bazilevsky A Belikov S Bennett R Berdnikov Y Bjorndal MT Boissevain JG Borel H Boyle K Brooks ML Brown DS Bucher D Buesching H Bumazhnov V Bunce G Burward-Hoy JM Butsyk S Campbell S Chai JS Chernichenko S Chiba J Chi CY Chiu M Choi IJ Chujo T Chung P Cianciolo V 《Physical review letters》2008,100(23):232301
A three-dimensional correlation function obtained from midrapidity, low p(T), pion pairs in central Au+Au collisions at sqrt[s(NN)]=200 GeV is studied. The extracted model-independent source function indicates a long range tail in the directions of the pion pair transverse momentum (out) and the beam (long). A proper breakup time tau(0) ~ 9 fm/c and a mean proper emission duration Delta tau ~ 2 fm/c, leading to sizable emission time differences ({|Delta t(LCM)|} approximately 12 fm/c), are required to allow models to be successfully matched to these tails. The model comparisons also suggest an outside-in "burning" of the emission source reminiscent of many hydrodynamical models. 相似文献
55.
Dr. Simon Pascal Léo Bucher Dr. Nicolas Desbois Dr. Christophe Bucher Dr. Chantal Andraud Prof. Dr. Claude P. Gros 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(14):4971-4979
The synthesis of dyad and triad aza‐BODIPY‐porphyrin systems in two steps starting from an aryl‐substituted aza‐BODIPY chromophore is described. The properties of the resulting aza‐BODIPY‐porphyrin conjugates have been extensively investigated by means of electrochemistry, spectroelectrochemistry, and absorption/emission spectroscopy. Fluorescence measurements have revealed a dramatic loss of luminescence intensity, mainly due to competitive energy transfer and photoinduced electron transfer involving charge separation followed by recombination. 相似文献
56.
Dr. Soukaina Bennaamane Barbara Rialland Lhoussain Khrouz Dr. Marie Fustier-Boutignon Dr. Christophe Bucher Dr. Eric Clot Dr. Nicolas Mézailles 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(3):e202209102
Ammonia, NH3, is an essential molecule, being part of fertilizers. It is currently synthesized via the Haber–Bosch process, from the very stable dinitrogen molecule, N2 and dihydrogen, H2. This process requires high temperatures and pressures, thereby generating ca 1.6 % of the global CO2 emissions. Alternative strategies are needed to realize the functionalization of N2 to NH3 under mild conditions. Here, we show that boron-centered radicals provide a means of activating N2 at room temperature and atmospheric pressure whilst allowing a radical process to occur, leading to the production of borylamines. Subsequent hydrolysis released NH4+, the acidic form of NH3. EPR spectroscopy supported the intermediacy of radicals in the process, corroborated by DFT calculations, which rationalized the mechanism of the N2 functionalization by R2B radicals. 相似文献
57.
We prove that there is a gap between \(\sqrt 2 and\left( {1 + \sqrt 5 } \right)/2\) for the exponential growth rate of nontrivial free products. For amalgamated products G = A*CB with ([A: C] ? 1)([B: C] ? 1) ≥ 2, we show that an exponential growth rate lower than \(\sqrt 2 \) can be achieved. Indeed, there are infinitely many amalgamated products for which the exponential growth rate is equal to ψ ≈ 1.325, where ψ is the unique positive root of the polynomial z3?z?1. One of these groups is \(PGL\left( {2,\mathbb{Z}} \right) \cong \left( {{C_2} \times {C_2}} \right){*_{{C_2}}}{D_6}\). However, under some natural conditions the lower bound can be put up to \(\sqrt 2 \). This answers two questions by Avinoam Mann [The growth of free products, Journal of Algebra 326, no. 1 (2011), 208–217]. We also prove that ψ is a lower bound for the minimal growth rates of a large class of Coxeter groups, including cofinite non-cocompact planar hyperbolic groups, which strengthens a result obtained earlier by William Floyd, who considered only standard Coxeter generators. 相似文献
58.
Enyne-allenes 4a-c bearing various cyclopropyl systems as radical clock reporter groups at the allene terminus have been synthesized and subjected to thermal C2-C6 cyclization. The ratio of ene versus formal Diels-Alder products could be rationalized on the basis of steric effects. Only the thermolysis of 4c, equipped with the fast diphenylcyclopropylcarbinyl radical clock, afforded a 1,3-butadienyl benzofulvene clearly formed via cyclopropyl ring opening. This finding provides unambiguous evidence for a stepwise mechanism of the C2-C6 cyclization making it possible to suggest a lifetime for the intermediate diradical of >1x10(-10) s (at 170 degrees C). An interesting corollary was the isolation of an unexpected silyl shift product in the thermolysis of all three enyne-allenes that allows explanation of the loss of the TIPS group in some of the Diels-Alder products. For a full understanding of the mechanism, silyl and hydrogen shift processes were interrogated using DFT. 相似文献
59.
60.
George O. Buica Christophe Bucher Jean‐Claude Moutet Guy Royal Eric Saint‐Aman Eleonora M. Ungureanu 《Electroanalysis》2009,21(1):77-86
Complexing polymer‐coated electrodes have been synthesized by oxidative electropolymerization of ethylenediamine tetra‐N‐(3‐pyrrole‐1‐yl)propylacetamide (monomer L ). The presence of four polymerizable pyrrole fragments on the same EDTA skeleton was thought to confer enhanced rigidity and controlled dimensionality to the resulting complexing materials, which were used for the electrochemical detection of Hg(II), Cu(II), Pb(II) and Cd(II) ions by means of the chemical preconcentration‐anodic stripping technique. The polyamide electrode material showed particularly a significant selectivity towards mercury ions, even in the presence of a large excess of other metal cations. Moreover, the use of imprinted polymer‐coated electrodes prepared by electropolymerization of L in the presence of metal cations turned out to significantly improve the detection limits, down to 5×10?10 mol L?1 for Hg(II) and Cu(II) species. 相似文献