Crossover between thermally assisted and pure quantum tunneling in molecular magnet Mn12-acetate

The crossover between thermally assisted and pure quantum tunneling has been studied in single crystals of high spin (S = 10) uniaxial molecular magnet Mn12 using micro-Hall-effect magnetometry. Magnetic hysteresis and relaxation experiments have been used to investigate the energy levels that determine the magnetization reversal as a function of magnetic field and temperature. These experiments demonstrate that the crossover occurs in a narrow ( approximately 0. 1 K) or broad ( approximately 1 K) temperature interval depending on the magnitude of the field transverse to the anisotropy axis.     

First On-line beta-NMR on oriented nuclei: magnetic dipole moments of the (nup(1/2))(-1) 1/2(-) ground state in 67Ni and (pip(3/2))(+1) 3/2(-) ground state in 69Cu

The first fully on-line use of the angular distribution of beta emission in detection of NMR of nuclei oriented at low temperatures is reported. The magnetic moments of the single valence particle, intermediate mass, isotopes 67Ni(nup(-1)(1/2);1/2(-)) and 69Cu(pip(1)(3/2);3/2(-)) are measured to be +0.601(5) &mgr;(N) and +2.84(1) &mgr;(N), respectively, revealing only a small deviation from the neutron p(1/2) single-particle value in the former and a large deviation from the proton p(3/2) single-particle value in the latter. Quantitative interpretation is given in terms of core polarization and meson-exchange currents.     

Recovery of embryos of Zizania palustris following exposure to liquid nitrogen

Factors affecting survival of embryos of Zizania palustris after exposure to liquid nitrogen were investigated. Moisture content was the most critical factor. Embryos desiccated to a moisture content between 0.36 and 0.56 g water per g dry weight had highest survival after liquid nitrogen exposure (56 +/- 4% and 52 +/- 9% respectively). The recovery of embryos in the light following liquid nitrogen exposure also influenced survival. Survival increased from 35 +/- 4% to 56 +/- 4% when embryos containing 0.36 g water per g dry weight were recovered in the dark compared to light. Embryos exposed to desiccation and freezing stresses were subject to increased levels of lipid peroxidation. Light exacerbated lipid peroxidation in recovering embryos. Furthermore, catalase and peroxidase, enzymes involved in reducing reactive oxygen species, increased in activity in response to stress, and were further up-regulated in tissues recovered in the light. This study suggests that there are a number of factors influencing the survival of tissues exposed to liquid nitrogen and recovery procedures that reduce oxidative stress should be employed.     

High-performance affinity chromatography: a powerful separation technique

Analyses of complex biochemical samples can be performed within one minute using a method which combines the selectivity of affinity chromatography with the speed of high-performance liquid chromatography.     

Software Reviews

Alcohol Discovery Lab Voltage Plotter USA Social and Geographical Database Hometown—A Local Area Study Heat and Light Drug Alert     

Glaspunkte von textilen Polyamidfasern. II. Beziehungen zwischen Glaspunkt und Anf?rbbarkeit

Ohne Zusammenfassung     

Effects of adsorbates on electron spin polarization in low energy electron diffraction from tungsten (001): I. Disordered CO and O2 overlayers

Electron spin polarization and intensity profiles have been measured in low energy electron diffraction (LEED) for the (00) beam at θ = 13δ and ø = 0δ from W(001) as a function of surface exposure to CO and O₂. Significant changes have been observed in the profiles upon exposure to both adsorbate gases, and the implications of these results are discussed.     

Long-range memory effects in flows involving abrupt changes in geometry: Part I: flows associated with I-shaped and T-shaped geometries

This is a theoretical paper which attempts to study for the first time the effect of high elasticity in flow situations involving elastico-viscous liquids and abrupt changes in geometry. It is argued that implicit rheological models are essential in this exercise and, accordingly, the numerical method of solution is forced to recognise the equations of continuity, the stress equations of motion and the rheological equations as separate equations involving velocity, pressure and stress variables with appropriate boundary conditions on these variables.The present paper is concerned with L-shaped and T-shaped geometries, and the effect of elasticity is assessed by comparing the numerical predictions for an elastic liquid with those for an inelastic liquid with the same “viscosity” behaviour. This comparison is facilitated by a simple limiting procedure outlined in Section 2.The main conclusions from the work are that, in general terms, elasticity works against inertia, reducing the pressure drop caused by the abrupt change in geometry and reducing the area of influence of the bend (for finite Reynolds numbers). So far as the stress fields are concerned most interest centres on the corner region, as one would expect, but there is also a region of normal-stress activity, which is generated by “stretching” rather than “shearing”.In an appendix, some consideration is given to the entry-length and exit-length problems. It is concluded that the overall problem is a complex one, since it depends to a large measure on the criterion one uses for “fully-developed” flow. If a fairly crude criterion is used, fluid elasticity is found to decrease the entry-length and increase the exit-length.