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171.
Zusammenfassung In 2-Stellung aliphatisch substituierte Pyrazolanthrone sind-im Gegensatz zu aromatisch substituierten Pyrazolanthronenleicht zu äthinieren.
Die Stellungsbezeichnung folgt dem Ringindex (RRI 4453) wonach das Grundsystem der Pyrazolanthrone als Anthra [1,9-cd] pyrazol bezeichnet wird.
23. Mitt.:W. Ried undSt. Piesch, Chem. Ber.99, 233 (1965).
Teil der Dissertat.St. Piesch, Univ. Frankfurt/M., 1965. 相似文献
Pyrazolanthrones with aliphatic substituents at position 2 readily undergo ethynation in contrast to those with aromatic substituents.
Die Stellungsbezeichnung folgt dem Ringindex (RRI 4453) wonach das Grundsystem der Pyrazolanthrone als Anthra [1,9-cd] pyrazol bezeichnet wird.
23. Mitt.:W. Ried undSt. Piesch, Chem. Ber.99, 233 (1965).
Teil der Dissertat.St. Piesch, Univ. Frankfurt/M., 1965. 相似文献
172.
Transient absorption spectra were recorded 15 ns to 6 μs following a 266 nm laser pulse for phenyl azide and for phenyl isocyanate in aerated acetonitrile and 3-methylpentane solutions. Transient spectra which are independent of concentration and of delay time, are essentially identical for phenyl azide and for phenyl isocyanate, except at higher energies where phenyl azide absorbs, and are assigned as that of triplet phenyl nitrene. Since there is no spectral evidence for a second species, phenyl nitrene is thought the chain propagator in the autocatalytic chain decomposition that occurs for phenyl azide and for phenyl isocyanate. 相似文献
173.
The partitioning behavior of erythrocytes in Reppal PES 200 (a hydroxypropyl starch produced by Reppe Glykos AB, V?xj?, Sweden)-polyethylene glycol (PEG) and in dextran (Dx)-PEG aqueous phase systems made isotonic with phosphate is similar in a number of ways: (i) There is a correlation between the relative electrophoretic mobilities and partition ratios, P, of red blood cells from different species; (ii) The cell P is reduced when, at constant polymer concentrations, phosphate is systematically replaced by sodium chloride (with the total concentration isotonic); (iii) The cell P is increased with reduced polymer concentrations (decreased interfacial tensions); (iv) Treatment of erythrocytes with neuraminidase results in a reduced P value; (v) Rat red cells of different ages can be fractionated by counter-current distribution; and (vi) Differences between red blood cells from genetically distinct rats or between humans can be detected. Aquaphase (a hydroxypropyl starch marketed by Perstorp AB, Lund, Sweden) has been tested as in ii-iv above with analogous results. The partitioning behavior of erythrocytes in PES-PEG and Dx-PEG aqueous phase systems containing sodium chloride differs in a number of ways: (vii) The correlation, apparent in Dx-PEG systems, between the P value of red blood cells from different species and the ratio of their membrane poly- to monounsaturated fatty acids is absent in PES-PEG systems. It is replaced by a correlation as in i; (viii) The increase in P value in Dx-PEG observed from red blood cells after treatment with neuraminidase is replaced by a decrease in P value in PES-PEG or Aquaphase-PEG systems. We conclude that PES (and Aquaphase) can be substitutes for dextran in cell partitioning studies when charge-sensitive phases are used (e.g., those containing phosphate) while separations based on properties reflected by Dx-PEG systems containing sodium chloride are not duplicated by PES-PEG (and probably not by Aquaphase-PEG). The hydroxypropyl starch-PEG systems containing sodium chloride, unlike the analogous Dx-PEG systems, have a significant electrostatic potential difference between the phases. 相似文献
174.
Determination of the Enantiomeric Excess of Chiral Ammonium long Using Liquid Membrane Electrodes A cell assembly with two membranes each containing one enantiomer of a chiral ionophore is described. It is suitable for the direct potentiometric determination of the enantiomeric excess of ions. The method is used to determine the enantiomeric excess of ephedronium ions in aqueous solutions. 相似文献
175.
Erik G.P. da Silva Ana Carolina do N. Santos Antnio C.S. Costa Dalva M. da N. Fortunato Ndia M. Jos Maria G.A. Korn Walter N.L. dos Santos Srgio L.C. Ferreira 《Microchemical Journal》2006,82(2):159-162
In the present work, a slurry sampling flame atomic absorption spectrometric method to determine directly manganese and zinc in powdered chocolate samples is proposed. The optimization step was performed using univariate methodology involving the following factors: nature and concentration of the acid solution, sonication time, and particle size. The established conditions led to the use of a sample mass of 150 mg, 2.0 mol L− 1 nitric acid solution, sonication time of 15 min, and a slurry volume of 50 mL. This method allows the determination of manganese and zinc with detection limit of 52 and 61 ng g− 1, respectively, and a precision expressed as relative standard deviation (RSD) of 2.6% and 3.2% (both, n = 10) for contents of manganese and zinc of 52.4 and 100.0 μg g− 1, respectively. The proposed method was applied for determination of manganese and zinc in five powdered chocolate samples. In these, the manganese content varied from 42.8 to 52.7 and from 88.6 to 102.4 μg g− 1 of zinc. The analytical results were compared with the results obtained by analysis of these samples after digestion using open vessel and acid bomb digestion procedures and determination using FS-FAAS. The statistical comparison by t-test (95% confidence level) showed no significant difference between these results. 相似文献
176.
Liu S Wollenberger U Halámek J Leupold E Stöcklein W Warsinke A Scheller FW 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(14):4239-4246
A method is provided for the recognition of glycated molecules based on their binding affinities to boronate-carrying monolayers. The affinity interaction of flavin adenine dinucleotide (FAD) and horseradish peroxidase (HRP) with phenylboronic acid monolayers on gold was investigated by using voltammetric and microgravimetric methods. Conjugates of 3-aminophenylboronic acid and 3,3'-dithiodipropionic acid di(N-hydroxysuccinimide ester) or 11-mercaptoundecanoic acid were prepared and self-assembled on gold surfaces to generate monolayers. FAD is bound to this modified surface and recognized by a pair of redox peaks with a formal potential of -0.433 V in a 0.1 M phosphate buffer solution, pH 6.5. Upon addition of a sugar to the buffer, the bound FAD could be replaced, indicating that the binding is reversible. Voltammetric, mass measurements, and photometric activity assays show that the HRP can also be bound to the interface. This binding is reversible, and HRP can be replaced by sorbitol or removed in acidic solution. The effects of pH, incubation time, and concentration of H(2)O(2) were studied by comparing the catalytic reduction of H(2)O(2) in the presence of the electron-donor thionine. The catalytic current of the HRP-loaded electrode was proportional to HRP concentrations in the incubation solution in the range between 5 microg mL(-1) and 0.1 mg mL(-1) with a linear slope of 3.34 microA mL mg(-1) and a correlation coefficient of 0.9945. 相似文献
177.
Chelate complexes of the type (CO)4MiX2 (X = Me, Cl) have been prepared from Na[Mn(CO)5] and HMn (CO)5, respectively, by two-step reactions with the ligands Me2PCH2CH2SiX2R′ using alkali salt, amine or HCl elimination. (CO)4MiCl2 is also obtained by cleavage of Mn2(CO)10 with Me2PCH2CH2SiCl3. IN the case of HMn (CO)5 the intermediates (CO)4Mn (H) L [L = Me2PSiMe3, Me2PCH2CH2SiMe2 (NMe2), Me2PCH2CH2SiCl2 (NMe2] can be isolated. The new compounds were identified by analytical and spectroscopic (IR, PMR, MS) methods. 相似文献
178.
Rodion V. Panin Nellie R. Khasanova Evgeny V. Antipov Walter Schnelle 《Journal of solid state chemistry》2007,180(5):1566-1574
NaPd3O4, Na2PdO3 and K3Pd2O4 have been prepared by solid-state reaction of Na2O2 or KO2 and PdO in sealed silica tubes. Crystal structures of the synthesized phases were refined by the Rietveld method from X-ray powder diffraction data. NaPd3O4 (space group Pm3¯n, a=5.64979(6) Å, Z=2) is isostructural to NaPt3O4. It consists of NaO8 cubes and PdO4 squares, corner linked into a three-dimensional framework where the planes of neighboring PdO4 squares are perpendicular to each other. Na2PdO3 (space group C2/c, a=5.3857(1) Å, b=9.3297(1) Å, c=10.8136(2) Å, β=99.437(2)°, Z=8) belongs to the Li2RuO3-structure type, being the layered variant of the NaCl structure, where the layers of octahedral interstices filled with Na+ and Pd4+ cations alternate with Na3 layers along the c-axis. Na2PdO3 exhibits a stacking disorder, detected by electron diffraction and Rietveld refinement. K3Pd2O4, prepared for the first time, crystallizes in the orthorhombic space group Cmcm (a=6.1751(6) Å, b=9.1772(12) Å, c=11.3402(12) Å, Z=4). Its structure is composed of planar PdO4 units connected via common edges to form parallel staggered PdO2 strips, where potassium atoms are located between them. Magnetic susceptibility measurements of K3Pd2O4 reveal a Curie-Weiss behavior in the temperature range above 80 K. 相似文献
179.
Holder Alvin A. Brown Ross F. G. Marshall Sophia C. Payne Vince C. R. Cozier Maria D. Alleyne Walter A. Bovell Christopher O. 《Transition Metal Chemistry》2000,25(5):605-611
A detailed investigation of the oxidation of L-ascorbic acid (H2A) by the title complex has been carried out using conventional spectrophotometry at 510 nm, over the ranges: 0.010 [ascorbate]
T
0.045 mol dm–3, 3.62 pH 5.34, and 12.0 30.0 °C, 0.50 I 1.00 mol dm–3, and at ionic strength 0.60 mol dm–3 (NaClO4). The main reaction products are the bis(pyridine-2,6-dicarboxylate)cobaltate(II) ion and l-dehydroascorbic acid. The reaction rate is dependent on pH and the total ascorbate concentration in a complex manner, i.e., k
obs = (k
1
K
1)[ascorbate]
T
/(K
1 + [H+]). The second order rate constant, k
1 [rate constant for the reaction of the cobalt(III) complex and HA–] at 25.0 °C is 2.31 ± 0.13 mol–1 dm3 s–1. H
= 30 ± 4 kJ mol–1 and S
= –138 ± 13 J mol–1 K–1. K
1, the dissociation constant for H2A, was determined as 1.58 × 10–4 mol dm–3 at an ionic strength of 0.60 mol dm–3, while the self exchange rate constant, k
11 for the title complex, was determined as 1.28 × 10–5 dm3 mol–1 s–1. An outer-sphere electron transfer mechanism has been proposed. 相似文献
180.
Losod, a new type of crystalline hydrated sodium aluminosilicate, Na12Al12Si12O48 · q H2O, has been prepared from reaction mixtures containing bulky quaternary alkylammonium ions, particularly azonia-spiro[4.4]nonane, besides sodium ions. Losod crystallizes from batches with a low sodium content (Na/Al ≤ 1 and Si/Al ≈? 1). The quaternary ammonium hydroxide primarily serves as a source of hydroxide ions and is not incorporated into the zeolite crystals. These bulky bases provide a useful means for controlling the alkalinity of the system independently of the concentration of the necessary cations built into the zeolite. The crystals of Losod are hexagonal (a = 12.91 and c = 10.54 Å) and the proposed framework structure shows a polytypic relationship to sodalite and cancrinite. Losod has reversible sorption and ion exchange properties typical of a small-pore zeolite and in essential agreement with the proposed structure. 相似文献