Pressure beneath a Stokes wave

We investigate the pressure within an irrotational fluid in a periodic, steady, two‐dimensional gravity wave above a flat bed. We prove that the pressure in the fluid strictly decreases horizontally away from the crest line. Furthermore, the pressure strictly increases with depth. We also investigate the effect of an underlying current on the paths of the particles. © 2009 Wiley Periodicals, Inc.     

Potential-modulated, attenuated total reflectance spectroscopy of poly(3,4-ethylenedioxythiophene) and poly(3,4-ethylenedioxythiophene methanol) copolymer films on indium-tin oxide

We report the first application of a potential-modulated spectroelectrochemical ATR (PM-ATR) instrument utilizing multiple internal reflections at an optically transparent electrode to study the charge-transfer kinetics and electrochromic response of adsorbed films. A sinusoidally modulated potential waveform was applied to an indium-tin oxide (ITO) electrode while simultaneously monitoring the optical reflectivity of thin (2-6 equivalent monolayers) copolymer films of poly(3,4-ethylenedioxythiophene) (PEDOT) and poly(3,4-ethylenedioxythiophene methanol) (PEDTM), previously characterized in our laboratory. At high modulation frequencies the measured response of the polymer film is selective toward the fastest electrochromic processes in the film, presumably those occurring within the first adsorbed monolayer. Quantitative determination of the electrochromic switching rate, derived from the frequency response of the attenuated reflectivity, shows a linear decrease in the rate, from 11 x 10(3) s(-1) to 3 x 10(3) s(-1), with increasing proportions of PEDTM in the copolymer, suggesting that interactions between the methanol substituent on EDTM and the ITO surface slow the switching process by limiting the rate of conformational change in the polymer film.     

Dependence of the zero shear-rate viscosity and the viscosity function of linear high-density polyethylenes on the mass-average molar mass and polydispersity

Linear high-density polyethylenes with molar masses M _w between 240 and 1,000,000 g/mol, obtained by metallocene catalysts, were characterized in shear using oscillatory and creep tests. The polydispersities of the molar mass distributions (MMDs) lay between 1 and 16. The resulting zero shear-rate viscosities η₀ covered a range from 2.5×10⁻³ to around 10⁸ Pas. Above a critical molar mass of M _c≈2,900 g/mol, the experimental results can be described by the relation η₀ ∼ M _w^3.6, independently of the MMD. The oscillatory data were fitted with a Carreau–Yasuda equation. The resulting parameters were correlated to molecular structure. The parameter a, being a quantity for the width of the transition between the Newtonian and the non-Newtonian regime, showed a dependence on the molar mass M _w but not on M _w/M _n. The parameter λ of the Carreau-Yasuda equation was found to be the reciprocal crossover frequency for all samples with a log-Gaussian MMD. λ depends on the molar mass M _w and also on M _w/M _n.

Equations on real intervals

A (finite or infinite) set ∑ of equations, in operation symbols F_t (t ∈T) and variables x_i, is said to be compatible with iff there exist continuous operations F_t^A on such that the algebra satisfies the equations ∑ (with the variables x_i understood as universally quantified). It is proved that there is no algorithm to decide -compatibility for all finite ∑. If the definition is restricted to C¹ idempotent operations F_t^A , then there does exist an algorithm for compatibility. Received August 9, 2005; accepted in final form February 14, 2006.     

An Optimal Algorithm for the <Emphasis Type="Italic">k</Emphasis>-Fixed-Endpoint Path Cover on Proper Interval Graphs

In this paper we consider the k-fixed-endpoint path cover problem on proper interval graphs, which is a generalization of the path cover problem. Given a graph G and a set T of k vertices, a k-fixed-endpoint path cover of G with respect to T is a set of vertex-disjoint simple paths that covers the vertices of G, such that the vertices of T are all endpoints of these paths. The goal is to compute a k-fixed-endpoint path cover of G with minimum cardinality. We propose an optimal algorithm for this problem with runtime O(n), where n is the number of intervals in G. This algorithm is based on the Stair Normal Interval Representation (SNIR) matrix that characterizes proper interval graphs. In this characterization, every maximal clique of the graph is represented by one matrix element; the proposed algorithm uses this structural property, in order to determine directly the paths in an optimal solution.     

Spontaneous Assembly of Miktoarm Stars into Vesicular Interpolyelectrolyte Complexes

Mixing a bis‐hydrophilic, cationic miktoarm star polymer with a linear polyanion leads to the formation of unilamellar polymersomes, which consist of an interpolyelectrolyte complex (IPEC) wall sandwiched between poly(ethylene oxide) brushes. The experimental finding of this rare IPEC morphology is rationalized theoretically: the star architecture forces the assembly into a vesicular shape due to the high entropic penalty for stretching of the insoluble arms in non‐planar morphologies. The transmission electron microscopy of vitrified samples (cryogenic TEM) is compared with the samples at ambient conditions (in situ TEM), giving one of the first TEM reports on soft matter in its pristine environment.

     

Infinite Quasimonotone Systems of Ordinary Differential Equations with Applications to Stochastic Processes

We deal with the initial value problem for countably infinite linear systems of ordinary differential equations of the form y '( t ) = A ( t ) y ( t ) where A ( t ) = ( a ij ( t ): i , j S 1) is a measurable, infinite and essentially positive matrix, i.e., a ij ( t ) S 0 for i p j . The main novelty of our approach is the systematic use of a classical comparison theorem for finite linear systems which leads easily to the existence of a nonnegative minimal solution and its properties. Application to generalized stochastic birth and death processes produces criteria for honest and dishonest probability distributions. A short proof of the Kolmogorov and Chapman-Kolmogorov equations for stochastic processes follows. The results hold for L 1 -coefficients. Our method extends to nonlinear infinite systems of quasimonotone type and can be used for numerical procedures that yield exact results; cf. the Addendum.