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201.
Ab initio coupled cluster calculations with single and double substitutions and a perturbative treatment of connected triple excitations [CCSD(T)] with the augmented correlation-consistent polarized valence triple-zeta aug-cc-pVTZ basis at 51 816 geometries provide a six-dimensional potential-energy surface for the electronic ground state of NH3. At 3814 selected geometries, CBS+ energies are obtained by extrapolating the CCSD(T) results for the aug-cc-pVXZ(X=T,Q,5) basis sets to the complete basis set (CBS) limit and adding corrections for core-valence correlation and relativistic effects. CBS** ab initio energies are generated at 51,816 geometries by an empirical extrapolation of the CCSD(T)/aug-cc-pVTZ results to the CBS+ limit. They cover the energy region up to 20,000 cm-1 above equilibrium. Parametrized analytical functions are fitted through the ab initio points. For these analytical surfaces, vibrational term values and transition moments are calculated by means of a variational program employing a kinetic-energy operator expressed in the Eckart-Sayvetz frame. Comparisons against experiment are used to assess the quality of the generated potential-energy surfaces. A "spectroscopic" potential-energy surface of NH3 is determined by a slight empirical adjustment of the ab initio potential to the experimental vibrational term values. Variational calculations on this refined surface yield rms deviations from experiment of 0.8 cm-1 for 24 inversion splittings and 0.4 (3.0) cm-1 for 34 (51) vibrational term values up to 6100 (10,300) cm-1. 相似文献
202.
The synthesis and selected reactions of 2-amino-3-(cyanomethylsulfonyl)thiophene is reported. In particular, cyclization reaction of the versatile aminothiophene yielded a number of novel thieno[3,2-b][1,4]-thiazine 1,1-dioxides, as well as the analogous thieno[2,3-e][1,3,4]thiadiazine 4,4-dioxide. Reaction of the thienothiazine system with hydrazine was subsequently explored, which resulted in either ring-opening of the thiazine and formation of an aminopyrazole or solely ring cleavage depending on the thiazine substituent. Additionally, the synthesis of bis(2-amino-3-thienyl)sulfone and the corresponding bis-acetamide is described. 相似文献
203.
Navzer D. Sachinvala Ruei F. Ju Morton H. Litt Walter P. Niemczura 《Journal of polymer science. Part A, Polymer chemistry》1995,33(1):15-29
A series of methyl methacrylate polymers have been prepared containing sucrose-based crosslinkers and additives. Thermogravimetry and long-term aging studies at 200°C show that sucrose-based alkyl and allyl ethers provide unprecedented thermal stability to linear, as well as crosslinked, poly (methyl methacrylate) or PMMA. Linear PMMA and PMMA crosslinked with trimethylolpropane trimethacrylate (TMPTMA) both degrade at 284°C. PMMA containing octa-O-crotylsucrose (1 mol %) degraded at 322°C. Depending on concentration, PMMA containing octa-O-allylsucrose (0.1-1.0 mol % and higher) degraded between 334 and 354°C, and PMMA containing 1′,6,6′-trimethacryloyl-2,3,3′,4,4′-penta-O-methylsucrose (0.1-1.0 mol %) degraded between 309 and 320°C. PMMA containing (1 mol % each) sucrose-based esters, ester-ether derivatives, all degraded at or below the degradation temperature of pure PMMA. Long-term air aging studies revealed that PMMA containing penta-O-methylsucrose trimethacrylate, octa-O-allylsucrose, and octa-O-crotylsucrose did not flow or sag after heating for 24 h at 200°C, but the polymers did show yellowing. While linear and crosslinked samples of PMMA containing compounds other than sucrose ethers lost more than 50% of their original weight within 15 h at 200°C, PMMA containing sucrose-based ethers lost about 8 and 20% of their original weight after 1 and 8.5 days, respectively. Herein we propose a unique mechanism by which saccharide ethers may be imparting this unprecedented thermal stabilization to PMMA. While tertiary hydrogens alpha to oxygens in saccharide ethers are stable to chain transfer during normal polymerization temperatures, they readily chain transfer at 200°C where PMMA is unstable. Chain transfer of these hydrogens is followed by fragmentation to produce alkyl, allyl or crotyl radicals, which combine with the macroradicals and terminate depropagation. © 1995 John Wiley & Sons, Inc. 相似文献
204.
Rate constants for the removal of Cl atoms in the reaction Cl + O3 → ClO + O2 were measured by the flash photolysis resonance fluorescence technique over the temperature range 213–298 K. The rate constant is given by the Arrhenius expression (2.94 ± 0.49) × 10?11 exp[?(298 ± 39)/T] in units of cm3 molecule?1 s?1. Comparison with recent results from other laboratories are presented. 相似文献
205.
The thermal expansion of VN1?x was determined from measurements of the lattice parameters in the temperature range of 298–1000 K and in the composition range of VN0.707–VN0.996. Within the accuracy of the results the expansion of the lattice parameter with temperature is not dependent on the composition. The lattice parameter as a function of composition ([N]/[V]=0.707?0.996) and temperature (298–1000 K) is given by $$\begin{gathered} a([N]/[V],T) = 0.38872 + 0.02488([N]/[V]) - \hfill \\ - (1.083 \pm 0.021) \cdot 10^{ - 4} T^{1/2} + (6.2 \pm 0.1) \cdot 10^{ - 6} T. \hfill \\ \end{gathered} $$ . The coefficient of linear thermal expansion as a function of temperature (in the same range) is given by $$\alpha (T) = a([N]/[V],T)^{ - 1} [( - 5.04 \pm 0.01) \cdot 10^5 T^{ - 1/2} + (6.2 \pm 0.1) \cdot 10^{ - 6} ].$$ . The average linear thermal expansion coefficient is $$\alpha _{av} = 9.70 \pm 0.15 \cdot 10^{ - 6} K^{ - 1} (298 - 1 000K).$$ . The data are compared with those of several fcc transition metal nitrides collected and evaluated from the literature. 相似文献
206.
Walter Harm 《Photochemistry and photobiology》1968,7(1):73-86
Abstract— Exposure of E. coli B/r and B at low average dose rates of u.v. radiation (2537 Å), produced either by fractionated doses or by continuous irradiation at a very low dose rate (80 ergs/mm2 /hr), results in much increased survival compared to single exposure at high dose rate. This increase is attributed to repair taking place during the irradiation period. The effect is small in the repair-deficient strains E. coli B8-1 _, and C syn- , and is absent in phage T1 and T4, which cannot undergo repair in the extracellular state. However, the prolonged time available for repair in these experiments accounts for only a very minor part of the increase in survival. The principal factor apparently is that the number of lesions present at any time remains relatively low. Presumably complete repair, not only the excision step, can occur in buffer during the irradiation period. This interpretation is supported by experiments in which cells were exposed to combinations of highly fractionated irradiation and single-dose irradiation. We therefore propose that mutual interference in repair, possibly by overlapping of repair regions in complementary DNA strands, reduces considerably the repair efficiency if many lesions are present. This hypothesis explains the 'shouldered' survival curves of B/r and possibly other E. coli strains as due to decreasing repair efficiency with increasing u.v. dose 相似文献
207.
Chen Z Heine T Jiao H Hirsch A Thiel W Schleyer Pv 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(4):963-970
Hybrid B3LYP and density-functional-based tight-binding (DFTB) computations on the solid-state structures and electronic properties of the C(20) fullerene monomer and oligomers are reported. C(20) cages with C(2), C(2h), C(i), D(3d), and D(2h) symmetries have similar energies and geometries. Release of the very high C(20) strain is, in theory, responsible for the ready oligomerization and the formation of different solid phases. Open [2+2] bonding is preferred both in the oligomers and in the infinite one-dimensional solids; the latter may exhibit metallic character. Two types of three-dimensional solids, the open [2+2] simple cubic and the body-centered cubic (bcc) forms, are proposed. The energy of the latter is lower due to the better oligomer bonding. The open [2+2] simple cubic solid should be a conductor, whereas the bcc solids are insulators. The most stable three-dimensional solid-state structure, an anisotropically compressed form of the bcc solid, has a HOMO-LUMO gap of approximately 2 eV and a larger binding energy than that of the proposed C(36) solid. 相似文献
208.
Walter Huber 《Mikrochimica acta》1969,57(5):897-904
Zusammenfassung Durch Hydrolyse in siedender, hochkonzentrierter Phosphorsäure läßt sich anscheinend aus allen Kohlensäurederivaten quantitativ Kohlendioxid abspalten. Dieses wird nach Reinigung und Trocknung gravimetrisch bestimmt. Folgende Verbindungen wurden analysiert: lineare und cyklische Harnstoffe, Thioharnstoffe, Urethane, Carbamate, Kohlensäureester, Phenylisocyanat, Melamin, Guanidin, Cyanursäure und Dicyandiamid. Die Anwendung verschiedener Phosphorsäurekonzentrationen erlaubt auch selektive Bestimmungen.
Herrn Prof. Dr.B. Timm zum 60. Geburtstag gewidmet. 相似文献
The determination of derivatives of carbonic acid via an acidic hydrolysis
Summary Hydrolysis in boiling highly concentrated phosphoric acid seemingly results in the quantitative splitting off of carbon dioxide from all derivatives of carbonic acid. The latter is determined gravimetrically after purification and drying. The following compounds were analyzed: linear and cyclic ureas, thioureas, urethanes, carbamates, esters of carbonic acid, phenylisocyanate, melamine, guanidine, cyanuric acid, dicyandiamide. The use of various concentrations of phosphoric acid permits selective determinations.
Herrn Prof. Dr.B. Timm zum 60. Geburtstag gewidmet. 相似文献
209.
A measuring system is described which permits study of all stages of combustion processes as functions of carrier gas, temperature, residence time and tube filling. The organic sample is fed at constant speed into a stream of carrier gas. The mixture reaches the combustion chamber within a few milliseconds via a transfer capillary. With the help of a viscous inlet system, a sample of the resulting reaction products is taken and fed into a mass spectrometer. Reaction time and temperature can be adjusted within wide ranges or varied continuously. A plot of the extent of reaction of the various combustion products against temperature at a chosen reaction time yields an oxidation-thermogram which gives a clear picture of the combustion process. It is evident from thermograms of selected compounds that the samples decompose in the presence of oxygen at appreciably lower temperatures than in inert gas. The primary step of the decomposition is “oxidative pyrolysis” which often leads to other products than “inert pyrolysis”. The intermediate products found are partly structurally specific and, especially with nitrogen-containing samples, are numerous and long-lived (for example, carbon monoxide, nitric oxide, cyanogen, hydrocyanic acid, cyanic acid and methyl cyanate). The notorious “difficult combustibility” is largely due to the fact that carbon monoxide, cyanic and hydrocyanic acids undergo complete combustion only at very high temperature. The combustion properties of the “empty tube” can be improved noticeably by a filling of quartz wool and markedly by partly filling with platinum wool. 相似文献
210.
A series of indole, thiophene and pyrrole-fused 1,3-oxazine-2,4-diones, 2-methyl-1,3-oxazin-4-ones and 2-dimethylamino-1,3-oxazin-4-ones were synthesized and evaluated as antitumor agents. 相似文献