全文获取类型
收费全文 | 241篇 |
免费 | 2篇 |
专业分类
化学 | 91篇 |
晶体学 | 9篇 |
力学 | 11篇 |
数学 | 54篇 |
物理学 | 78篇 |
出版年
2019年 | 2篇 |
2014年 | 2篇 |
2013年 | 14篇 |
2012年 | 8篇 |
2011年 | 4篇 |
2010年 | 3篇 |
2009年 | 2篇 |
2008年 | 3篇 |
2007年 | 5篇 |
2006年 | 6篇 |
2005年 | 6篇 |
2004年 | 3篇 |
2003年 | 5篇 |
2002年 | 2篇 |
2001年 | 7篇 |
2000年 | 3篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 10篇 |
1992年 | 13篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 7篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1974年 | 8篇 |
1973年 | 15篇 |
1972年 | 5篇 |
1971年 | 4篇 |
1970年 | 2篇 |
1969年 | 3篇 |
1968年 | 2篇 |
1966年 | 1篇 |
1907年 | 1篇 |
1890年 | 1篇 |
排序方式: 共有243条查询结果,搜索用时 15 毫秒
91.
Biomolecular homochirality, the origin of which is still a puzzle, has challenged scientists to design chemical systems that provide chiral molecules through absolute asymmetric synthesis and to amplify a small stereochemical bias in such systems. The photoresolution of the enantiomers of helical-shaped, sterically overcrowded alkene 1 with circularly polarized light and the transduction of the stereochemical information by triggering the helical arrangement of a large collection of achiral molecules in a twisted nematic liquid crystalline phase (2) are examples of control and amplification of chirality. 相似文献
92.
In the crystal structure of the title compound at 98 K the dimethylamino group has pyramidal geometry. The nitrogenlone pair is not directed towards the triple bond; instead, one N? CH3 bond lies almost in the plane of the disubstituted ring, directed away from the triple bond, while the other N? CH3 bond and the lone pair are directed to opposite sides of the plane, nearer to the acetylene. There is a remarkably short intramolecular contact (2.39 Å) between a methyl H- and an acetylenic C-atom. The Taft σI parameter of the arylethynyl substituent appears to be similar to that of a carboxylic ester, judging from the bond-angle deformation at the ipso-C-atom. 相似文献
93.
The time constant for the collisional deactivation of the υ = 1 vibrational level of N2 is found to be 1.5 ± 0.5 s in liquid nitrogen of 99.9995% purity of 78 K. This result is consistent with a simple binary collision theory of vibrational relaxation for liquids. 相似文献
94.
Michael Wallis 《Polymer Degradation and Stability》2006,91(7):1476-1483
The thermal degradation of high density polyethylene has been modelled by the random breakage of polymer bonds, using a set of population balance equations. A model was proposed in which the population balances were lumped into representative sizes so that the experimentally determined molecular weight distribution of the original polymer could be used as the initial condition. This model was then compared to two different cases of the unlumped population balance which assumed unimolecular initial distributions of 100 and 500 monomer units, respectively. The model that utilised the experimentally determined molecular weight distribution was found to best describe the experimental data. The model fits suggested a second mechanism in addition to random breakage at slow reaction rates. 相似文献
95.
Salts of Halogenophosphoric Acids. XVII. Preparation and Crystal Structure of Copper(II) Monofluorophosphate Dihydrate CuPO3F · 2H2O Copper(II) monofluorophosphate dihydrate, CuPO3F · 2H2O 1 was obtained by the reaction of aqueous NH4HPO3F and acid (NH4)2PO3F solutions, respectively, using acetone or ethanol as precipitating agents. The thermal dehydration of 1 gives the water-free copper monofluorophosphate CuPO3F ( 2 ). 1 crystallizes in the monoclinic space group P21/c with a = 761,44, b = 780,97, c = 921,02 pm, β = 112,94° and Z = 4. 相似文献
96.
97.
Megan Hogan Juliet Cotter James Claffey Brendan Gleeson Denise Wallis Donal O'Shea Matthias Tacke 《Helvetica chimica acta》2008,91(9):1787-1797
From the carbolithiation of 1‐(cyclopenta‐2,4‐dien‐1‐ylidene)‐N,N‐dimethylmethanamine (=6‐(dimethylamino)fulvene; 3 ) and different lithiated azaindoles 2 (1‐methyl‐7‐azaindol‐2‐yl, 1‐[(diethylamino)methyl]‐7‐azaindol‐2‐yl, and 1‐(methoxymethyl)‐7‐azaindol‐2‐yl), the corresponding lithium cyclopentadienide intermediates 4a – 4c were formed (7‐azaindole=1H‐pyrrolo[2,3‐b]pyridine). The latter underwent a transmetallation reaction with TiCl4 resulting in the (dimethylamino)‐functionalised ‘titanocenes’ 5a – 5c . When the ‘titanocenes’ 5a – 5c were tested against LLC‐PK cells, the IC50 values obtained were of 8.8, 12, and 87 μM , respectively. The most cytotoxic ‘titanocene’, 5a , with an IC50 value of 8.8 μM is nearly as cytotoxic as cis‐platin, which showed an IC50 value of 3.3 μM when tested on the epithelial pig kidney LLC‐PK cell line, and ca. 200 times better than ‘titanocene dichloride’ itself. 相似文献
98.
Structural studies of peri-interactions with dimethylamino groups in naphthalene systems indicate that the N-phenylcarboxamide group has a through-space electron attracting power closer to that of a carboxylic ester than a N,N-dialkylcarboxamide, while 2-nitroalkenyl groups have a lower through-space electron attracting power. However, addition of a benzoyl group to the 2-position of the nitroethenyl group leads to cyclisation to give a zwitterion, in which the carbanion is stabilised by full conjugation with the nitro group and partial conjugation with the carbonyl group. An interesting case where a steric interaction overrides an electrophile/nucleophile attraction is also described. The limitations to the interpretation of short contact distances from crystallographic measurements are discussed. 相似文献
99.
W. D. Wallis 《Combinatorica》1982,2(1):99-101
The problem is considered of decomposing a given graph into the minimum number of complete subgraphs. Asymptotic results are
obtained for the case where the graph is the complement of a graph with relatively few unisolated vertices.
This research was carried out while the author was visting Queen’s University, Kingston, whose hospitality is gratefully acknowledged. 相似文献
100.
Jennifer Wallis 《Journal of Combinatorial Theory, Series A》1973,15(3):323-328
We show that if four suitable matrices of order m exist then there are Hadamard matrices of order 28m, 36m, and 44m. In particular we show that Hadamard matrices of orders 14(q + 1), 18(q + 1), and 22(q + 1) exist when q is a prime power and q ≡ 1 (mod 4).Also we show that if n is the order of a conference matrix there is an Hadamard matrix of order 4mn.As a consequence there are Hadamard matrices of the following orders less than 4000: 476, 532, 836, 1036, 1012, 1100, 1148, 1276, 1364, 1372, 1476, 1672, 1836, 2024, 2052, 2156, 2212, 2380, 2484, 2508, 2548, 2716, 3036, 3476, 3892.All these orders seem to be new. 相似文献