Ueber die Einwirkung des Wasserstoffs auf salpetersaures Silberoxyd

Ohne Zusammenfassung     

Anionic iron(II) alkoxides as initiators for the controlled ring‐opening polymerization of lactide

Hetero‐bimetallic Fe(II) alkoxide/aryloxides were evaluated as initiators for the ring‐opening polymerization of rac‐lactide. [(THF)NaFe(O^tBu)₃]₂ ( 1 ) and [(THF)₄Na₂Fe(2,6‐diisopropylphenolate)₄] ( 2 ) (THF = tetrahydrofuran) both polymerized lactide efficiently at room temperature, with complex 1 affording better control over the molecular weight parameters of the resultant polymer. At conversions below 70%, a linear increase in molecular weight with conversion was observed, indicative of a well‐controlled polymerization process. Complex 2 is the first example of a dianionic Fe(II) alkoxide and has been structurally characterized to reveal a distorted square planar FeO₄ array in which both Na counterions bridge two aryloxide ligands and are further complexed by two THF ligands. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3798–3803, 2003     

Modelling and design of a travelling-wave electro-optic modulator on InP

Based on a rigorous vectorial analysis, a fast travelling-wave Mach–Zehnder modulator is modelled and designed. The cross-section of the semiconductor layer stack and the lossy electrodes are carefully modelled using the method of lines in order to investigate propagation characteristics, velocity and losses. This yields an accurate microwave and optical field distribution to explain the behaviour of the component. In order to enhance the modulation efficiency, design curves are derived and the cross-sectional dimensions for minimum microwave loss are determined. The loss of the optimized modulator agrees very well with small-signal measurements up to 40 GHz and HFSS simulations. The layerstack of the fabricated device is suitable for integration with InP multi-wavelength lasers.     

Nuclear clusters and covalently bound nuclear molecules

Nuclear clustering in N = Z nuclei has been studied for many decades. Of particular relevance are states close to the decay thresholds, as described by the Ikeda diagram. Recent interest has focused on loosely bound systems as observed with exotic nuclei. Extreme deformations are simultaneously observed. In the deformed shell model these are referred to as super- and hyper-deformation. Another feature related to clustering is the development of octupole deformations. A possible approach to describe these states is to use explicitly molecular concepts, with neutrons in covalent binding orbits. Examples for molecular structure in beryllium isotopes and in other neutron-rich light nuclei (carbon and neon) are now well established. The predicted chain states in the carbon isotopes are the first example of structures with an axis ratio of 3:1. A threshold diagram for molecular configurations in nuclei with clusters and covalent neutrons can be established.