Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Z photoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities

Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of gamma-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by gamma-CD.     

Application of the Swimming Pool Backwash Water Recovery System with the Use of Filter Tubes

During the operation of swimming pools, large losses of water from the backwash of swimming pool filters are observed. This water is often discharged into sewers or used to sprinkle sports grounds. The aim of the research was to design and build an installation for purification and recovery of backwash water (BWW). It consists of flocculation, pre-filtration, and ultrafiltration based on filter tubes and ozone disinfection. Backwash water treatment installation contributes to purification and improvement of water quality. The effectiveness of the removal of microbial contamination with the use of the system was over 99%. The high efficiency of removing physicochemical impurities was also achieved. Water turbidity was reduced from 96.9 NTU to 0.13 NTU. After using the system, the oxidability of water decreased from 6.26 mg O₂∙dm⁻³ to 0.4 mg O₂∙dm⁻³. When using the system, a reduction of total organic carbon by 80% was also noticed. After the treatment process, water meets the strict criteria and can be returned to the pool system of water as fresh water with parameters of supply water—directly to the overflow tank. It has been shown that up to 96% of water can be recovered with the technology. The cost comparison showed annual savings of over EUR 9000.     

Singlet oxygenation of cis,cis-1,5-cyclooctadiene: a convenient synthetic entry into 5,8-difunctionalized oxygen derivatives of 1,3-cyclooctadiene

The 6-hydroperoxy-1,4-cyclooctadiene ($\text{2}$), which is formed in the photosensitized oxygenation of 1,5-cyclooctadiene ($\text{1}$), affords on further singlet oxygenation 5,8-dihydroperoxy-1,3-cyclooctadiene ($\text{3}$), which via triphenylphosphine reduction leads to $\text{cis}$-5,8-dihydroxy-1,3-cyclooctadiene ($\text{4}$) and subsequent pyridinium chlorochromate oxidation to 1,3-cyclooctadien-5,8-dione ($\text{8}$).     

Extension of longwavelength IR photovoltaic detector operation to near room-temperatures

Practical realization of near room temperature (230–300 K) longwavelength (5–12 μm) photovoltaic detectors is reported. The devices are epitaxial n⁺ip photodiodes operated at ambient temperature or with a simple, two-stage thermoelectric cooling. The performance of the photodiodes has been improved by the use optimized composition and doping profile structures. The tunnel currents were minimized by interfacing the n⁺ and p-type layers with a thin (0.5 μm) lightly doped i-region. The quantum efficiency has been increased by the use of backside reflector. Further improvement of performance was achieved by the use of monolithic optical immersion. Large area devices with useful performance were obtained by the use of small close-spaced elements connected in series. The near room temperature photovoltaic detectors are of particular significance for very low and very high frequency applications.     

Corneal topography measurement by means of radial shearing interference: Part III – measurement errors

This work contains results of computer simulation researches, which define requirements for measurement conditions, which should be fulfilled so that measurement results ensure allowable errors. They define: allowable measurement errors (interferogram's scanning) and conditions, which should fulfill computer programs, so that errors introduced by mathematical operations and computer are the smallest.     

Analysis of supramolecular interactions in alendroniate alkali metal salts: synthesis,structure, and properties of novel sodium alendronate polymorph

A new polymorph of anhydrous sodium alendronate, C₄H₁₂NO₇P₂Na, has been synthesized and characterized by single crystal X-ray diffraction as well as infrared spectroscopy and thermal analysis. The title compound crystallizes in the monoclinic P2₁/c space group. Asymmetric unit consists of one alendronic anion and one sodium cation. An interplay of classical strong O-H^…O, N-H^…O and non-classical weak C-H^…O hydrogen bonds creates 3D framework in the crystal. Contrary to previously reported sodium alendronate salts, in which Na⁺ cation is surrounded by six-coordinated sphere, in compound (1), the Na⁺ cation is five-coordinated in a distorted trigonal-bipyramidal geometry. In order to provide a detailed investigation of the molecular arrangement in view of intermolecular interactions, the title compound was compared with alendronic acid and other known alkali metal alendronate salts, retrieved from the Cambridge Crystal Structure Database. The intercontacts were qualitatively and quantitatively compared using Hirshfeld surface analysis. It highlights that strong O^…H/H^…O and subtle H^…H contacts play an influential role in the total surface area. The Me^+…H/H^…Me⁺ and Me^+…O/O^…Me⁺ contacts are meaningful as well. These evidently simple systems show a diverse complexity. Moreover, the powder X-ray diffraction, DSC, thermogravimetry/derivative thermogravimetry, and FT-IR results are also reported.